Fe基催化剂上二氧化碳加氢制C2+烃的研究进展

应用化学, 2016, 33(2): 123-132. doi: 10.11944/j.issn.1000-0518.2016.02.150431

Fe基催化剂上二氧化碳加氢制C2+烃的研究进展

丁凡舒 ^1, , 聂小娃 ^2, , 刘民 ^3, , 宋春山 ^4, , 郭新闻 ^5,

1.大连理工大学化工学院工业催化系,宾州-大连联合能源研究中心,精细化工国家重点实验室辽宁大连116024

2.大连理工大学化工学院工业催化系,宾州-大连联合能源研究中心,精细化工国家重点实验室辽宁大连116024

3.大连理工大学化工学院工业催化系,宾州-大连联合能源研究中心,精细化工国家重点实验室辽宁大连116024

4.大连理工大学化工学院工业催化系,宾州-大连联合能源研究中心,精细化工国家重点实验室辽宁大连116024;宾夕法尼亚州立大学能源研究所美国16802

5.大连理工大学化工学院工业催化系,宾州-大连联合能源研究中心,精细化工国家重点实验室辽宁大连116024

基金项目: the National Natural Science Foundation of China(21503029,21503027) 国家自然科学基金资助项目(21503029,21503027) the Fundamental Research Funds for the Central Universities(No.DUT15ZD236,No.DUT15RC(3)027) 中央高校基本科研业务费专项资金资助(DUT15ZD236,DUT15RC(3)027)

关键词：二氧化碳 , 催化加氢 , Fe基催化剂 , 烃类合成

Research Progress in Catalytic Conversion of Carbon Dioxide to C2+ Hydrocarbons over Fe-Based Catalysts

Keywords： carbon dioxide , hydrogenation , Fe-based catalyst , hydrocarbons synthesis

将二氧化碳(CO2)催化加氢转化为具有高附加值的烃类化合物,既可减缓大气中CO2浓度的攀升速度,又符合可持续发展战略,对环境和社会均具有重要意义.本文综述了Fe基催化剂上CO2加氢制C2+烃的研究进展,着重介绍了反应路径及机理、催化剂研制及反应器设计,展望了CO2制烃的研究前景.

