由于有机磷阻燃剂具有高效、低毒、无污染及无烟等特点,该领域的研究在国内外得到极大的关注,已经在合成和应用等方面取得了显著成就.本文对磷系阻燃剂的阻燃机理及近年来磷系阻燃剂的应用进展作了简要综述.分别综述了各类有机含磷阻燃剂的研究进展,并提出了有机磷阻燃剂今后的发展方向.
参考文献
| [1] | Ravey M.;Keidar I.;Pearce EM.;Weil ED..Flexible polyurethane foam. II. Fire retardation by tris(1,3-dichloro-2-propyl) phosphate. Part B. Examination of the condensed phase (the pyrolysis zone)[J].Journal of Applied Polymer Science,19982(2):231-254. |
| [2] | Nishihara H.;Kanatani R.;Tanji S..Interactions between phosphorus- and nitrogen-containing flame retardants[J].Polymer Journal,19983(3):163-167. |
| [3] | Mandal H.;Hay AS..Polycyclic phosphonate resins: Thermally cross-linkable intermediates for flame-retardant materials[J].Journal of Polymer Science, Part A. Polymer Chemistry,199811(11):1911-1918. |
| [4] | Liu YL.;Chiu YS.;Jeng RJ.;Ma C.;Hsiue GH..SYNTHESIS AND FLAME-RETARDANT PROPERTIES OF PHOSPHORUS-CONTAINING POLYMERS BASED ON POLY(4-HYDROXYSTYRENE)[J].Journal of Applied Polymer Science,199610(10):1619-1625. |
| [5] | Ma ZL.;Liu YF.;Shi JR.;Zhao WG..SYNTHESIS AND PROPERTIES OF INTUMESCENT, PHOSPHORUS-CONTAINING, FLAME-RETARDANT POLYESTERS[J].Journal of Applied Polymer Science,199712(12):1511-1515. |
| [6] | Sponton, M;Ronda, JC;Galila, M;Cadiz, V.Cone calorimetry studies of benzoxazine-epoxy systems flame retarded by chemically bonded phosphorus or silicon[J].Polymer Degradation and Stability,20091(1):102-106. |
| [7] | Guo, Y.-N.;Qiu, J.-J.;Tang, H.-Q.;Liu, C.-M..High transmittance and environment-friendly flame-resistant optical resins based on poly(methyl methacrylate) and cyclotriphosphazene derivatives[J].Journal of Applied Polymer Science,20112(2):727-734. |
| [8] | Chuan Shao Wu;Ying Ling Liu;Yie Shung Chiu.Epoxy resins possessing flame retardant elements from silicon incorporated epoxy compounds cured with phosphorus or nitrogen containing curing agents[J].Polymer: The International Journal for the Science and Technology of Polymers,200215(15):4277-4284. |
| [9] | Liu YA;Wang Q.Reactive extrusion to synthesize intumescent flame retardant with a solid acid as catalyst and the flame retardancy of the products in polypropylene[J].Journal of Applied Polymer Science,20081(1):14-20. |
| [10] | Matuschek G..THERMAL DEGRADATION OF DIFFERENT FIRE RETARDANT POLYURETHANE FOAMS[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,19950(0):59-71. |
| [11] | Aleksandr A. Kapura.Chemistry of Flame Retardants: Ⅲ. Aging of N-Methylol-3-dimethoxyphosphorylpropionamide and Commercial Flame Retardants for Fabrics Containing This Substance[J].Journal of fire sciences,19963(3):169-185. |
| [12] | 辛菲.无卤阻燃剂间苯二酚双（二苯基）磷酸酯的合成及表征[J].化工新型材料,2011(07):123-125. |
| [13] | 付全军;王辛龙;张志业;周健;黎金霞;钟本和;杨林.磷酸酯阻燃剂HDP的合成工艺及其在ABS中的阻燃作用[J].高分子学报,2013(2):166-173. |
| [14] | 方科益;李娟;柯晨皓;朱琦良;陶慷;严庆;王玉忠.超支化聚磷酸酯阻燃剂对尼龙6的成炭促进作用[J].高分子学报,2011(1):55-62. |
| [15] | 毋登辉;赵培华;张美;刘亚青;李天凯;廖登雄.新型单组分磷-氮膨胀型阻燃剂的合成及其阻燃性能[J].合成化学,2013(5):530-533. |
| [16] | Enescu, D.;Frache, A.;Lavaselli, M.;Monticelli, O.;Marino, F..Novel phosphorous-nitrogen intumescent flame retardant system. Its effects on flame retardancy and thermal properties of polypropylene[J].Polymer Degradation and Stability,20131(1):297-305. |
