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在汽车上使用轻质铝合金发动机可以有效减少燃油消耗和环境污染,但铝合金的耐磨损性能较差,从而造成发动机工作过程中气缸壁面容易磨损。利用表面改性技术对铝合金表面进行强化处理,可以满足其作为滑动部件在高载荷条件下的使用要求。灰铸铁较低的成本和其中石墨的自润滑作用,使其成为铝合金发动机气缸表面保护涂层材料的首选。等离子喷涂技术以其高效率和灵活性在表面强化领域受到广泛应用。因此,利用等离子喷涂制备灰铸铁涂层成为改善铝合金发动机气缸表面耐磨性的有效方法之一。但是,由于等离子喷涂过程中熔滴冷却速度极快,等离子喷涂很难得到含大量石墨组织的灰铸铁涂层。以调控灰铸铁涂层中的石墨含量为目的,总结了等离子喷涂灰铸铁涂层的研究现状,以及基体温度、颗粒尺寸、添加合金元素等对熔滴冷却速度的影响,并以此为基础,结合凝固理论分析了在涂层中保留灰铸铁粉末中的石墨组织的可行性,同时分析了在铸铁涂层中保留石墨所面临的主要问题,并提出了解决这些问题的主要措施。最后就在等离子喷涂灰铸铁涂层中保留石墨的研究方向进行了展望。

Objective The use of light aluminum alloys engine in the automobiles can effectively reduce fuel consumption and environmental pollution. However, the poor wear resistance of aluminum alloys is easy to cause the severe surface wear of alumi-num alloys cylinder bore during working. Surface modification technology can be used to strengthen the surface of aluminum alloy, which can meet the requirements of the aluminum alloys sliding parts under high load conditions. The self-lubricating effect of graphite and low cost of grey cast iron make grey cast iron as the preferred material for protecting coating of the cylinder surface of aluminum alloys engines. Plasma spraying technology has been widely used in the field of surface hardening due to its high efficien-cy and flexibility. Therefore, plasma sprayed gray cast iron coating has become one of the effective ways to improve the wear resist-ance of the aluminum alloy engine cylinder surface. However, it is difficult to precipitate the graphite crystal in coating owing to the rapid cooling of melting particles during deposition. The purpose of this paper is to discuss the controlling of the graphite content in gray cast iron coating. The research status of plasma spraying gray cast iron coatings and the effect of substrate temperature, parti-cle size and elements addition on cooling rate were introduced and summarized. On the basis of above reports and solidification the-ory, the feasibility of reserving the graphite in the coating was analyzed. The major obstructions for reserving the graphite in gray cast iron coating were also analyzed. Finally, the future research direction of reserving graphite in the plasma spraying gray cast iron coating was prospected.

