欢迎登录材料期刊网

材料期刊网

高级检索

碳量子点(carbon quantum dots,CQDs)作为碳纳米材料家族的新成员引起了科学家广泛关注和极大的研究兴趣.CQDs具有优良的光学特性、生物相容性及微弱的细胞毒性,在生物医药、生物传感器及光电子设备、环境及能源等领域中具有重要的应用.本文从CQDs的制备方法出发,介绍了近年来发展的新型制备方法,讨论了其优缺点以及对所得CQDs在组成、结构和性质等方面的影响;基于CQDs独特的光学及电化学性能,重点介绍了CQDs在环境与能源领域的应用.此外,对CQDs研究过程中存在的若干挑战进行了分析,提出了未来发展的一些思考和建议,为拓展CQDs多方面应用提供重要参考.

参考文献

[1] Xiaoyou Xu;Robert Ray;Harry J.Pleohn;Latha Gearheart.Electrophoretic Analysis and Purification of Fluorescent Single-Walled Carbon Nanotube Fragments[J].Journal of the American Chemical Society,200440(40):12736-12737.
[2] Ya-Ping Sun;Bing Zhou;Yi Lin;Wei Wang;K.A.Shiral Fernando.Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence[J].Journal of the American Chemical Society,200624(24):7756-7757.
[3] Lim, Shi Ying;Shen, Wei;Gao, Zhiqiang.Carbon quantum dots and their applications[J].Chemical Society Reviews,20151(1):362-381.
[4] Haitao Li;Zhenhui Kang;Yang Liu.Carbon nanodots: synthesis, properties and applications[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201246(46):24230-24253.
[5] 刘畅;成会明.电弧放电法制备纳米碳管[J].新型炭材料,2001(1):67-71.
[6] Massimo Bottini;Chidambara Balasubramanian;Marcia I.Daw son;Antonio Bergamaschi;Stefano Bellucci.Isolation and Characterization of Fluorescent Nanoparticles from Pristine and Oxidized Electric Arc-Produced Single-Walled Carbon Nanotubes[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,20062(2):831-836.
[7] Xu, J.;Sahu, S.;Cao, L.;Anilkumar, P.;Tackett II, K.N.;Qian, H.;Bunker, C.E.;Guliants, E.A.;Parenzan, A.;Sun, Y.-P..Carbon nanoparticles as chromophores for photon harvesting and photoconversion[J].Chemphyschem: A European journal of chemical physics and physical chemistry,201218(18):3604-3608.
[8] Xiaoming Wen;Pyng Yu;Yon-Rui Toh;Xiaoqian Ma;Jau Tang.On the upconversion fluorescence in carbon nanodots and graphene quantum dots[J].Chemical communications,201436(36):4703-4706.
[9] Cao L;Wang X;Meziani MJ;Lu FS;Wang HF;Luo PJG;Lin Y;Harruff BA;Veca LM;Murray D.Carbon dots for multiphoton bioimaging[J].Journal of the American Chemical Society,200737(37):11318-11319.
[10] 吴旭峰;凌一鸣.激光烧蚀法制备准一维纳米材料[J].激光技术,2005(6):575-578.
[11] Sheng-Liang Hu;Kai-Yang Niu;Jing Sun.One-step synthesis of fluorescent carbon nanoparticles by laser irradiation[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,20094(4):484-488.
[12] Li, X.;Wang, H.;Shimizu, Y.;Pyatenko, A.;Kawaguchi, K.;Koshizaki, N..Preparation of carbon quantum dots with tunable photoluminescence by rapid laser passivation in ordinary organic solvents[J].Chemical communications,20113(3):932-934.
[13] S. C. Ray;Arindam Saha;Nikhil R. Jana.Fluorescent Carbon Nanoparticles: Synthesis, Characterization, and Bioimaging Application[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200943(43):18546-18551.
[14] Lei Tian;Debraj Ghosh;Wei Chen.Nanosized Carbon Particles From Natural Gas Soot[J].Chemistry of Materials: A Publication of the American Chemistry Society,200913(13):2803-2809.
