欢迎登录材料期刊网

材料期刊网

高级检索

目的 研究稀土氧化物Y2O3对粒状贝氏体堆焊金属相转变以及力学性能的影响.方法 采用金相显微镜和场发射扫描电镜对堆焊金属的微观组织进行观察,采用金相显微镜观察并统计出奥氏体晶粒度,采用XRD对堆焊金属表面物相进行测定,采用显微硬度计和电子万能试验机测量不同Y2 O3质量分数堆焊金属的硬度和拉伸性能,采用透射电子显微镜对堆焊金属微观结构进行表征.结果 Y2O3能够有效细化堆焊金属的初生奥氏体晶粒,尺寸由51.2μm减小到40.1μm,大块先共析铁素体尺寸明显减小,组织分布均匀,且M/A岛弥散分布.堆焊金属中残余奥氏体相数量随着Y2O3质量分数的增加而逐渐降低,马氏体相体积分数增加.Y2O3的加入明显提升堆焊金属的力学性能,显微硬度由(272±13)HV提升至(312±8)HV;抗拉强度由(764±10)MPa提升至(885±12)MPa,且延伸率增加了4%.结论 Y2 O3的加入能够细化堆焊金属的初生奥氏体晶粒,促进形成均匀细化的粒状贝氏体组织,M/A岛的数量逐渐增加,且M/A岛中马氏体相数量增加,粒状贝氏体堆焊金属的力学性能显著提高.

Objective To investigate the effects of Y2O3 additive on the microstructure and mechanical property of granular bainite hardfacing alloy. Methods The microstructures of the hardfacing alloy with different Y2O3 additives were observed using op-tical microscopy ( OM) , scanning electron microscopy ( SEM) and transmission electron microscopy ( TEM) . The phase structures of the hardfacing alloys were determined using X-ray diffraction. The hardness, tensile property and abrasive resistance of the hard-facing alloys with different Y2O3 additions were determined. Results The results showed that the primary austenite in the hardfacing alloy could be refined by Y2O3 additive. The grain size of primary austenite decreased from 51. 2μm to 40. 1μm with the increase of Y2O3 addition. Meanwhile, the size of proeutectoid ferrite ( PF) decreased significantly and the faction of the bainite increased, so the M/A island could be distributed uniformly. The XRD analysis showed that the fraction of martensite increased while that of retained austenite decreased with the increase of Y2 O3 addition. TEM results showed that large number of dislocation martensite was transformed in M/A. The Y2 O3 additive could improve the hardness, strength and plasticity of the hardfacing alloys. With the in-crease of Y2O3 addition, the hardness increased from (272±13)HV to (312±8)HV, the tensile strength increased from (764±10) MPa to (885±12) MPa and the elongation increased by 4%. Conclusion The grain size of primary austenite decreased with the in-crease of Y2O3 addition. Meanwhile, the PF was refined significantly and M/A islands distributed uniformly. The fraction of mar-tensite increased and the RA decreased with the increase of Y2O3 addition. The mechanical property of the hardfacing alloy with Y2O3 additive was improved.

