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采用静电纺丝技术制备聚乙烯醇/二氧化钛复合纳米纤维膜,利用戊二醛对复合纳米纤维膜进行改性.分析改性前后材料表面形貌、表面化学基团的变化及其耐水性和热性能.结果表明:复合纳米纤维表面粗糙度随二氧化钛含量的增大而增大.改性后纤维形貌保持不变,纤维间出现粘结,材料表面发生羟醛缩合反应,在1600cm-1处出现-C=C红外特征峰,复合纳米纤维膜耐水性显著提高,材料在190℃处的熔融峰消失.

参考文献

[1] 马贵平;方大为;刘洋;陈洁;聂俊.电纺丝制备纳米纤维及其应用[J].材料科学与工程学报,2012(2):312-323.
[2] Zheng-Ming Huang;Y.-Z. Zhang;M. Kotaki.A review on polymer nanofibers by electrospinning and their applications in nanocomposites[J].Composites science and technology,200315(15):2223-2253.
[3] 丁源维;王騊;姚菊明;王晟.静电纺制备TiO2/PVA复合纳米纤维及其光催化性能研究[J].浙江理工大学学报,2013(1):31-35.
[4] Costa, R.G.F.;Ribeiro, C.;Mattoso, L.H.C..Study of the effect of rutile/anatase TiO_2 nanoparticles synthesized by hydrothermal route in electrospun PVA/TiO_2 nanocomposites[J].Journal of Applied Polymer Science,20136(6):4463-4469.
[5] Saeed Abbasizadeh;Ali Reza Keshtkar;Mohammad Ali Mousavian.Preparation of a novel electrospun polyvinyl alcohol/titanium oxide nanofiber adsorbent modified with mercapto groups for uranium(VI) and thorium(IV) removal from aqueous solution[J].Chemical engineering journal,2013:161-171.
[6] Lee, K.;Lee, S..Multifunctionality of poly(vinyl alcohol) nanofiber webs containing titanium dioxide[J].Journal of Applied Polymer Science,20125(5):4038-4046.
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