[15] Yongqiang Dong;Nana Zhou;Xiaomei Lin.Extraction of Electrochemiluminescent Oxidized Carbon Quantum Dots from Activated Carbon[J].Chemistry of Materials: A Publication of the American Chemistry Society,201021(21):5895-5899.
[16] Siwei Yang;Jing Sun;Xiubing Li.Large-scale fabrication of heavy doped carbon quantum dots with tunable-photoluminescence and sensitive fluorescence detection[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201423(23):8660-8667.
[17] Jigang Zhou;Christina Booker;Ruying Li.An Electrochemical Avenue to Blue Luminescent Nanocrystals from Multiwalled Carbon Nanotubes (MWCNTs)[J].Journal of the American Chemical Society,20074(4):744-745.
[18] Zheng, LY;Chi, YW;Dong, YQ;Lin, JP;Wang, BB.Electrochemiluminescence of Water-Soluble Carbon Nanocrystals Released Electrochemically from Graphite[J].Journal of the American Chemical Society,200913(13):4564-4566.
[19] Lei Bao;Zhi-Ling Zhang;Zhi-Quan Tian;Li Zhang;Cui Liu;Yi Lin;Baoping Qi;Dai-Wen Pang.Electrochemical Tuning of Luminescent Carbon Nanodots: From Preparation to Luminescence Mechanism[J].Advanced Materials,201148(48):5801-5806.
[20] Lu, J.;Yang, J.-X.;Wang, J.;Lim, A.;Wang, S.;Loh, K.P..One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids[J].ACS nano,20098(8):2367-2375.
[21] Li, Xuehua;Zhao, Zhiwei.Facile ionic-liquid-assisted electrochemical synthesis of size-controlled carbon quantum dots by tuning applied voltages[J].RSC Advances,2014101(101):57615-57619.
[22] Zhao QL;Zhang ZL;Huang BH;Peng J;Zhang M;Pang DW.Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite[J].Chemical communications,200841(41):5116-5118.
[23] Hou, Yuxin;Lu, Qiujun;Deng, Jianhui;Li, Haitao;Zhang, Youyu.One-pot electrochemical synthesis of functionalized fluorescent carbon dots and their selective sensing for mercury ion[J].Analytica chimica acta,2015:69-74.
[24] Athanasios B. Bourlinos;Jan Petr;Radek Zboril.Luminescent Surface Quaternized Carbon Dots[J].Chemistry of Materials: A Publication of the American Chemistry Society,20121(1):6-8.
[25] Pan, D.;Zhang, J.;Li, Z.;Wu, C.;Yan, X.;Wu, M..Observation of pH-, solvent-, spin-, and excitation-dependent blue photoluminescence from carbon nanoparticles[J].Chemical communications,201021(21):3681-3683.
[26] Fu Wang;Maximilian Kreiter;Bo He;Shuping Pang;Chun-yan Liu.Synthesis of direct white-light emitting carbogenic quantum dots[J].Chemical communications,201019(19):3309-3311.
[27] Fu Wang;Zheng Xie;Hao Zhang;Chun-yan Liu;Ying-ge Zhang.Highly Luminescent Organosilane-Functionalized Carbon Dots[J].Advanced functional materials,20116(6):1027-1031.
[28] 赵希强;宋占龙;王涛;李龙之;马春元.微波技术用于热解的研究进展[J].化工进展,2008(12):1873-1877,1881.
[29] Zhu, H;Wang, XL;Li, YL;Wang, ZJ;Yang, F;Yang, XR.Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties[J].Chemical communications,200934(34):5118-5120.
[30] Changjun Liu;Peng Zhang;Feng Tian.One-step synthesis of surface passivated carbon naeodots by microwave assisted pyrolysis for enhanced multicolor photoluminescence and bioimaging[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201135(35):13163-13167.
[31] Jaiswal, A.;Ghosh, S.S.;Chattopadhyay, A..One step synthesis of C-dots by microwave mediated caramelization of poly(ethylene glycol)[J].Chemical communications,20123(3):407-409.