参考文献

[1] Jun Chen;Shuai Tang;Zhenyu Liu;Guodong Wang.Influence of molybdenum content on transformation behavior of high performance bridge steel during continuous cooling[J].Materials & design,2013Aug.(Aug.):465-470.
[2] Yakubtsov, IA;Poruks, P;Boyd, JD.Microstructure and mechanical properties of bainitic low carbon high strength plate steels[J].Materials Science & Engineering. A, Structural Materials: Properties, Microstructure and Processing,20081-2(1-2):109-116.
[3] Lan, Liangyun;Kong, Xiangwei;Qiu, Chunlin.Characterization of coarse bainite transformation in low carbon steel during simulated welding thermal cycles[J].Materials Characterization,2015:95-103.
[4] Z.X. Qiao;Y.C. Liu;L.M. Yu.Formation mechanism of granular bainite in a 30CrNi3MoV steel[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20091/2(1/2):560-564.
[5] M. F. Buchely;J. C. Gutierrez;L. M. Leon;A. Toro.The effect of microstructure on abrasive wear of hardfacing alloys[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20051(1):52-61.
[6] S. Chatterjee;T. K. Pal.Wear behaviour of hardfacing deposits on cast iron[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20031/6(1/6):417-425.
[7] M. Kirchgassner;E. Badisch;F. Franek.Behaviour of iron-based hardfacing alloys under abrasion and impact[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20085/6(5/6):772-779.
[8] Cabrol, E.;Boher, C.;Vidal, V.;Rezai-Aria, F.;Touratier, F..Plastic strain of cobalt-based hardfacings under friction loading[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,2015:354-363.
[9] Ke Yang;Qin Yang;Yefeng Bao.Effect of carbonitride precipitates on the solid/liquid erosion behaviour of hardfacing alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Nov.1(Nov.1):540-544.
[10] I. Hemmati;V. Ocelik;J.Th.M. De Hosson.Dilution effects in laser cladding of Ni-Cr-B-Si-C hardfacing alloys[J].Materials Letters,2012:69-72.
[11] H. Kashani;A. Amadeh;H. M. Ghasemi.Room and high temperature wear behaviors of nickel and cobalt base weld overlay coatings on hot forging dies[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20077/8(7/8):800-806.
[12] S. Das Bakshi;P. H. Shipway;H. K. D. H. Bhadeshia.Three-body abrasive wear of fine pearlite, nanostructured bainite and martensite[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20131/2(1/2):46-53.
[13] N. Saeidi;A. Ekrami.Comparison of mechanical properties of martensite/ferrite and bainite/ferritedual phase 4340 steels[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20091/2(1/2):125-129.
[14] R. Bakhtiari;A. Ekrami.The effect of bainite morphology on the mechanical properties of a high bainite dual phase (HBDP) steel[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20091/2(1/2):159-165.
[15] S. Das Bakshi;A. Leiro;B. Prakash;H. K. D. H. Bhadeshia.Dry rolling/sliding wear of nanostructured bainite[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20141/2(1/2):70-78.
[16] Jia Guo;Aimin Guo;Hui Guo;Ying Wang;Jing Li;Xinlai He.Effect of zirconium addition on the austenite grain coarsening behavior and mechanical properties of 900 Mpa low carbon bainite steel[J].北京科技大学学报(英文版),2008(06):688-695.
[17] J.P. Wang;Z.-G. Yang;B.Z. Bai;H.S. Fang.Grain refinement and microstructural evolution of grain boundary allotriomorphic ferrite/granular bainite steel after prior austenite deformation[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20041/2(1/2):112-118.
[18] Hong-Seok Yang;H.K.D.H. Bhadeshia.Austenite grain size and the martensite-start temperature[J].Scripta materialia,20097(7):493-495.
[19] Chen, Jigang;Xing, Xiaolei;Wang, Yajun;Zhou, Yefei;Ren, Xuejun;Yang, Yulin;Yang, Qingxiang.Effects of Vanadium Addition on Microstructure and Tribological Performance of Bainite Hardfacing Coatings[J].Journal of Materials Engineering and Performance,20153(3):1157-1164.
[20] Fu HG;Xiao Q;Kuang JC;Jiang ZQ;Xing JD.Effect of rare earth and titanium additions on the microstructures and properties of low carbon Fe-B cast steel[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20071-2(1-2):160-165.
[21] Xue YJ;Jia XZ;Zhou YW;Ma W;Li JS.Tribological performance of Ni-CeO2 composite coatings by electrodeposition[J].Surface & Coatings Technology,200620/21(20/21):5677-5681.
[22] Yangyang Zhao;Junfeng Wang;Shu Zhou;Xiaodong Wang.Effects of rare earth addition on microstructure and mechanical properties of a Fe-15Mn-1.5Al-0.6C TWIP steel[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2014:106-113.
[23] Chen H;Li HQ;Sun YZ;Li M.Microstructure and properties of coatings with rare earth formed by DC-plasma jet surface metallurgy[J].Surface & Coatings Technology,200616/17(16/17):4741-4745.
[24] Garrison, WM;Maloney, JL.Lanthanum additions and the toughness of ultra-high strength steels and the determination of appropriate lanthanum additions[J].Materials Science & Engineering. A, Structural Materials: Properties, Microstructure and Processing,20051-2(1-2):299-310.
[25] Long-Mei Wang;Qin Lin;Li-Jie Yue.Study of application of rare earth elements in advanced low alloy steels[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20081/2(1/2):534-537.
[26] 王亚军;陈继刚;杨健;郝飞飞;淡婷;杨育林;杨庆祥.Effect of La2O3 on granular bainite microstructure and wear resistance of hardfacing layer metal[J].稀土学报(英文版),2014(1):83-89.
[27] M.J. Alinger;G.R. Odette;D.T. Hoelzer.On the role of alloy composition and processing parameters in nanocluster formation and dispersion strengthening in nanostuctured ferritic alloys[J].Acta materialia,20092(2):392-406.
[28] Mian Radu;D. Y. Li;R. Llewellyn.Tribological behavior of Stellite 21 modified with yttrium[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,200411(11):1154-1166.
[29] Riffard F;Buscail H;Caudron E;Cueff R;Issartel C;Perrier S.The influence of implanted yttrium on the cyclic oxidation behaviour of 304 stainless steel[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,200610(10):3697-3706.
[30] M.MILITZER;R. PANDI.Ferrite Nucleation and Growth During Continuous Cooling[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,19966(6):1547-1556.
[31] Militzer, M..Phase field modeling of microstructure evolution in steels[J].Current opinion in solid state & materials science,20113(3):106-115.
[32] F.G. Caballero;M.K. Miller;S.S. Babu.Atomic scale observations of bainite transformation in a high carbon high silicon steel[J].Acta materialia,200726(26):381-390.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%