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采用超景深三维显微镜和扫描电镜(SEM)对汉代含“银灰亮”钱币锈蚀产物进行显微观察,并通过电子能谱、X射线粉末衍射和X射线荧光光谱等手段,对钱币本体、银灰亮层及其他锈蚀产物进行了研究,利用离子色谱法对钱币的包裹土进行了分析.确定钱币表面的锈蚀物主要为Cu2S(银灰色)、Cu2O(红褐色)、Cu2(OH)2CO3(绿色)和PbCO3(白色),探讨了含银灰亮钱币锈蚀结构的形成机理.

Ultra-depth three-dimensional microscopy,scanning electron microscopy coupled with energy-dispersive X-ray analysis,X-ray fluorescence as well as X-ray diffraction were used to investiguate the corrosion products of ancient coins and soil on the surface of coins.The results revealed that the corrosion products mainly consisted of Cu2 S (silver-grey),Cu2O (red),Cu2(OH)2CO3 (green) and PbCO3 (white).The mechanism of structure formation for the coins containing silver-grey corrosion products discussed.

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