欢迎登录材料期刊网

材料期刊网

高级检索

镁合金作为最轻的金属结构材料,在汽车、3C、国防军工、航空航天等领域具有广阔的应用前景,但耐蚀性较差是其大规模应用的瓶颈。介绍了镁合金的腐蚀机理,包括全面腐蚀、局部腐蚀、电偶腐蚀等,以及影响镁合金耐腐蚀的因素,根据不同介质中的具体腐蚀情况,对影响镁合金腐蚀的三大因素作了重点介绍,从而总结出提高镁合金防腐性能的两个研究方向,一是改善镁合金的本征耐蚀性,即通过优化合金成分,改善镁合金的微观组织等方式提高材料的耐蚀性;二是采用表面防护处理技术,通过表面防护层对基体进行保护,隔离腐蚀介质与基体。然后详细综述了净化合金成分、开发新型耐蚀镁合金、改善镁合金的表层微观组织等提高镁合金本征耐蚀性的方法,以及有机/聚合物、金属/化合物镁合金耐蚀涂层的研究现状。最后指出了镁合金防腐技术研究过程中存在的问题和今后的发展方向。

ABSTRACT:Magnesium alloy is the lightest metallic structural material, and has broad application prospects in fields of automo-bile, 3C, national defence, aerospace and so on. However, the poor anti-corrosion property has become the bottleneck for its large-scale applications. The corrosion mechanisms of comprehensive corrosion, local corrosion and galvanic corrosion etc. of magnesium alloys as well as the factors affecting the corrosion resistance of magnesium alloy were elucidated in the paper. Based on the corro-sion resistance of magnesium alloy in different media, the three major factors affecting corrosion of magnesium alloys were intro-duced, and the two study directions to improve magnesium alloy′s corrosion resistance were summarized:one was to improve mag-nesium alloy′s intrinsic corrosion resistance, i. e. to improving the corrosion resistance of the material by optimization of alloy com-position and improving magnesium alloy′s microstructure. The other way was to use surface protection treatment technology, i. e. to separate the basis materials and the corrosion medium by using protective coatings to protect the basis materials. Then the methods to enhance the intrinsic corrosion resistance of magnesium alloy were reviewed, including purification of magnesium alloy′s compo-nents, inventing new kinds of anti-corrosion magnesium alloy, improving magnesium alloy′s surface microstructure, etc. The re-search status of organic polymerization and metallic compound corrosion resistant coatings for magnesium alloy were also summa-rized. Furthermore, the existing problems in the corrosion protection technologies of magnesium alloys and the future development orientation were pointed out.

