首先从成键结构的角度分析了DLC薄膜摩擦性能的由来,然后分别从DLC薄膜的沉积工艺(包括制备方法、气源种类和掺杂元素)、摩擦环境条件和基底材料选择等三方面入手,讨论了影响DLC薄膜摩擦性能的主要因素及其影响规律. 经过总结发现,通过调节DLC薄膜的沉积工艺可以改变DLC薄膜中sp2 杂化碳的含量以及氢的含量,进而影响DLC薄膜的摩擦性能;真空、惰性气体和低湿环境有利于获得更好的摩擦效果;过渡层和偏压有利于提高DLC薄膜与基底之间的附着力,其摩擦性能也会得到提升. 最后对DLC薄膜在机械加工及耐磨器件、光学和电子保护以及生物医学领域的应用进行了综述,并对应用过程中存在的两大问题——DLC薄膜的内应力和热稳定性进行了分析,归纳了一些具体的解决方案,并对DLC薄膜的发展趋势进行了展望.
First of all, the origin of the DLC film friction performance was analyzed from the point of bonding structure, and then the main factors of friction properties of diamond films and the influencing law were discussed from the three aspects:deposi-tion process of DLC films ( including the preparation method, the type of the gas source and doping elements) , friction environmen-tal conditions and substrate materials. It was concluded that:the content of sp2 in the carbon and the hydrogen content in the DLC film could be changed by adjusting the deposition process of DLC films, and then the tribological properties of the DLC films were influenced;vacuum, inert gas and low humidity environment were beneficial to better friction performance;the transition layer and the bias could improve the adhesion between the DLC film and the substrate, and enhance the friction performance. At last, the paper reviewed the applications of DLC films in mechanical processing and wear resistance, optical and electronic protection, ana-lyzed the two major problems in the application process, namely, the internal stress and thermal stability of DLC film, and summa-rized the corresponding solutions. The development trend of DLC films was prospected as well.
参考文献
[1] | Okubo, Hikaru;Tsuboi, Ryo;Sasaki, Shinya.Frictional properties of DLC films in low-pressure hydrogen conditions[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,2015:2-8. |
[2] | C. A. Love;R. B. Cook;T. J. Harvey;P. A. Dearnley;R. J. K. Wood.Diamond like carbon coatings for potential application in biological implants - a review[J].Tribology International,2013:141-150. |
[3] | Polaki, S. R.;Kumar, N.;Ganesan, K.;Madapu, Kishore;Bahuguna, Ashok;Kamruddin, M.;Dash, S.;Tyagi, A. K..Tribological behavior of hydrogenated DLC film: Chemical and physical transformations at nano-scale[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,2015:105-113. |
[4] | Ma, KD;Yang, GB;Yu, LG;Zhang, PY.Synthesis and characterization of nickel-doped diamond-like carbon film electrodeposited at a low voltage[J].Surface & Coatings Technology,201016/17(16/17):2546-2550. |
[5] | 武彬;李骏;张俊彦;张斌.类金刚石薄膜挺柱的制备与性能[J].吉林大学学报(工学版),2013(1):51-55. |
[6] | Fujimoto, S.;Ohtake, N.;Takai, O..Mechanical properties of silicon-doped diamond-like carbon films prepared by pulse-plasma chemical vapor deposition[J].Surface & Coatings Technology,20115(5):1011-1015. |
[7] | F. Zhao;H.X. Ii;L Ji;Y.F. Mo;W.L Quan;Y.J. Wang;J.M. Chen;H.D. Zhou.Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,20116(6):2043-2048. |
[8] | 潘德芳;苑进社.PECVD制备类金刚石薄膜的光学特性[J].重庆理工大学学报:自然科学,2011(8):111-116. |
[9] | 罗乐;赵读亮;储雅琼;汪毅;马跃;陶汝华.脉冲激光沉积法沉积类金刚石薄膜的实验研究[J].量子电子学报,2012(6):759-763. |
[10] | 杨玉卫;杨坚;古宏伟;刘慧舟;张华;金薇.类金刚石膜的性能、制备及其应用[J].硅酸盐通报,2008(1):119-126. |
[11] | Asl, A. Modabber;Kameli, P.;Ranjbar, M.;Salamati, H.;Jannesari, M..Correlations between microstructure and hydrophobicity properties of pulsed laser deposited diamond-like carbon films[J].Superlattices and microstructures,2015:64-79. |
[12] | 曾群锋;刘官;董光能;彭润玲.类金刚石碳膜高温摩擦学性能的研究进展[J].真空科学与技术学报,2014(10):1024-1029. |
[13] | 张东灿 .金刚石薄膜和类金刚石薄膜摩擦学性能试验及其应用研究[D].上海交通大学,2010. |
[14] | 张艳;东梅;李媚;段早琦.纳尺度下类金刚石(DLC)薄膜摩擦性能研究[J].摩擦学学报,2015(2):242-248. |
[15] | 凌晓 .碳基薄膜的摩擦学性能及应用研究[D].兰州理工大学,2013. |
[16] | 任妮;马占吉;李波;程峰;武生虎;肖更竭.NiTi合金表面镀类金刚石薄膜的生物摩擦学性能研究[J].真空与低温,2004(3):137-143. |