| [17] | 钟柳;刘治国;欧育湘.新型含卤磷酸酯阻燃剂的合成、表征和应用[J].塑料,2008(5):27-30. |
| [18] | 卢林刚;周霞;赵敏;唐凯.阻燃剂二（5,5-二溴甲基-1,3,2-二氧六环磷酰）双酚A的合成[J].化学研究与应用,2009(12):1667-1670. |
| [19] | 王会娅;周霞;王永明;努娜;唐宝华.新型单组分磷溴协效阻燃剂1,3-二（5,5-二溴甲基-1,3-二氧杂己内磷酰氧基）苯的合成[J].化学试剂,2010(1):52-54,76. |
| [20] | 马志领;崔海香;张娇娇;刘平;王建勋.膨胀型阻燃剂二溴新戊二醇磷酸酯三聚氰胺盐的合成及应用[J].河北大学学报（自然科学版）,2008(3):258-262. |
| [21] | Congtranh Nguyen;Jinhwan Kim.Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS[J].Macromolecular Research,20087(7):620-625. |
| [22] | 王丹;周浩;职慧珍;杨锦飞.无卤阻燃剂1,2-亚乙基双膦酸四甲酯的合成[J].精细化工,2011(4):389-392. |
| [23] | Fan, R. L.;Guo, L.;Wang, P. Z.;Chen, S. F.;Bian, Z. X..Synthesis and Solubilities of 3,9-Dipyrolidino-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane-3,9-dioxide in Selected Solvents[J].Chemical Engineering Communications,20151/3(1/3):96-101. |
| [24] | Lin, HT;Lin, CH;Hu, YM;Su, WC.An approach to develop high-Tg epoxy resins for halogen-free copper clad laminates[J].Polymer: The International Journal for the Science and Technology of Polymers,200924(24):5685-5692. |
| [25] | Hoang D;Kim J;Jang BN.Synthesis and performance of cyclic phosphorus-containing flame retardants[J].Polymer Degradation and Stability,200811(11):2042-2047. |
| [26] | Karatas, S;Hosgor, Z;Kayaman-Apohan, N;Gungor, A.Preparation and characterization of phosphine oxide containing organosilica hybrid coatings by photopolymerization and sol-gel process[J].Progress in Organic Coatings: An International Review Journal,20091(1):49-55. |
| [27] | K SHREE MEENAKSHI;E PRADEEP JAYA SUDHAN;S ANANDA KUMAR.Development and characterization of new phosphorus based flame retardant tetraglycidyl epoxy nanocomposites for aerospace application[J].Bulletin of Materials Science,20122(2):129-136. |
| [28] | YANG XIAO FENG;LI QIAO LING;CHEN ZHI PING.Study on crystallization behaviour of co-polyamide 66 containing triaryl phosphine oxide[J].Bulletin of Materials Science,20122(2):233-242. |
| [29] | R.Rajasekaran;C.Karikalchozhan;M.Alagar.Preparation and Characterization of 3,3-bis (maleimidophenyl)phenylphosphine Oxide (BMI)/ Polysulfone Modified Epoxy Intercrosslinked Matrices[J].Polymer Composites,20087(7):773-781. |
| [30] | Hua Ren;Jianzhong Sun;Binjie Wu;Qiyun Zhou.Synthesis and properties of a phosphorus-containing flame retardant epoxy resin based on bis-phenoxy (3-hydroxy) phenyl phosphine oxide[J].Polymer Degradation and Stability,20076(6):956-961. |
| [31] | Schafer A;Seibold S;Lohstroh W;Walter O;Doring M.Synthesis and properties of flame-retardant epoxy resins based on DOPO and one of its analog DPPO[J].Journal of Applied Polymer Science,20072(2):685-696. |
| [32] | Vasiljevic, Jelena;Jerman, Ivan;Jaksa, Gregor;Alongi, Jenny;Malucelli, Giulio;Zorko, Milena;Tomsic, Brigita;Simoncic, Barbara.Functionalization of cellulose fibres with DOPO-polysilsesquioxane flame retardant nanocoating[J].Cellulose,20153(3):1893-1910. |
| [33] | Sablong, R.;Duchateau, R.;Koning, C.E.;Pospiech, D.;Korwitz, A.;Komber, H.;Starke, S.;H?u?ler, L.;Jehnichen, D.;Auf Der Landwehr, M..Incorporation of a flame retardancy enhancing phosphorus-containing diol into poly(butylene terephthalate) via solid state polycondensation: A comparative study[J].Polymer Degradation and Stability,20113(3):334-341. |