参考文献

[1]	梁兵连;段洪敏;侯宝林;苏雄;黄延强;王爱琴;王晓东;张涛.二氧化碳加氢合成低碳烯烃的研究进展[J].化工进展,2015(10):3746-3754.
[2]	Iglesias, M.;de Vries, C.;Claeys, M.;Schaub, G..Chemical energy storage in gaseous hydrocarbons via iron Fischer-Tropsch synthesis from H-2/CO2-Kinetics, selectivity and process considerations[J].Catalysis Today,2015Pt.A(Pt.A):184-192.
[3]	Chunshan Song.Global challenges and strategies for control,conversion and utilization of CO_2 for sustainable development involving energy,catalysis,adsorption and chemical processing[J].Catalysis Today,20061/4(1/4):2-32.
[4]	Thomas Riedel;Georg Schaub;Ki-Won Jun;Kyu-Wan Lee.Kinetics of CO_2 Hydrogenation on a K-Promoted Fe Catalyst[J].Industrial & Engineering Chemistry Research,20015(5):1355-1363.
[5]	Qingquan Lin;Xiao Yan Liu;Ying Jiang.Crystal phase effects on the structure and performance of ruthenium nanoparticles for CO2 hydrogenation[J].Catalysis science & technology,20147(7):2058-2063.
[6]	Owen, R.E.;O'Byrne, J.P.;Mattia, D.;Plucinski, P.;Pascu, S.I.;Jones, M.D..Cobalt catalysts for the conversion of CO_2 to light hydrocarbons at atmospheric pressure[J].Chemical communications,201399(99):11683-11685.
[7]	刘业奎;王黎;侯栋;万华;冯霄.二氧化碳加氢合成低碳烯烃反应平衡体系热力学研究[J].催化学报,2004(3):210-218.
[8]	Wang, L.C.;Tahvildar Khazaneh, M.;Widmann, D.;Behm, R.J..TAP reactor studies of the oxidizing capability of CO_2 on a Au/CeO_2 catalyst-A first step toward identifying a redox mechanism in the Reverse Water-Gas Shift reaction[J].Journal of Catalysis,2013:20-30.
[9]	何孝祥;顾雄毅;范琛;朱贻安.Fe3O4表面逆水煤气反应的DFT研究[J].华东理工大学学报：自然科学版,2011(4):424-429.
[10]	Sung-Chul Lee;Jun-Sik Kim;Woo Cheol Shin.Catalyst deactivation during hydrogenation of carbon dioxide: Effect of catalyst position in the packed bed reactor[J].Journal of molecular catalysis, A. Chemical,20091/2(1/2):98-105.
[11]	John M. H. Lo;Tom Ziegler.A First-Principle Study of Chain Propagation Steps in the Fischer-Tropsch Synthesis on Fe(100)[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200835(35):13681-13691.
[12]	Jong Wook Bae;Seon-Ju Park;Yun-Jo Lee.Effects of Reaction Variables on Fischer-Tropsch Synthesis with Co-Precipitated K/FeCeAlO_x Catalysts[J].Catalysis Letters,20116(6):799-807.
[13]	Mingyue Ding;Yong Yang;Baoshan Wu.Transformation of carbonaceous species and its influence on catalytic performance for iron-based Fischer-Tropsch synthesis catalyst[J].Journal of molecular catalysis, A. Chemical,2011:165-173.
[14]	De Smit, E.;Cinquini, F.;Beale, A.M.;Safonova, O.V.;Van Beek, W.;Sautet, P.;Weckhuysen, B.M..Stability and reactivity of ε-Χ-θ iron carbide catalyst phases in fischer-tropsch synthesis: Controlling μ_c[J].Journal of the American Chemical Society,201042(42):14928-14941.
[15]	Mogorosi, R.P.;Fischer, N.;Claeys, M.;Van Steen, E..Strong-metal-support interaction by molecular design: Fe-silicate interactions in Fischer-Tropsch catalysts[J].Journal of Catalysis,2012:140-150.
[16]	Yang, C.;Zhao, H.;Hou, Y.;Ma, D..Fe _5C _2 nanoparticles: A facile bromide-induced synthesis and as an active phase for Fischer-Tropsch synthesis[J].Journal of the American Chemical Society,201238(38):15814-15821.
[17]	侯文娟;吴宝山;安霞;李廷真;相宏伟;李永旺.浆态床F-T合成Fe/Cu/K/SiO2催化剂中K助剂作用的研究[J].燃料化学学报,2008(2):186-191.
[18]	Kangkai Liu;Haiyun Suo;Chenghua Zhang.An active Fischer-Tropsch synthesis FeMo/SiO2 catalyst prepared by a modified sol-gel technique[J].Catalysis Communications,20102(2):137-141.
[19]	Fischer-tropsch Synthesis By Carbon Dioxide Hydrogenation On Fe-based Catalysts[J].Catalysis surveys from Asia,20083(3):170.
[20]	赵乐.Fischer-Tropsch合成铁基催化剂研究进展[J].浙江工业大学学报,2008(06):642-646.
[21]	Hou, WJ;Wu, BS;An, X;Li, TZ;Tao, ZC;Zheng, HY;Xiang, HW;Li, YW.Effect of the ratio of precipitated SiO2 to binder SiO2 on iron-based catalysts for Fischer-Tropsch synthesis[J].Catalysis Letters,20073/4(3/4):353-360.
[22]	Yan SR.;Hong JS.;Choi MJ.;Lee KW.;Jun KW..Promotion effect of Fe-Cu catalyst for the hydrogenation of CO2 and application to slurry reactor[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2000Special Issue SI(Special Issue SI):63-70.
[23]	Jingjuan Wang;Zhenya You;Qinghong Zhang.Synthesis of lower olefins by hydrogenation of carbon dioxide over supported iron catalysts[J].Catalysis Today,2013:186-193.
[24]	丁凡舒 .二氧化碳加氢合成C5+烃反应中铁基催化剂的性能研究[D].大连理工大学,2014.
[25]	Tingzhen Li;Yong Yang;Chenghua Zhang;Xia An;Haijun Wan;Zhichao Tao;Hongwei Xiang;Yongwang Li;Fan Yi;Binfu Xu.Effect of manganese on an iron-based Fischer-Tropsch synthesis catalyst prepared from ferrous sulfate[J].Fuel,20077/8(7/8):921-928.
[26]	Li SZ.;Krishnamoorthy S.;Li AW.;Meitzner GD.;Iglesia E..Promoted iron-based catalysts for the Fischer-Tropsch synthesis: Design, synthesis, site densities, and catalytic properties[J].Journal of Catalysis,20022(2):202-217.
[27]	King DL;Faz C.Desulfurization of Tier 2 gasoline by divalent copper-exchanged zeolite Y[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,20060(0):58-65.
[28]	郑斌;张安峰;刘民;丁凡舒;代成义;宋春山;郭新闻.纳米铁基催化剂在CO2加氢制烃中的性能[J].物理化学学报,2012(8):1943-1950.
[29]	Hans Schulz;Thomas Riedel;Georg Schaub.Fischer-Tropsch principles of co-hydrogenation on iron catalysts[J].Topics in Catalysis,20053/4(3/4):117-124.
[30]	章素;王承玉;潘立金;蔡海林;梁东白;林励吾.57Fe穆斯堡尔谱研究费-托合成铁催化剂Ⅰ.担载型铁催化剂制备条件的考察[J].燃料化学学报,1988(04):289-297.
[31]	白荣献;谭猗生;韩怡卓.Fe-Zn-Zr/分子筛复合催化剂上CO2加氢合成异构烷烃Ⅰ.不同分子筛对催化剂性能的影响[J].催化学报,2004(3):223-226.
[32]	李捷 .碳材料负载Fe催化CO2加氢制烃类的研究[D].大连理工大学,2014.
[33]	慕灯友 .Fe@C催化二氧化碳加氢制烃类的研究[D].大连理工大学,2014.
[34]	Jun-Sik Kim;Sunmook Lee;Sang-Bong Lee;Myoung-Jae Choi;Kyu-Wan Lee.Performance of catalytic reactors for the hydrogenation of CO_2 to hydrocarbons[J].Catalysis Today,20061/4(1/4):228-234.
[35]	Satthawong, Ratchprapa;Koizumi, Naoto;Song, Chunshan;Prasassarakich, Pattarapan.Light olefin synthesis from CO2 hydrogenation over K-promoted Fe-Co bimetallic catalysts[J].Catalysis Today,2015:34-40.
[36]	Ratchprapa Satthawong;Naoto Koizumi;Chunshan Song.Comparative Study on CO2 Hydrogenation to Higher Hydrocarbons over Fe-Based Bimetallic Catalysts[J].Topics in Catalysis,20146/9(6/9):588-594.
[37]	M. Farsi;A. Jahanmiri.Application of water vapor-permselective alumina-silica composite membrane in methanol synthesis process to enhance CO2 hydrogenation and catalyst life time[J].Journal of industrial and engineering chemistry,20123(3):1088-1095.

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