[32] 胡亚楠;赵荣祥;李秀萍.超声法制备纳米材料的研究进展[J].当代化工,2013(11):1565-1567.
[33] Haitao Li;Xiaodie He;Yang Liu;Hang Yu;Zhenhui Kang;Shuit-Tong Lee.Synthesis of fluorescent carbon nanoparticles directly from active carbon via a one-step ultrasonic treatment[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,20111(1):147-151.
[34] Haitao Li;Xiaodie He;Yang Liu.One-step ultrasonic synthesis of water-soluble carbon nanoparticles with excellent photoluminescent properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,20112(2):605-609.
[35] Tao, H.;Yang, K.;Ma, Z.;Wan, J.;Zhang, Y.;Kang, Z.;Liu, Z..In vivo NIR fluorescence imaging, biodistribution, and toxicology of photoluminescent carbon dots produced from carbon nanotubes and graphite[J].Small,20122(2):281-290.
[36] Zhang, B.;Liu, C.-Y.;Liu, Y..A novel one-step approach to synthesize fluorescent carbon nanoparticles[J].European journal of inorganic chemistry,201028(28):4411-4414.
[37] Zhu, C.;Zhai, J.;Dong, S..Bifunctional fluorescent carbon nanodots: Green synthesis via soy milk and application as metal-free electrocatalysts for oxygen reduction[J].Chemical communications,201275(75):9367-9369.
[38] Sahu, S.;Behera, B.;Maiti, T.K.;Mohapatra, S..Simple one-step synthesis of highly luminescent carbon dots from orange juice: Application as excellent bio-imaging agents[J].Chemical communications,201170(70):8835-8837.
[39] Mehta, Vaibhavkumar N.;Jha, Sanjay;Basu, Hirakendu;Singhal, Rakesh Kumar;Kailasa, Suresh Kumar.One-step hydrothermal approach to fabricate carbon dots from apple juice for imaging of mycobacterium and fungal cells[J].Sensors and Actuators, B. Chemical,2015:434-443.
[40] Zhu Lian Wu;Pu Zhang;Ming Xuan Gao.One-pot hydrothermal synthesis of highly luminescent nitrogen-doped amphoteric carbon dots for bioimaging from Bombyx mori silk - natural proteins[J].Journal of Materials Chemistry, B. materials for biology and medicine,201322(22):2868-2873.
[41] 余正发;王旭珍;刘宁;刘洋.N掺杂多孔碳材料研究进展[J].化工进展,2013(4):824-831,862.
[42] Li, Zi;Yu, Huijun;Bian, Tong;Zhao, Yufei;Zhou, Chao;Shang, Lu;Liu, Yanhui;Wu, Li-Zhu;Tung, Chen-Ho;Zhang, Tierui.Highly luminescent nitrogen-doped carbon quantum dots as effective fluorescent probes for mercuric and iodide ions[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,20159(9):1922-1928.
[43] Fang, Y.;Guo, S.;Li, D.;Zhu, C.;Ren, W.;Dong, S.;Wang, E..Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles[J].ACS nano,20121(1):400-409.
[44] Srivastava, S.;Gajbhiye, N.S..Carbogenic nanodots: Photoluminescence and room-temperature ferromagnetism[J].Chemphyschem: A European journal of chemical physics and physical chemistry,201114(14):2624-2632.
[45] Goki Eda;Yun-Yue Lin;Cecilia Mattevi;Hisato Yamaguchi;Hsin-An Chen;I-Sheng Chen;Chun-Wei Chen;Manish Chhowalla.Blue Photoluminescence from Chemically Derived Graphene Oxide[J].Advanced Materials,20104(4):505-509.
[46] Dengyu Pan;Jingchun Zhang;Zhen Li;Minghong Wu.Hydrothermal Route for Cutting Graphene Sheets into Blue-Luminescent Graphene Quantum Dots[J].Advanced Materials,20106(6):734-738.