[17] | 杨永亮;岳莉;李娜;唐昊龙.Rf-PECVD制备Si掺杂DLC薄膜性能的研究[J].激光与光电子学进展,2015(1):233-237. |
[18] | Kumar, N.;Barve, S. A.;Chopade, S. S.;Kar, Rajib;Chand, N.;Dash, S.;Tyagi, A. K.;Patil, D. S..Scratch resistance and tribological properties of SiOx incorporated diamond-like carbon films deposited by r.f. plasma assisted chemical vapor deposition[J].Tribology International,2015:124-131. |
[19] | A. Erdemir;O. L. Eryilmaz;I. B. Nilufer;G. R. Fenske.Effect of source gas chemistry on tribological performance of diamond-like carbon films[J].Diamond and Related Materials,20003-6(3-6):632-637. |
[20] | A. Erdemir;O. L. Eryilmaz;G. Fenske.Synthesis of diamondlike carbon films with superlow friction and wear properties[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,20004(4):1987-1992. |
[21] | Zhang, L. L.;Yang, Q.;Tang, Y.;Yang, L.;Zhang, C.;Hu, Y.;Cui, X..Synthesis and characterization of boron incorporated diamond-like carbon thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2015Aug.31(Aug.31):457-464. |
[22] | K. J. Clay;S. P. Speakman;N. A. Morrison;N. Tomozeiu;W. I. Milne;A. Kapoor.Material properties and tribological performance of rf-PECVD deposited DLC coatings[J].Diamond and Related Materials,19988(8):1100-1107. |
[23] | Zhongzhen Wu;XiuboTian;GangGui;Chunzhi Gong;Shiqin Yang;Paul K.Chu.Microstructure and surface properties of chromium-doped diamond-like carbon thin films fabricated by high power pulsed magnetron sputtering[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Jul.1(Jul.1):31-36. |
[24] | 柳翠;苟伟;牟宗信;李国卿.钛离子注入类金刚石碳膜的结构与性能的研究[J].功能材料,2005(2):301-303. |
[25] | 牛芳 .Si、Ni、Ti掺杂类金刚石薄膜的制备及摩擦学性能研究[D].河南大学,2013. |
[26] | Bhowmick, S.;Banerji, A.;Lukitsch, M. J.;Alpas, A. T..The high temperature tribological behavior of Si, O containing hydrogenated diamond-like carbon (a-C:H/a-Si:O) coating against an aluminum alloy[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,2015:261-271. |
[27] | Wei Zhang;Akihiro Tanaka;Koichiro Wazumi;Yoshinori Koga.Tribological properties of diamond-like carbon films in low and high moist air[J].Tribology letters,20032(2):123-130. |
[28] | Wei Zhang;Akihiro Tanaka;Koichiro Wazumi.Effect of environment on friction and wear properties of diamond-like carbon film[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,20021/2(1/2):104-109. |
[29] | Andersson J.;Erck RA.;Erdemir A..Frictional behavior of diamondlike carbon films in vacuum and under varying water vapor pressure[J].Surface & Coatings Technology,20030(0):535-540. |
[30] | Sen, F.G.;Meng-Burany, X.;Lukitsch, M.J.;Qi, Y.;Alpas, A.T..Low friction and environmentally stable diamond-like carbon (DLC) coatings incorporating silicon, oxygen and fluorine sliding against aluminum[J].Surface & Coatings Technology,2013:340-349. |
[31] | 郑锦华;李聪慧;张冲;晁云峰.不同金属基材上类金刚石薄膜的摩擦特性[J].光学精密工程,2013(6):1545-1552. |
[32] | 谭笛;代明江;林松盛;胡芳;周宏明;赵齐.CoCrMo合金表面掺金属类金刚石薄膜的摩擦学性能[J].中国表面工程,2014(1):75-80. |
[33] | Yu, X.;Qin, Y.;Wang, C.B.;Yang, Y.Q.;Ma, X.C..Effects of nanocrystalline silver incorporation on sliding tribological properties of Ag-containing diamond-like carbon films in multi-ion beam assisted deposition (Conference Paper)[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2013:82-85. |
[34] | Zou, Y.S.;Zhou, K.;Wu, Y.F.;Yang, H.;Cang, K.;Song, G.H..Structure, mechanical and tribological properties of diamond-like carbon films on aluminum alloy by arc ion plating[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,20128(8):1141-1146. |
[35] | Nobili, L.;Guglielmini, A..Thermal stability and mechanical properties of fluorinated diamond-like carbon coatings[J].Surface & Coatings Technology,2013:144-150. |
