1-(芘-1-基)-3-(4-甲氧基苯基)丙烯酮的合成及三阶非线性光学性质

应用化学, 2016, 33(2): 149-154. doi: 10.11944/j.issn.1000-0518.2016.02.150216

1-(芘-1-基)-3-(4-甲氧基苯基)丙烯酮的合成及三阶非线性光学性质

石玉芳 ^1, , 孙金鱼 ^2, , 刘成琪 ^3, , 赵明根 ^4,

1.忻州师范学院化学系,山西省材料与计算化学重点实验室山西忻州,034000

2.忻州师范学院化学系,山西省材料与计算化学重点实验室山西忻州,034000

3.忻州师范学院化学系,山西省材料与计算化学重点实验室山西忻州,034000

4.忻州师范学院化学系,山西省材料与计算化学重点实验室山西忻州,034000

基金项目: the Key Discipline of Xinzhou Teachers University Subject(XK201205) 忻州师范学院重点学科专项课题(XK201205)

关键词：芘衍生物 , (芘基)-(甲氧基苯基)丙烯酮 , 查尔酮 , 合成 , 非线性光学性质

Synthesis and Third-order Nonlinear Optical Property of 1-(Pyrene-1-yl)-3-(4-methoxyphenyl) acrylic Ketone

Keywords： pyrene derivatives , Chalcone , (pyrene-yl)-(methoxyphenyl) acrylic ketone , synthesis , nonlinear optical properties

合成了一种新的有机非线性光学(NLO)材料1-(芘-1-基)-3-(4-甲氧基苯基)丙烯酮(PMPAK),通过1 H NMR、IR、HR-MS和元素分析表征其结构.以Nd∶ YAG-Laser System作为光源,激光波长450 nm,脉冲宽度4 ns(FWHM),采用4f相位相干成像技术测定了PMPAK的三阶NLO性质并确定了相关参数:非线性折射率n2=-1.84 ×10-16 m2/W,非线性吸收系数β=2.53 ×10-9 m/W,非线性极化率x(3)=1.137×10-10 esu.

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