参考文献

[1] Yo Kojima.Project of Platform Science and Technology for Advanced Magnesium Alloys[J].Materials transactions,20017(7):1154-1159.
[2] 曾荣昌;柯伟;徐永波;韩恩厚;朱自勇.Mg合金的最新发展及应用前景[J].金属学报,2001(7):673-685.
[3] 韩宝军;何琼;杨妙.机械研磨处理 AZ91D 镁合金表面晶粒细化研究[J].表面技术,2014(4):32-36.
[4] 康鸿跃;陈善华;马永平;王忠海.镁合金在军事装备中的应用[J].金属世界,2008(1):61-64.
[5] 欧阳珂宁;赵景茂;谢雄;付文景.镁合金微弧氧化过程中电源模式对颗粒掺杂的影响[J].表面技术,2015(10):1-6,15.
[6] 李锦妍;郝建民;陈永楠;陈宏.镁合金微弧氧化膜层退除工艺[J].表面技术,2015(10):27-32,45.
[7] G. Song;A. Atrens.Recent Insights into the Mechanism of Magnesium Corrosion and Research Suggestions[J].Advanced Engineering Materials,20073(3):177-183.
[8] 王新印;周亚茹;张鉴清;曹发和.镁及其合金腐蚀析氢的研究现状[J].装备环境工程,2015(4):129-136,141.
[9] 张新;张奎.镁合金腐蚀行为及机理研究进展[J].腐蚀科学与防护技术,2015(1):78-84.
[10] 钟显康 .镁合金表面耐蚀性溶胶-凝胶膜层的制备与修复研究[D].西南大学,2010.
[11] 石凯;王日初;彭超群;冯艳;金和喜.应用稀土提高AZ91镁合金性能的研究进展[J].腐蚀科学与防护技术,2012(02):81-85.
[12] ZENG Rong-chang;ZHANG jin;HUANG Wei-jiu;W. DIETZEL;K. U. KAINER;C. BLAWERT;KE Wei.Review of studies on corrosion of magnesium alloys[J].中国有色金属学会会刊(英文版),2006(z1):763-771.
[13] 陈先华;王敬丰;汤爱涛;潘复生.杂质元素对镁合金组织与性能的影响及其对应措施[J].材料导报,2010(3):37-41.
[14] 李肖丰;李全安;陈君;张清;张兴渊.Ca含量对AZ61-1.2Y镁合金耐蚀性能的影响[J].稀有金属材料与工程,2011(8):1466-1469.
[15] 李肖丰;李全安;陈君;张清;张兴渊.镁合金的腐蚀特性及耐蚀性研究[J].材料保护,2009(2):37-42.
[16] 赵立新;顾云飞;邵忠财;魏守强.镁合金无铬化学转化膜的研究现状及发展趋势[J].电镀与涂饰,2009(1):33-36.
[17] 朱青;朱明;余勇;张路路.AZ91 D镁合金Mo-Mn无铬转化膜的制备与耐蚀性[J].表面技术,2015(8):9-14.
[18] Wanqiu Zhou;Dayong Shan;En-Hou Han;Wei Ke.Structure and formation mechanism of phosphate conversion coating on die-cast AZ91D magnesium alloy[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,20082(2):329-337.
[19] Mosia?ek, M.;Mordarski, G.;Nowak, P.;Simka, W.;Nawrat, G.;Hanke, M.;Socha, R.P.;Michalska, J..Phosphate-permanganate conversion coatings on the AZ81 magnesium alloy: SEM, EIS and XPS studies[J].Surface & Coatings Technology,20111(1):51-62.
[20] Y.L Lee;Y.R. Chu;W.C. Li;C.S. Lin.Effect of permanganate concentration on the formation and properties of phosphate/permanganate conversion coating on AZ31 magnesium alloy[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2013May(May):74-81.
[21] Jian, Shun-Yi;Chu, Yu-Ren;Lin, Chao-Sung.Permanganate conversion coating on AZ31 magnesium alloys with enhanced corrosion resistance[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2015Apr.(Apr.):301-309.
[22] Yang KH;Ger MD;Hwu WH;Sung Y;Liu YC.Study of vanadium-based chemical conversion coating on the corrosion resistance of magnesium alloy[J].Materials Chemistry and Physics,20072/3(2/3):480-485.
[23] Cerium conversion coatings for AZ91D magnesium alloy in ethanol solution and its corrosion resistance[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,200912(12):2916.
[24] M.A. GONZALEZ-NUNEZ;C.A. NUNEZ-LOPEZ;P. SKELDON;G.E. THOMPSON;H. KARIMZADEH;P. LYON;T.E. WILKS.A NON-CHROMATE CONVERSION COATING FOR MAGNESIUM ALLOYS AND MAGNESIUM-BASED METAL MATRIX COMPOSITES[J].Corrosion Science,199511(11):1763-1772.
[25] 霍宏伟;郑志国;李明升;张轲;曹中秋.镁合金的阳极氧化研究[J].稀有金属材料与工程,2005(9):1345-1348.
[26] 朱阮利;张津;高帅;倪娜.SiO2对镁合金阴极电泳涂层耐磨性的影响[J].表面技术,2015(7):27-33.
