采用溶胶-凝胶法制备HZSM-5分子筛负载SrTiO3,对其进行XRD、FTIR和N2吸附-脱附表征,研究负载对活性艳红X-3B光催化降解过程的影响.通过分析降解液的FTIR谱图、紫外-可见光谱和总有机碳(TOC)数据,对活性艳红X-3B的光催化降解过程进行了探讨.结果表明:催化剂的主要成分为钙钛矿结构SrTiO3,负载对SrTiO3晶粒尺寸几乎没有影响.纯SrTiO3没有明显的孔结构,负载后样品的比表面积和孔隙主要由HZSM-5提供.负载之后催化剂的降解活性显著提高,30%SrTiO3/HZSM-5对活性艳红X-3B染料溶液的脱色和TOC去除速率最快.
参考文献
[1] | S. Murcia-Lopez;M.C. Hidalgo;J.A. Navio.Synthesis, characterization and photocatalytic activity of Bi-doped TiO2 photocatalysts under simulated solar irradiation[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,20111/2(1/2):59-67. |
[2] | Akira Fujishima;Tata N. Rao;Donald A. Tryk.Titanium dioxide photocatalysis[J].Journal of photochemistry and photobiology, C. Photochemistry reviews,20001(1):1-21. |
[3] | 周琪;钟永辉;陈星;王岩;刘平;吴玉程.石墨烯/纳米TiO2复合材料的制备及其光催化性能[J].复合材料学报,2014(2):255-262. |
[4] | N. Arconada;A. Duran;S. Suarez.Synthesis and photocatalytic properties of dense and porous TiO2-anatase thin films prepared by sol-gel[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20091/2(1/2):1-7. |
[5] | Yong Zhao;Xintong Zhang;Jin Zhai.Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20081/2(1/2):24-29. |
[6] | Peng Guo;Xiangsheng Wang;Hongchen Guo.TiO2/Na-HZSM-5 nano-composite photocatalyst: Reversible adsorption by acid sites promotes photocatalytic decomposition of methyl orange[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20093/4(3/4):677-687. |
[7] | Wenjie Zhang;Feifei Bi;Yang Yu.Phosphoric acid treating of ZSM-5 zeolite for the enhanced photocatalytic activity of TiO2/HZSM-5[J].Journal of molecular catalysis, A. Chemical,2013:6-12. |
[8] | Todorovsky DS;Todorovska RV;Milanova MM;Kovacheva DG.Deposition and characterization of La2Ti2O7 thin films via spray pyrolysis process[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,200710(10):4560-4565. |
[9] | Hun Xue;Yiwen Zhang;Jing Xu.Facile one-pot synthesis of porous Ln2Ti2O7 (Ln = Nd, Gd, Er) with photocatalytic degradation performance for methyl orange[J].Catalysis Communications,2014:72-76. |
[10] | Garcia-Lopez, E.;Marci, G.;Megna, B.;Parisi, F.;Armelao, L.;Trovarelli, A.;Boaro, M.;Palmisano, L..SrTiO3-based perovskites: Preparation, characterization and photocatalytic activity in gas-solid regime under simulated solar irradiation[J].Journal of Catalysis,2015:13-22. |
[11] | Zhang, Wenjie;Du, Ling;Bi, Feifei;He, Hongbo.A novel SrTiO3/HZSM-5 photocatalyst prepared by sol-gel method[J].Materials Letters,2015Oct.15(Oct.15):103-105. |
[12] | 吴峰;华河林;邓南圣.三种偶氮染料降解历程在紫外-可见光谱上的表现[J].环境化学,2000(4):348-351. |
[13] | Wu F.;Hua HL.;Deng NS..Degradation mechanism of azo dye C.I. reactive red 2 by iron powder reduction and photooxidation in aqueous solutions[J].Chemosphere,20008(8):1233-1238. |
[14] | 雷阳明;申哲民;余晴春;胡晓芳;祝松鹤;王文华.酸性红B染料的阴极氧化降解机理[J].环境科学,2005(5):115-119. |
[15] | 李昱昊;毛立群;张顺利;金振声;张治军.活性艳红X-3B水溶液的光催化脱色及矿化过程研究[J].感光科学与光化学,2004(5):383-390. |
[16] | 李勇;吕松;朱素芳.Fenton试剂处理活性艳红印染废水的实验研究[J].环境科学与技术,2008(3):88-90. |
[17] | Nobuyuki Sakai;Akira Fujishima;Toshiya Watanabe;Kazuhito Hashimoto.Quantitative Evaluation of the Photoinduced Hydrophilic Conversion Properties of TiO_2 Thin Film Surfaces by the Reciprocal of Contact Angle[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,20034(4):1028-1035. |
[18] | 毛立群;杨建军;郭泉辉;李庆霖;张治军.活性艳红X-3B水溶液的光化学与光催化协同脱色反应[J].催化学报,2001(2):181-184. |
[19] | Yangming Lei;Zhemin Shen;Renhua Huang;Wenhua Wang.Treatment of landfill leachate by combined aged-refuse bioreactor and electro-oxidation[J].Water research: A journal of the international water association,200711(11):2417-2426. |
[20] | Birame Boye;Momar M. Dieng;Enric Brillas.Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods[J].Environmental Science & Technology: ES&T,200213(13):3030-3035. |
[21] | M.Karkmaz;E.Puzenat;J.M.Herrmann.Photocatalytic degradation of the alimentary azo dye amaranth Mineralization of the azo group to nitrogen[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20043(3):183-194. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%