| [34] | Doris Pospiech;Liane HauBler;Andreas Korwitz.The miscibility of poly(butylene terephthalate) (PBT) with phosphorus polyester flame retardants[J].High performance polymers,20121(1):64-73. |
| [35] | Fischer, O.;Pospiech, D.;Korwitz, A.;Sahre, K.;H?u?ler, L.;Friedel, P.;Fischer, D.;Harnisch, C.;Bykov, Y.;D?ring, M..Synthesis and properties of phosphorus polyesters with systematically altered phosphorus environment[J].Polymer Degradation and Stability,201112(12):2198-2208. |
| [36] | 卢林刚;王晓;杨守生;董希琳;唐凯;余厚珺.新型树状单分子磷-氮膨胀阻燃剂的合成及阻燃性能研究[J].化学学报,2012(2):190-194. |
| [37] | 卢林刚;王晓;杨守生;董希琳;陈英辉;唐凯.单组分磷-氮膨胀阻燃剂的合成及成炭性能[J].高分子材料科学与工程,2012(07):10-13. |
| [38] | Lijun Qian;Fafei Feng;Shuo Tang.Bi-phase flame-retardant effect of hexa-phenoxy-cyclotriphosphazene on rigid polyurethane foams containing expandable graphite[J].Polymer: The International Journal for the Science and Technology of Polymers,20141(1):95-101. |
| [39] | Qian, L.-J.;Ye, L.-J.;Xu, G.-Z.;Liu, J.;Guo, J.-Q..The non-halogen flame retardant epoxy resin based on a novel compound with phosphaphenanthrene and cyclotriphosphazene double functional groups[J].Polymer Degradation and Stability,20116(6):1118-1124. |
| [40] | Perret, B.;Schartel, B.;St??, K.;Ciesielski, M.;Diederichs, J.;D?ring, M.;Kr?mer, J.;Altst?dt, V..Novel DOPO-based flame retardants in high-performance carbon fibre epoxy composites for aviation[J].European Polymer Journal,20115(5):1081-1089. |
| [41] | Zhao CS;Huang FL;Xiong WC;Wang YZ.A novel halogen-free flame retardant for glass-fiber-reinforced poly(ethylene terephthalate)[J].Polymer Degradation and Stability,20086(6):1188-1193. |
| [42] | Zhang, X.;Zhong, Y.;Mao, Z.-P..The flame retardancy and thermal stability properties of poly (ethylene terephthalate)/hexakis (4-nitrophenoxy) cyclotriphosphazene systems[J].Polymer Degradation and Stability,20128(8):1504-1510. |
| [43] | 班大明;刘吉平.聚苯基磷酸间苯二酚酯的合成、表征及热性能[J].高等学校化学学报,2013(5):1284-1287. |
| [44] | Wang, X.;Hu, Y.;Song, L.;Yang, H.;Xing, W.;Lu, H..Synthesis and characterization of a DOPO-substitued organophosphorus oligomer and its application in flame retardant epoxy resins[J].Progress in Organic Coatings: An International Review Journal,20111(1):72-82. |
| [45] | Zhou, Cheng;Wei, Zhiyong;Yu, Yang;Li, Yang.Synthesis and crystallization behavior of novel poly(butylene succinate) copolyesters containing phosphorus pendent groups[J].Journal of thermal analysis and calorimetry,20153(3):1799-1810. |
| [46] | Li Chen;Chao Ruan;Rong Yang.Phosphorus-containing thermotropic liquid crystalline polymers: a class of efficient polymeric flame retardants[J].Polymer chemistry,201412(12):3737-3749. |
| [47] | 杜大江;曹芳利;陈佳;刘继延.磷-氮协效型烷基次膦酸盐阻燃剂的合成及其在PBT中的应用[J].江汉大学学报（自然科学版）,2015(1):19-23. |
| [48] | 徐建中;刘欣;屈红强;王春征.次磷酸盐阻燃剂的合成及其在PBT中的应用[J].塑料科技,2013(11):90-95. |
| [49] | Chen, L.;Luo, Y.;Hu, Z.;Lin, G.-P.;Zhao, B.;Wang, Y.-Z..An efficient halogen-free flame retardant for glass-fibre-reinforced poly(butylene terephthalate)[J].Polymer Degradation and Stability,20122(2):158-165. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%