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试验采用煤基直接还原熔分技术和热力学分析手段,对高铁铝土矿含碳球团在还原熔分过程中的渣相组成机理进行了研究。试验结果表明,渣系碱度对粒铁的收得率和粒铁尺寸以及渣系组成有重要影响。当碱度为1.00、2.00、3.85时,粒铁收得率分别为91.55%、44.53%和88.48%,粒铁尺寸分别为15.50、7.00和8.54 mm;熔分渣的相组成(质量分数)分别为55%A-34%CA6-6%C2AS-4%Fe、64%A-35%C2AS-2%Fe、24%C2S-62%C12A7-7%C2AS-4%C3AS3-3%Fe;当渣系碱度为3.85时,还原熔分渣系的组成主要为C2S和C12A7,两者质量分数约为85%;只有当混合物处在C2S到C12A7的渣线上或者渣线附近时(即R=3.85时),冷却析晶的平衡相中才会出现C2S和C12A7。

The smelting slag reaction mechanism was studied by thermodynamic analysis and coal-based direct reduction and smelting experiment. The experiment result shows that the slag basicity has an important influence on iron nuggets size,metal yield and slag composition. When the basicity were 1.00,2.00 and 3.85,the iron nuggets yield were 91.55%, 44.53%and 88.48%respectively,the iron nuggets size were 15.50,7.00 and 8.54mm respectively,and the smelting slag composition (mass percent) were 55%A-34%CA6-6%C2AS-4%Fe,64%A-35%C2AS-2%Fe and 24%C2S-62%C12A7-7%C2AS-4%C3AS3-3%Fe respectively. When the slag basicity was 3.85,the reduction smelting slag is mainly composed of C2S and C12A7,which mass percent is about 85%. Only when the mixture is close to the slag line of C2S-C12A7 ( R=3.85),the C2S and C12A7 will appear in the cooling crystallization equilibrium phase.

参考文献

[1] LIU Xue-fei,WANG Qing-fei,ZHANG Qi-zuan . Mineralogical characteristics of the superlarge quaternary bauxite deposits in Jingxi and Debao counties,Western Guangxi,China[J].Journal of Asian Earth Sciences,2012,52
[2] WANG Rui-hu,LI Mei,CHEN Ding-xiong . Resource potential prediction for lateritic high-iron gibbsite bauxite deposits in Guangxi[J].Geological Bulletin of China,2011,30(8):1303.,2011.
[3] WANG Qing-fei,DENG Jun,LIU Xue-fei,et al . Discovery of the REE minerals and its geological significance in the Quyang Bauxite Deposit,West Guangxi,China[J].Journal of Asian Earth Sciences,2010,39(6):701.,2010.
[4] 王瑞湖,李梅,陈定雄.广西红土型高铁三水铝土矿资源潜力预测[J].地质通报,2011(08):1303-1311.
[5] LIU Xue-fei,WANG Qing-fei,DENG Jun,et al . Mineralogical and geochemical investigations of the Dajia Salento-Type Baux-ite deposits,Western Guangxi,China[J].Journal of Geochemi-cal Exploration,2010,105(3):137.,2010.
[6] 张秀峰,谭秀民,张利珍,等 .我国难利用高铁铝土矿的综合利用技术研究现状[J].中国矿业,2011,20:110.,2011.
[7] Taylor G,Eggleton R A,Foster L D,et al . Nature of the Weipa Bauxite deposit,Northern Australia[J].Australian Journal of Earth Sciences,2008,55(1):45.,2008.
[8] Kahn H,Tassinari M M L,Ratti G . Characterization of Bauxite fines aiming to minimize their iron content[J].Minerals Engi-neering,2003,16(11):1313.,2003.
[9] Luke J Kirwan,Francis A Deeney,Gerard M Croke,et al . Char-acterisation of various Jamaican Bauxite ores by quantitative ri-etveld X-ray powder diffraction and 57Fe mössbauer spectrosco-py[J].Int J Miner Process,2009,91(1):14.,2009.
[10] 鲁逢霖,郭玉华,张颖异,高建军.镍渣直接还原磁选提铁试验[J].钢铁,2014(02):19-23.
[11] 丁闪,薛庆国,佘雪峰,等 .碳酸钙对钒钛磁铁精矿直接还原-熔分的影响[J].钢铁,2014,49(8):15.,2014.
[12] GUO Yu-hua,GAO Jian-jun,XU Hong-jun,ZHAO Kai,SHI Xue-feng.Nuggets Production by Direct Reduction of High Iron Red Mud[J].钢铁研究学报(英文版),2013(05):24-27.
[13] 王波,于海燕,孙会兰,毕诗文.物料配比对铝酸钙炉渣浸出和自粉性能的影响[J].东北大学学报(自然科学版),2008(11):1593-1596.
[14] 佟志芳,毕诗文,杨毅宏.微波辐射加热下高炉铝酸钙炉渣的浸出性能[J].东北大学学报(自然科学版),2005(02):148-151.
[15] 陈树江,田凤仁,李国华,等.相图分析及应用[M].北京:冶金工业出版社,2007.,2007.
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