[27] 贾平平;马捷;王晓光;魏建忠;范爱玲.镁合金表面沉积铜钨复合涂层工艺及涂层性能研究[J].表面技术,2015(5):43-47.
[28] 章志友;赵睛;刘月娥.不同体系中镁合金微弧氧化膜层的耐蚀性研究[J].材料保护,2008(5):19-22.
[29] 刘宸旭;张津;朱阮利;高文;朱晓辉.镁合金在盐溶液中的腐蚀产物及应用分析[J].表面技术,2015(5):118-122.
[30] Comparison of electrochemical corrosion behaviour of MgO and ZrO_2 coatings on AM50 magnesium alloy formed by plasma electrolytic oxidation[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,200910(10):2483.
[31] Wei Yang;Peiling Ke;Yong Fang;He Zheng;Aiying Wang.Microstructure and properties of duplex (Ti:N)-DLC/MAO coating on magnesium alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Apr.1(Apr.1):519-525.
[32] Shi ZM;Song GL;Atrens A.Corrosion resistance of anodised single-phase Mg alloys[J].Surface & Coatings Technology,20061/2(1/2):492-503.
[33] Malyshev, VN;Zorin, KM.Features of microarc oxidation coatings formation technology in slurry electrolytes[J].Applied Surface Science,20075(5):1511-1516.
[34] P. Shi;W.F. Ng;M.H. Wong.Improvement of corrosion resistance of pure magnesium in Hanks' solution by microarc oxidation with sol-gel TiO_2 sealing[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20091/2(1/2):286-292.
[35] Zhiwen Xie;Zhuangzhu Luo;Qin Yang;Tian Chen;Sheng Tan;Yunjiao Wang;Yimin Luo.Improving anti-wear and anti-corrosion properties of AM60 magnesium alloy by ion implantation and Al/AlN/CrAlN/CrN/MoS2 gradient duplex coating[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2014:171-176.
[36] 董凯辉;宋影伟;单大勇;孙硕;韩恩厚.镁合金微弧氧化技术的研究进展[J].表面技术,2015(3):74-80,99.
[37] Mohammad Reza Elahi;Mahmoud Heydarzadeh Sohi;Abdolghayoom Safaei.Liquid phase surface alloying of AZ91D magnesium alloy with Al and Ni powders[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,201215(15):5876-5880.
[38] 谢治辉.环保型AZ91 D镁合金直接化学镀镍工艺研究[J].表面技术,2015(02):24-28,47.
[39] Hu, R.-G.;Zhang, S.;Bu, J.-F.;Lin, C.-J.;Song, G.-L..Recent progress in corrosion protection of magnesium alloys by organic coatings[J].Progress in Organic Coatings: An International Review Journal,20122/3(2/3):129-141.
[40] 胡荣 .镁合金化学镀镍工艺研究[D].沈阳理工大学,2010.
[41] Xiong, Yuming;Zhang, Ming-Xing.The effect of cold sprayed coatings on the mechanical properties of AZ91D magnesium alloys[J].Surface & Coatings Technology,2014:89-95.
[42] 刘秋月;张修庆;浦海洲;徐金鹏.AZ91 D镁合金表面Ni-P/Ni-Sn-P双镀层的制备与性能研究[J].表面技术,2015(2):34-37,133.
[43] Hoche, Holger;Gross, Stefan;Oechsner, Matthias.Development of new PVD coatings for magnesium alloys with improved corrosion properties[J].Surface & Coatings Technology,2014Pt.A(Pt.A):102-108.
[44] Zhu, Rundong;Li, Zhiyong;Li, Xiaoxi;Sun, Qi.Microstructure and properties of the low-power-laser clad coatings on magnesium alloy with different amount of rare earth addition[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2015Oct.30(Oct.30):405-413.
[45] 李忠厚;郭腾腾;宫学博;马芹芹;杨迪.磁控溅射镀钛提高AZ31镁合金耐磨耐蚀性能的研究[J].表面技术,2014(6):121-124.
[46] 杨小奎;张涛;张世艳;何建新;牟献良.环氧富锌涂层对AZ91D镁合金的腐蚀防护能力研究[J].装备环境工程,2014(1):18-23.
[47] 宋东福;农登;戚文军;龙思远;陶军.镁合金复合有机涂层的研究现状与展望[J].材料研究与应用,2012(2):81-86.
[48] 尚伟;温玉清;司延举;王旭峰;姜吉琼.镁合金表面磷化/溶胶凝胶复合膜的制备及其耐蚀性[J].表面技术,2014(2):95-99.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%