欢迎登录材料期刊网

材料期刊网

高级检索

以棉纤维为碳源和模板,采用生物模板法成功合成制备直径约100~150 nm、长度几至十几微米的TiC纳米线,进而通过水热反应在其表面均匀沉积Co3O4纳米微粒,所构建的核壳结构TiC/Co3O4纳米线具有良好的循环稳定性和高倍率性能.在50mA/g电流密度下循环的第2次、第50次放电容量分别为824.3mAh/g和753.7mAh/g;在倍率性能测试中,当电流密度回到50mA/g时,可逆放电容量为1060.4mAh/g,高于起始的1048.2mAh/g.

参考文献

[1] Whittingham, M. Stanley.Introduction: Batteries[J].Chemical Reviews,201423(23):11413-11413.
[2] Obrovac, M. N.;Chevrier, V. L..Alloy Negative Electrodes for Li-Ion Batteries[J].Chemical Reviews,201423(23):11444-11502.
[3] 张建军;周金天;吴萌迪;陈涛;陈北虎;姚奇杰;黄小华.片状介孔Co3O4的制备及其储锂性能[J].材料科学与工程学报,2014(2):276-279,312.
[4] 张春明;黄昭;张遥遥;王丹;何丹农.Li4Ti5O12负极材料的制备及其A位掺杂改性[J].材料科学与工程学报,2014(6):781-786,797.
[5] Wang Y;Zhang HJ;Lu L;Stubbs LP;Wong CC;Lin JY.Designed Functional Systems from Peapod-like Co@Carbon to Co3O4@Carbon Nanocomposites[J].ACS nano,20108(8):4753-4761.
[6] Fengbin Hao;Zhiwei Zhang;Longwei Yin.Co3O4/Carbon Aerogel Hybrids as Anode Materials for Lithium-Ion Batteries with Enhanced Electrochemical Properties[J].ACS applied materials & interfaces,201317(17):8337-8344.
[7] Reddy, M.V.;Subba Rao, G.V.;Chowdari, B.V.R..Metal oxides and oxysalts as anode materials for Li ion batteries[J].Chemical Reviews,20137(7):5364-5457.
[8] Wang, Wenzhong;Xu, Jie.Structure and Visible Light Luminescence of 3D Flower-like Co3O4 Hierarchical Microstructures Assembled by Hexagonal Porous Nanoplates[J].ACS applied materials & interfaces,20151(1):415-421.
[9] Liu, Tao;Li, Yang;Quan, Guiying;Dai, Peng;Yu, Xinxin;Wu, Mingzai;Sun, Zhaoqi;Li, Guang.Magnetic-field-assisted preparation of one-dimensional (1-D) wire-like NiO/Co3O4 composite for improved specific capacitance and cycle ability[J].Materials Letters,2015Jan.15(Jan.15):208-211.
[10] Zou, GF;Wang, HY;Mara, N;Luo, HM;Li, N;Di, ZF;Bauer, E;Wang, YQ;McCleskey, T;Burrell, A;Zhang, XH;Nastasi, M;Jia, Q.Chemical Solution Deposition of Epitaxial Carbide Films[J].Journal of the American Chemical Society,20108(8):2516-2517.
[11] Zhen Qiu;Hui Huang;Jun Du.Biotemplated synthesis of bark-structured TiC nanowires as Pt catalyst supports with enhanced electrocatalytic activity and durability for methanol oxidation[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201421(21):8003-8008.
[12] Wang, Y.;Xia, H.;Lu, L.;Lin, J..Excellent performance in lithium-ion battery anodes: Rational synthesis of Co(CO_3)_(0.5)(OH)0.11H_2O nanobelt array and its conversion into mesoporous and single-crystal Co_3O_4[J].ACS nano,20103(3):1425-1432.
[13] Hui Huang;Wenjun Zhu;Xinyong Tao.Nanocrystal-Constructed Mesoporous Single-Crystalline Co3O4 Nanobelts with Superior Rate Capability for Advanced Lithium-Ion Batteries[J].ACS applied materials & interfaces,201211(11):5974-5980.
[14] Shim, Hyun-Woo;Jin, Yun-Ho;Seo, Seung-Deok;Lee, Seung-Hun;Kim, Dong-Wan.Highly Reversible Lithium Storage in Bacillus subtilis-Directed Porous Co_3O_4 Nanostructures[J].ACS nano,20111(1):443-449.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%