为研究氧化石墨烯(GO)对共混橡胶的补强改性作用,首先,通过改进的H ummers方法制备了GO,并通过乳液共混法制备了GO/天然橡胶(NR)-丁腈橡胶(NBR)复合材料;然后,采用SEM、FTIR、XRD、溶胀测试和力学性能测试表征了GO、NR-NBR硫化胶和GO/NR-NBR复合材料的微观形态、结构和力学性能.结果表明:所得GO含有大量的含氧官能团,氧化效果较好;橡胶基体中GO分散均匀,且GO/NR-NBR复合材料的拉伸断面粗糙程度显著增加;GO的填充可以提高复合材料的表观交联密度;GO/NR-NBR复合材料的力学性能随着GO含量的增加而改善,当GO含量为3.0wt%时,GO/NR-NBR复合材料的拉伸强度、100%定伸应力和邵氏A硬度分别提高了53.3%、67.3%和10.5%,断裂伸长率降低了9.6%.
参考文献
[1] | 王磊;李文姬;王敏莲;吴友平.改性累托石粉体的制备及其填充橡胶复合材料的结构与性能[J].复合材料学报,2013(1):39-44. |
[2] | 吴文敬;任文坛;禹海洋;杜爱华;张勇;张隐西.乙烯-醋酸乙烯酯橡胶的共混改性[J].高分子材料科学与工程,2014(2):186-191. |
[3] | 陈尔凡;刘才茂;马驰;吴波;裴群.滑石粉改性氯磺化聚乙烯/丁苯橡胶共混物的耐酸碱性能[J].合成橡胶工业,2014(4):304-307. |
[4] | Ozbas, B.;O'Neill, C.D.;Register, R.A.;Aksay, I.A.;Prud'Homme, R.K.;Adamson, D.H..Multifunctional elastomer nanocomposites with functionalized graphene single sheets[J].Journal of Polymer Science, Part B. Polymer Physics,201213(13):910-916. |
[5] | Yanhu Zhan;Marino Lavorgna;Giovanna Buonocore.Enhancing electrical conductivity of rubber composites by constructing interconnected network of self-assembled graphene with latex mixing[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201221(21):10464-10468. |
[6] | Kim, H.;Abdala, A.A.;MacOsko, C.W..Graphene/polymer nanocomposites[J].Macromolecules,201016(16):6515-6530. |
[7] | Xin Bai;Chaoying Wan;Yong Zhang.Reinforcement of hydrogenated carboxylated nitrile-butadiene rubber with exfoliated graphene oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,20115(5):1608-1613. |
[8] | Araby, S.;Zhang, L.;Kuan, H.-C.;Dai, J.-B.;Majewski, P.;Ma, J..A novel approach to electrically and thermally conductive elastomers using graphene[J].Polymer: The International Journal for the Science and Technology of Polymers,201314(14):3663-3670. |
[9] | Sherif Araby;Qingshi Meng;Liqun Zhang;Hailan Kang;Peter Majewski;Youhong Tang;Jun Ma.Electrically and thermally conductive elastomer/graphene nanocomposites by solution mixing[J].Polymer: The International Journal for the Science and Technology of Polymers,20141(1):201-210. |
[10] | Lei Lei Wang;Li Qun Zhang;Ming Tian.Mechanical and tribological properties of acrylonitrile-butadiene rubber filled with graphite and carbon black[J].Materials & design,2012Aug.(Aug.):450-457. |
[11] | Jeffrey R. Potts;Om Shankar;Shanthi Murali;Ling Du;Rodney S. Ruoff.Latex and two-roll mill processing of thermally-exfoliated graphite oxide/natural rubber nanocomposites[J].Composites science and technology,2013Jan.(Jan.):166-172. |
[12] | Sasha Stankovich;Dmitriy A. Dikin;Richard D. Piner.Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,20077(7):1558-1565. |
[13] | Xing, Wang;Tang, Maozhu;Wu, Jinrong;Huang, Guangsu;Li, Hui;Lei, Zhouyue;Fu, Xuan;Li, Hengyi.Multifunctional properties of graphene/rubber nanocomposites fabricated by a modified latex compounding method[J].Composites science and technology,2014Jul.30(Jul.30):67-74. |
[14] | Stankovich S;Dikin DA;Dommett GHB;Kohlhaas KM;Zimney EJ;Stach EA;Piner RD;Nguyen ST;Ruoff RS.Graphene-based composite materials[J].Nature,20067100(7100):282-286. |
[15] | Interfacial Stress Transfer in a Graphene Monolayer Nanocomposite[J].Advanced Materials,201024(24):2694-697,2599. |
[16] | Chengpeng Li;Chunfang Feng;Zheng Peng.Ammonium-Assisted Green Fabrication of Graphene/ Natural Rubber Latex Composite[J].Polymer Composites,20131(1):88-95. |
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