贵金属纳米颗粒-玻璃复合材料是一种重要的非线性材料.利用光致发光谱及配位场理论,深入研究了离子交换及氢气热处理对硅酸盐玻璃中贵金属离子的引入、还原、成核及生长过程的影响,发现延长离子交换时间有利于提高玻璃中金属离子的浓度.对于掺Ag+硅酸盐玻璃,不仅存在孤立Ag+离子,同时也存在Ag2+团簇.H2中热处理后,样品中孤立Ag+离子浓度迅速降低,同时出现Ag32+团簇.对于掺Cu+硅酸盐玻璃,仅存在孤立CU+和Cu2+,没有发现Cu+团簇的发光峰,Cu2+的存在造成Cu+的发光强度显著降低.掺Ag+硅酸盐玻璃经H2热处理后,再经过第二次离子交换往玻璃中掺Cu+是十分困难的.
参考文献
| [1] | William E. Doering;Shuming Nie.Single-Molecule and Single-Nanoparticle SERS: Examining the Roles of Surface Active Sites and Chemical Enhancement[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,20022(2):311-317. |
| [2] | JON P. CAMDEN;JON A. DIERINGER;JING ZHAO.Controlled Plasmonic Nanostructures for Surface-Enhanced Spectroscopy and Sensing[J].Accounts of Chemical Research,200812(12):1653-1661. |
| [3] | Haes AJ.;Van Duyne RP..A nanoscale optical blosensor: Sensitivity and selectivity of an approach based on the localized surface plasmon resonance spectroscopy of triangular silver nanoparticles[J].Journal of the American Chemical Society,200235(35):10596-10604. |
| [4] | G. Raschke;S. Kowarik;T. Franzl;C. Sonnichsen;T. A. Klar;J. Feldmann.Biomolecular Recognition Based on Single Gold Nanoparticle Light Scattering[J].Nano letters,20037(7):935-938. |
| [5] | PRASHANT K. JAIN;XIAOHUA HUANG;IVAN H. EL-SAYED.Noble Metals on the Nanoscale: Optical and Photothermal Properties and Some Applications in Imaging, Sensing, Biology, and Medicine[J].Accounts of Chemical Research,200812(12):1578-1586. |
| [6] | D.Cotter;R.J.Manning;K.J.Blow.Nonlinear optics for high-speed digital information processing[J].Science,19995444(5444):1523-1528. |
| [7] | Weitian Wang;Guang Yang;Zhenghao Chen;Yueliang Zhou;Huibin Lu;Guozhen Yang.Iron nanoparticles in amorphous BaTiO_(3) thin films with large third-order optical nonlinearity[J].Journal of Applied Physics,200212(12):7242-7245. |
| [8] | Zhi-Wei Dong;Xiu-Chun Yang;Zhi-Hui Li;Jing-Xian Xu;Kang-Jiu Liu;Chun-Feng Zhang;Guan-Jun You;Yong-Li Yan;Shi-Xiong Qian.Ultrafast dynamics of copper nanoparticles embedded in soda-lime silicate glass fabricated by ion exchange[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,200921(21):6046-6049. |
| [9] | YANG XiuChun;LI ZhiHui;LI WeiJie;XU JingXian;DONG ZhiWei;QIAN ShiXiong.Optical nonlinearity and-ultrafast dynamics of ion exchanged silver nanoparticles embedded in soda-lime silicate glass[J].科学通报（英文版）,2008(5):695-699. |
| [10] | Yang, XC;Dong, ZW;Liu, HX;Xu, JX;Qian, SX.Effects of thermal treatment on the third-order optical nonlinearity and ultrafast dynamics of Ag nanoparticles embedded in silicate glasses[J].Chemical Physics Letters,20094/6(4/6):256-259. |
| [11] | Ari Tervonen;Brian R. West;Seppo Honkanen.Ion-exchanged glass waveguide technology: a review[J].Optical Engineering,20117(7):071107-1-071107-15. |
| [12] | 杨修春;杜天伦;陈爽;熊定邦;赵景泰;黄文旵.光谱学研究银纳米颗粒在玻璃中的生成规律[J].功能材料与器件学报,2006(3):177-181. |
| [13] | 许静仙;杨修春;刘会欣;刘艳;张文华;徐法强.Ag-Cu双金属纳米颗粒在硅酸盐玻璃中的形成过程[J].硅酸盐学报,2009(6):953-959. |
| [14] | Yang, X.C.;Li, L.L.;Huang, M.;Zhao, J.F.;Hou, J.W..In situ synthesis of Ag-Cu bimetallic nanoparticles in silicate glass by a two-step ion-exchange route[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,201111/13(11/13):2306-2308. |
| [15] | X. C. Yang;W. J. Li;M. Dubiel;W. H. Huang;T. Yano.Silver Structure Environments in Ion-Exchanged Silicate Glasses Studied by X-ray Absorption Fine Structure[J].Journal of nanoscience and nanotechnology,20092(2):1659-1662. |
| [16] | E. Borsella;A. Dal Vecchio;M. A. Garcia;C. Sada;F. Gonella;R. Polloni;A. Quaranta;L. J. G. W. van Wilderen.Copper doping of silicate glasses by the ion-exchange technique: A photoluminescence spectroscopy study[J].Journal of Applied Physics,20021(1):90-98. |
| [17] | Podlipensky AV;Grebenev V;Seifert G;Graener H.Ionization and photomodification of Ag nanoparticles in soda-lime glass by 150 fs laser irradiation: a luminescence study[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,20043/4(3/4):135-142. |
| [18] | Eichelbaum M;Rademann K;Hoell A;Tatchev DM;Weigel W;Stosser R;Pacchioni G.Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses[J].Nanotechnology,200813(13):135701-1-135701-9-0. |
| [19] | D.Manikandan;S.Mohan;K.LG.M.Nair.Absorption and luminescence of silver nanocomposite soda-lime glass formed by Ag~+-Na~+ ion-exchange[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,20039/10(9/10):1545-1550. |
| [20] | Véron, O.;Blondeau, J.P.;Abdelkrim, N.;Ntsoenzok, E..Luminescence study of silver nanoparticles obtained by annealed ionic exchange silicate glasses[J].Plasmonics,20102(2):213-219. |
| [21] | Borsella E.;Mazzoldi P.;Quaranta A.;Battaglin G.;Polloni R.;Gonella F..Spectroscopic investigation of silver in soda-lime glass[J].Chemical Physics Letters,19985-6(5-6):429-434. |
| [22] | 何峰;李钱陶;张兆艳.表面掺银浮法玻璃的光致发光性能[J].硅酸盐学报,2003(7):711-714. |
| [23] | Paje SE.;Garcia MA.;Llopis J.;Villegas MA..Optical spectroscopy of silver ion-exchanged As-doped glass[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,20033(3):239-247. |
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