[47] Hui Ding;Li-Wei Cheng;Ying-Ying Ma.Luminescent carbon quantum dots and their application in cell imaging[J].New Journal of Chemistry,20138(8):2515-2520.
[48] Yan, H.;Tan, M.;Zhang, D.;Cheng, F.;Wu, H.;Fan, M.;Ma, X.;Wang, J..Development of multicolor carbon nanoparticles for cell imaging[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2013:59-65.
[49] Yang, ST;Cao, L;Luo, PGJ;Lu, FS;Wang, X;Wang, HF;Meziani, MJ;Liu, YF;Qi, G;Sun, YP.Carbon Dots for Optical Imaging in Vivo[J].Journal of the American Chemical Society,200932(32):11308-11309.
[50] Xiaoyong Zhang;Shiqi Wang;Liangxin Xu.Biocompatible polydopamine fluorescent organic nanoparticles: facile preparation and cell imaging[J].Nanoscale,201218(18):5581-5584.
[51] Han, B.;Wang, W.;Wu, H.;Fang, F.;Wang, N.;Zhang, X.;Xu, S..Polyethyleneimine modified fluorescent carbon dots and their application in cell labeling[J].Colloids and Surfaces, B. Biointerfaces,2012:209-214.
[52] Karthik, S.;Saha, B.;Ghosh, S.K.;Pradeep Singh, N.D..Photoresponsive quinoline tethered fluorescent carbon dots for regulated anticancer drug delivery[J].Chemical communications,201389(89):10471-10473.
[53] Yan Li;Yue Hu;Yang Zhao;Caoquan Shi;Lier Deng;Yanbing Hou;Liangti Qu.An Electrochemical Avenue to Green-Luminescent Graphene Quantum Dots as Potential Electron-Acceptors for Photovoltaics[J].Advanced Materials,20116(6):776-780.
[54] Xia YS;Zhu CQ.Use of surface-modified CdTe quantum dots as fluorescent probes in sensing mercury (II)[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,20081(1):215-221.
[55] Zhou, L.;Lin, Y.;Huang, Z.;Ren, J.;Qu, X..Carbon nanodots as fluorescence probes for rapid, sensitive, and label-free detection of Hg ~(2+) and biothiols in complex matrices[J].Chemical communications,20128(8):1147-1149.
[56] Lu, Ya-Chun;Chen, Jia;Wang, Ai-Jun;Bao, Ning;Feng, Jiu-Ju;Wang, Weiping;Shao, Linxiang.Facile synthesis of oxygen and sulfur co-doped graphitic carbon nitride fluorescent quantum dots and their application for mercury(II) detection and bioimaging[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,20151(1):73-78.
[57] Xu, Jinjin;Lai, Tiantian;Feng, Zhiling;Weng, Xuexiang;Huang, Chaobiao.Formation of fluorescent carbon nanodots from kitchen wastes and their application for detection of Fe3+[J].Luminescence: The journal of biological and chemical luminescence,20154(4):420-424.
[58] Sen Liu;Jingqi Tian;Lei Wang;Yingwei Zhang;Xiaoyun Qin;Yonglan Luo;Abdullah M.Asiri;Abdulrahman O.Al-Youbi;Xuping Sun.Hydrothermal Treatment of Crass: A Low-Cost, Green Route to Nitrogen-Doped, Carbon-Rich, Photoluminescent Polymer Nanodots as an Effective Fluorescent Sensing Platform for Label-Free Detection of Cu(ll) Ions[J].Advanced Materials,201215(15):2037-2041.
[59] Li, Yancai;Zhong, Yanmei;Zhang, Yayun;Weng, Wen;Li, Shunxing.Carbon quantum dots/octahedral Cu2O nanocomposites for non-enzymatic glucose and hydrogen peroxide amperometric sensor[J].Sensors and Actuators, B. Chemical,2015:735-743.
[60] Xing Zhang;Fang Wang;Hui Huang.Carbon quantum dot sensitized TiO2 nanotube arrays for photoelectrochemical hydrogen generation under visible lightt[J].Nanoscale,20136(6):2274-2278.