参考文献

[1] 魏秋兰;邢亚哲.汽车发动机气缸热喷涂涂层的现状与发展[J].车用发动机,2012(5):1-5,18.
[2] 杨忠须;刘贵民;闫涛;朱晓莹.热喷涂Mo及Mo基复合涂层研究进展[J].表面技术,2015(5):20-30,110.
[3] 答建成;周细应;周涛;张有为;杨涛.汽车零部件表面强化技术研究现状及展望[J].表面技术,2015(7):68-75.
[4] 王刚;焦孟旺;李贺;贡泽飞;魏元生;杨红新.热喷涂新技术在发动机减摩性能方面的应用和研究[J].表面技术,2014(1):103-108,130.
[5] Barbezat G.Advanced thermal spray technology and coating for lightweight engine blocks for the automotive industry[J].Surface & Coatings Technology,20055/6(5/6):1990-1993.
[6] Gerard B.Application of thermal spraying in the automobile industry[J].Surface & Coatings Technology,20065(5):2028-2031.
[7] A. Edrisy;T. Perry;A. T. Alpas.Investigation of scuffing damage in aluminum engines with thermal spray coatings[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20052(2):1056-1062.
[8] 朴钟宇;徐滨士;王海斗;濮春欢.等离子喷涂铁基涂层的接触疲劳失效机理研究[J].材料工程,2009(11):69-73.
[9] Bobzin K;Ernst F;Richardt K;Schlaefer T;Verpoort C;Flores G.Thermal spraying of cylinder bores with the Plasma Transferred Wire Arc process[J].Surface & Coatings Technology,200818(18):4438-4443.
[10] Kim, WJ;Ahn, SH;Kim, HG;Kim, JG;Ozdemir, I;Tsunekawa, Y.Corrosion performance of plasma-sprayed cast iron coatings on aluminum alloy for automotive components[J].Surface & Coatings Technology,20051/4(1/4):1162-1167.
[11] M. F. Morks;Y. Tsunekawa;M. Okumiya;M. A. Shoeib.Splat morphology and microstructure of plasma sprayed cast iron with different preheat substrate temperatures[J].Journal of Thermal Spray Technology,20022(2):226-232.
[12] Magdi F. Morks;Yoshiki Tsunekawa;Masahiro Okumiya.Microstructure of Plasma-Sprayed Cast Iron Splats with Different Particle Sizes[J].Materials transactions,20034(4):743-748.
[13] M. F. Morks;Y. Tsunekawa;M. Okumiya;M. A. Shoeib.Splat microstructure of plasma sprayed cast iron with different chamber pressures[J].Journal of Thermal Spray Technology,20032(2):282-289.
[14] Morks MF;Tsunekawa Y;Fahim NF;Okumiya M.Microstructure and friction properties of plasma sprayed Al-Si alloyed cast iron coatings[J].Materials Chemistry and Physics,20061(1):170-175.
[15] Y. Tsunekawa;I. Ozdemir;M. Okumiya.Plasma Sprayed Cast Iron Coatings Containing Solid Lubricant Graphite and h-BN Structure[J].Journal of Thermal Spray Technology,20062(2):239-245.
[16] C. Tekmen;K. Iwata;Y. Tsunekawa;M. Okumiya.Controlling graphite content in plasma sprayed cast iron coatings via in-flight particle diagnostic[J].Journal of Materials Processing Technology,200914(14):5417-5422.
[17] Influence of methane and carbon dioxide on in-flight particle behavior of cast iron powder by atmospheric plasma spraying[J].Materials Letters,200928(28):2439.
[18] C. Tekmen;K. Iwata;Y. Tsunekawa;M. Okumiya.In Situ Particle Behavior of Cast Iron Powder by Suspension Plasma Spraying[J].Journal of Thermal Spray Technology,20101/2(1/2):255-261.
[19] Brandl W;Toma D;Kruger J;Grabke HJ;Matthaus G;Max Planck Inst Eisenforsch GmbH D-40237 Dusseldorf Germany.;OSU Maschinenbau GmbH D-44577 Castrop Rauxel Germany..The oxidation behaviour of HVOF thermal-sprayed MCrA1Y coatings[J].Surface & Coatings Technology,19971/3(1/3):21-26.
[20] Cheng K;Chen X;Wang HX;Pan WX.Modeling study of shrouding gas effects on a laminar argon plasma jet impinging upon a flat substrate in air surroundings[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,20060(0):724-728.
[21] Syed AA;Denoirjean A;Fauchais P;Labbe JC.On the oxidation of stainless steel particles in the plasma jet[J].Surface & Coatings Technology,200614/15(14/15):4368-4382.
[22] 张林伟 .大气等离子喷涂粒子氧化及其对热障涂层性能影响研究[D].北京工业大学,2009.
[23] 张林伟;魏琪;李辉;栗卓新.热喷涂粒子氧化机理分析及其保护方法概述[J].材料工程,2009(6):78-82.
[24] Deshpande S;Sampath S;Zhang H.Mechanisms of oxidation and its role in microstructural evolution of metallic thermal spray coatings - Case study for Ni-Al[J].Surface & Coatings Technology,200618/19(18/19):5395-5406.
[25] Hong-Bing Xiong;Li-Li Zheng;Li Li;Anirudha Vaidya.Melting and oxidation behavior of in-flight particles in plasma spray process[J].International Journal of Heat and Mass Transfer,200525/26(25/26):5121-5133.
[26] Li CJ.;Li WY..Effect of sprayed powder particle size on the oxidation behavior of MCrAlY materials during high velocity oxygen-fuel deposition[J].Surface & Coatings Technology,20031(1):31-41.
[27] Planche MP;Liao H;Coddet C.Oxidation control in atmospheric plasma spraying coating[J].Surface & Coatings Technology,20071(1):69-76.
[28] Piao Zhong-yu;Xu Bin-shi;Wang Hai-dou;Wen Dong-hui.Characterization of Fe-based alloy coating deposited by supersonic plasma spraying[J].Fusion engineering and design,201311(11):2933-2938.
[29] Zeng, Z;Kuroda, S;Era, H.Comparison of oxidation behavior of Ni-20Cr alloy and Ni-base self-fluxing alloy during air plasma spraying[J].Surface & Coatings Technology,20091/2(1/2):69-77.
[30] Zhenyu Zhang;Xinchun Lu;Baolei Han.Rare earth effect on the microstructure and wear resistance of Ni-based coatings[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20070(0):194-202.
[31] Tang, L.N.;Yan, M.F..Effects of rare earths addition on the microstructure, wear and corrosion resistances of plasma nitrided 30CrMnSiA steel[J].Surface & Coatings Technology,20128/9(8/9):2363-2370.
[32] C.Wu;V.Sahajwalla.Dissolution Rates of Coals and Graphite in Fe-C-S Melts in Direct Ironmaking: Influence of Melt Carbon and Sulfur on Carbon Dissolution[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,20002(2):243-251.
[33] Sheau Tsuey CHAM;Richard SAKUROVS;Haiping SUN;Veena SAHAJWALLA.Influence of Temperature on Carbon Dissolution of Cokes in Molten Iron[J].ISIJ International,20065(5):652-659.
[34] Sung-Ha Hwang;Jin-Hwa Song;Yong-Suk Kim.Effects of carbon content of carbon steel on its dissolution into a molten aluminum alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20051/2(1/2):437-443.
[35] Haiping Sun;Katsumi Mori;Veena Sahajwalla.Carbon Solution in Liquid Iron and Iron Alloys[J].HIGH TEMPERATURE MATERIALS AND PROCESSES,19984(4):257-270.
[36] 郭占成;王大光;许志宏.Fe-C熔体中石墨溶解动力学及石墨溶解表面形貌[J].化工冶金,1994(01):1-6.
[37] V.SAHAJWALLA;R. KHANNA.A Monte Carlo Simulation Study of Dissolution of Graphite in Iron-Carbon Melts[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,20006(6):1517-1525.
[38] Tekmen, C;Tsunekawa, Y;Okumiya, M.Effect of plasma spray parameters on in-flight particle characteristics and in-situ alumina formation[J].Surface & Coatings Technology,20083/4(3/4):223-228.
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