[36] | Ramos, B. C.;Saito, E.;Trava-Airoldi, V. J.;Lobo, A. O.;Marciano, F. R..Diamond-like carbon electrochemical corrosion resistance by addition of nanocrystalline diamond particles for biomedical applications[J].Surface & Coatings Technology,2014Pt.C(Pt.C):732-736. |
[37] | Aiping Zeng;Victor F. Neto;Jose J. Gracio.Diamond-like carbon (DLC) films as electrochemical electrodes[J].Diamond and Related Materials,2014:12-22. |
[38] | Bhowmick, S.;Alpas, A.T..The role of diamond-like carbon coated drills on minimum quantity lubrication drilling of magnesium alloys[J].Surface & Coatings Technology,201123/24(23/24):5302-5311. |
[39] | Aizawa, T.;Fukuda, T..Oxygen plasma etching of diamond-like carbon coated mold-die for micro-texturing[J].Surface & Coatings Technology,2013:364-368. |
[40] | Saha, B.;Liu, E.;Tor, S.B.;Hardt, D.E.;Chun, J.H..Modification of surface properties of silicon micro-molds by nitrogen and silicon doped diamond-like carbon coatings deposited with magnetron co-sputtering[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,201112(12):1105-1107. |
[41] | 侯惠君;李洪武;林松盛;朱霞高;林凯生;代明江.掺钨类金刚石膜的制备与性能研究[J].广东有色金属学报,2006(3):184-187. |
[42] | A. Banerji;S. Bhowmick;A.T. Alpas.High temperature tribological behavior of W containing diamond-like carbon (DLC) coating against titanium alloys[J].Surface & Coatings Technology,2014:93-104. |
[43] | 朱怀义.类金刚石碳膜(DLC)的制备和性能及其在工具和模具中的应用[J].新技术新工艺,2005(08):25-28. |
[44] | Mutafov, P.;Lanigan, J.;Neville, A.;Cavaleiro, A.;Polcar, T..DLC-W coatings tested in combustion engine - Frictional and wear analysis[J].Surface & Coatings Technology,2014:284-289. |
[45] | 李振军;徐洮;李红轩;郝俊英;周惠娣;陈建敏.类金刚石薄膜的摩擦学特性及磨损机制研究进展[J].材料科学与工程学报,2004(5):774-777. |
[46] | 张伟;张纾;田中章浩;徐滨士.类金刚石多层膜在不同环境下的摩擦磨损行为研究[J].摩擦学学报,2006(6):510-514. |
[47] | 王刚;薛东;魏元生;杨红新;刘占强.活塞销表面 DLC 涂层的试验研究及应用分析[J].表面技术,2014(4):124-129. |
[48] | 代明江;林松盛;候惠君;李洪武.类金刚石膜的性能及其在模具上的应用[J].模具制造,2005(9):54-56. |
[49] | Meskinis, S.;Ciegis, A.;Vasiliauskas, A.;Slapikas, K.;Tamulevicius, T.;Tamuleviciene, A.;Tamulevicius, S..Optical properties of diamond like carbon films containing copper, grown by high power pulsed magnetron sputtering and direct current magnetron sputtering: Structure and composition effects[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2015Apr.30(Apr.30):48-53. |
[50] | Cokun, Ozlem Duyar;Zerrin, Taner.Optical, structural and bonding properties of diamond-like amorphous carbon films deposited by DC magnetron sputtering[J].Diamond and Related Materials,2015:29-35. |
[51] | 马国佳;邓新绿.类金刚石膜的应用及制备[J].真空,2002(5):27-31. |
[52] | Wen-Chien Lan;Shih-Fu Ou;Ming-Hong Lin.Development of silver-containing diamond-like carbon for biomedical applications. Part I: Microstructure characteristics, mechanical properties and antibacterial mechanisms[J].CERAMICS INTERNATIONAL,20134(4):4099-4104. |
[53] | A.P. Rubstein;E.B. Makarova;I.Sh. Trakhtenberg.Osseointegration of porous titanium modified by diamond-like carbon and carbon nitride[J].Diamond and Related Materials,2012:128-135. |
[54] | 曾群锋;刘官;彭润玲;董光能;徐飞燕.退火温度对DLC膜热稳定性及摩擦学性能的影响[J].真空科学与技术学报,2015(5):601-607. |
[55] | 高功申 .钛掺杂类金刚石膜的摩擦学行为研究[D].中国地质大学(北京),2010. |
[56] | 聂朝胤;安藤彰朗;卢春灿;廖兵.Ti掺杂及Ti应力缓和层对类金刚石薄膜附着力的影响[J].功能材料,2009(2):226-229. |
[57] | Hideki Nakazawa;Soushi Miura;Ryosuke Kamata;Saori Okuno;Maki Suemitsu;Toshimi Abe.Effects of pulse bias on structure and properties of silicon/nitrogen-incorporated diamond-like carbon films prepared by plasma-enhanced chemical vapor deposition[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Jan.1(Jan.1):625-632. |
[58] | 沟引宁;黄楠;孙鸿.C/C多层类金刚石薄膜的热稳定性研究[J].真空科学与技术学报,2008(6):557-560. |
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