[61] Linlin Peng;Tengfeng Xie;Yongchun Lu.Synthesis, photoelectric properties and photocatalytic activity of the Fe2O3/TiO2 heterogeneous photocatalysts[J].Physical chemistry chemical physics: PCCP,201028(28):8033-8041.
[62] Zhang, H.;Ming, H.;Lian, S.;Huang, H.;Li, H.;Zhang, L.;Liu, Y.;Kang, Z.;Lee, S.-T..Fe_2O_3/carbon quantum dots complex photocatalysts and their enhanced photocatalytic activity under visible light[J].Dalton transactions: An international journal of inorganic chemistry,201141(41):10822-10825.
[63] Hengchao Zhang;Hui Huang;Hai Ming.Carbon quantum dots/Ag3PO4 complex photocatalysts with enhanced photocatalytic activity and stability under visible light[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201221(21):10501-10506.
[64] Hang Yu;Hengchao Zhang;Hui Huang.ZnO/carbon quantum dots nanocomposites: one-step fabrication and superior photocatalytic ability for toxic gas degradation under visible light at room temperature[J].New Journal of Chemistry,20124(4):1031-1035.
[65] 王维大;李浩然;冯雅丽;唐新华;杜竹玮;杜云龙.微生物燃料电池的研究应用进展[J].化工进展,2014(5):1067-1076.
[66] Bo, Xiangjie;Li, Mian;Han, Ce;Zhang, Yufan;Nsabimana, Anaclet;Guo, Liping.Noble metal-free electrocatalysts for the oxygen reduction reaction based on iron and nitrogen-doped porous graphene[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20153(3):1058-1067.
[67] Yanmei Yang;Juan Liu;Yuzhi Han.Porous cobalt, nitrogen-codoped carbon nanostructures from carbon quantum dots and VB12 and their catalytic properties for oxygen reduction[J].Physical chemistry chemical physics: PCCP,201446(46):25350-25357.
[68] Hu, Chao;Yu, Chang;Li, Mingyu;Wang, Xiuna;Dong, Qiang;Wang, Gang;Qiu, Jieshan.Nitrogen-doped carbon dots decorated on graphene: a novel all-carbon hybrid electrocatalyst for enhanced oxygen reduction reaction[J].Chemical communications,201516(16):3419-3422.
[69] 杨健茂;胡向华;田启威;唐明华;陈志钢;查刘生.量子点敏化太阳能电池研究进展[J].材料导报,2011(23):1-4.
[70] 郑皓源.量子点敏化太阳能电池研究进展[J].化工技术与开发,2015(03):31-34.
[71] 马娟;宋凤丹;陈昊;周运禄;齐随涛;杨伯伦.量子点敏化太阳能电池研究进展[J].化工进展,2015(10):3601-3608.
[72] Xing Zhang;Hui Huang;Juan Liu.Carbon quantum dots serving as spectral converters through broadband upconversion of near-infrared photons for photoelectrochemicai hydrogen generation[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201338(38):11529-11533.
[73] Huijun Yu;Yufei Zhao;Chao Zhou.Carbon quantum dots/TiO2 composites for efficient photocatalytic hydrogen evolution[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201410(10):3344-3351.
[74] Suzuki, Kazumasa;Malfatti, Luca;Carboni, Davide;Loche, Danilo;Casula, Maria;Moretto, Alessandro;Maggini, Michele;Takahashi, Masahide;Innocenzi, Plinio.Energy Transfer Induced by Carbon Quantum Dots in Porous Zinc Oxide Nanocomposite Films[J].The journal of physical chemistry, C. Nanomaterials and interfaces,20155(5):2837-2843.
[75] Yu, Yang-Yang;Guo, Chun Xian;Yong, Yang-Chun;Li, Chang Ming;Song, Hao.Nitrogen doped carbon nanoparticles enhanced extracellular electron transfer for high-performance microbial fuel cells anode[J].Chemosphere: Environmental toxicology and risk assessment,2015Dec.(Dec.):26-33.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%