石墨烯由于独特的结构和优异的性能，成为复合材料中最具吸引力的碳质材料增强体。系统介绍了近年来石墨烯增强铜基复合材料的制备方法以及国内外相关研究现状。针对石墨烯表面润湿性和分散性差的问题，概述了石墨烯表面改性的方法及相关研究进展，提出了利用稀土对石墨烯进行表面改性的可行性。总结了目前石墨烯增强铜基复合材料研究中存在的主要问题，并对今后石墨烯增强铜基复合材料的研究方向及发展趋势进行了展望。
Graphene has become the most attractive carbonaceous reinforcement because of its unique structure and excel-lent properties. The preparation methods of copper matrix composites and the research status at home and abroad were intro-duced. Targeting at the poor surface wettability and dispersibility of grapheme, the graphene surface modification methods and research progress were reviewed. And the feasibility of using rare earth to modify graphene surface was proposed. The main problems in the research of graphene reinforced copper matrix composites were summarized. Meanwhile, the research direction in future and development trend of the graphene reinforced copper matrix composites were discussed.
参考文献
| [1] | Geim AK;Novoselov KS.The rise of graphene[J].Nature materials,20073(3):183-191. |
| [2] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone.Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,20085887(5887):385-388. |
| [3] | Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN.Superior thermal conductivity of single-layer graphene[J].Nano letters,20083(3):902-907. |
| [4] | Chen JH;Jang C;Xiao SD;Ishigami M;Fuhrer MS.Intrinsic and extrinsic performance limits of graphene devices on SiO2[J].Nature nanotechnology,20084(4):206-209. |
| [5] | Novoselov KS;Jiang Z;Zhang Y;Morozov SV;Stormer HL;Zeitler U;Maan JC;Boebinger GS;Kim P;Geim AK.Room-temperature quantum Hall effect in graphene.[J].Science,20075817(5817):1379-0. |
| [6] | Chai G;Sun Y;Sun J;Chen QF.Mechanical properties of carbon nanotube-copper nanocomposites[J].Journal of Micromechanics and Microengineering,20083(3):35013-1-35013-4-0. |
| [7] | Yang, K.;Zhang, S.;Zhang, G.;Sun, X.;Lee, S.-T.;Liu, Z..Graphene in mice: Ultrahigh in vivo tumor uptake and efficient photothermal therapy[J].Nano letters,20109(9):3318-3323. |
| [8] | 张煜;宋美慧;张晓臣.石墨烯增强金属基复合材料研究进展[J].黑龙江科学,2015(2):16-18. |
| [9] | 李彬 .石墨烯/铜复合材料制备及性能研究[D].哈尔滨工业大学,2012. |
| [10] | W.J. Kim;T.J. Lee;S.H. Han.Multi-layer graphene/copper composites: Preparation using high-ratio differential speed rolling, microstructure and mechanical properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,2014:55-65. |
| [11] | Jaewon Hwang;Taeshik Yoon;Sung Hwan Jin;Jinsup Lee;Taek-Soo Kim;Soon Hyung Hong;Seokwoo Jeon.Enhanced Mechanical Properties of Graphene/Copper Nanocomposites Using a Molecular-Level Mixing Process[J].Advanced Materials,201346(46):6724-6729. |
| [12] | Hassan M. A. Hassan;Victor Abdelsayed;Abd El Rahman S. Khder.Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic medial[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200923(23):3832-3837. |
| [13] | Seung I. Cha;Kyung T. Kim;Salman N. Arshad;Chan B. Mo;Soon H. Hong.Extraordinary Strengthening Effect of Carbon Nanotubes in Metal-Matrix Nanocomposites Processed by Molecular-Level Mixing[J].Advanced Materials,200511(11):1377-1381. |
| [14] | Xu, Z.;Buehler, M.J..Interface structure and mechanics between graphene and metal substrates: A first-principles study[J].Journal of Physics. Condensed Matter,201048(48):485301-1-485301-5. |
| [15] | 郭俊贤;王波;杨振宇.石墨烯/Cu复合材料力学性能的分子动力学模拟[J].复合材料学报,2014(1):152-157. |
| [16] | 杨帅 .少层石墨烯增强铜基复合材料制备和性能研究[D].哈尔滨工业大学,2011. |
| [17] | 李瑞宇 .石墨烯/铜复合材料的改进分子级混合方法制备、表征及其性能研究[D].哈尔滨工业大学,2013. |
| [18] | 魏炳伟 .铜-石墨烯复合材料制备和性能的研究[D].重庆理工大学,2014. |
| [19] | 胡增荣;童国权;张超;郭华锋;徐家乐;陈长军.激光烧结石墨烯-铜纳米复合材料性能研究[J].强激光与粒子束,2015(9):293-298. |
| [20] | 贾园;颜红侠;公超;冯逸晨.石墨烯的表面改性及其在摩擦领域中的应用[J].材料导报,2013(5):18-21. |
| [21] | Shen, J.;Li, N.;Shi, M.;Hu, Y.;Ye, M..Covalent synthesis of organophilic chemically functionalized graphene sheets[J].Journal of Colloid and Interface Science,20102(2):377-383. |
| [22] | Yingqing Zhan;Xulin Yang;Heng Guo.Cross-linkable nitrile functionalized graphene oxide/poly(arylene ether nitrile) nanocomposite films with high mechanical strength and thermal stability[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201212(12):5602-5608. |
| [23] | Wang, J.;Xu, C.;Hu, H.;Wan, L.;Chen, R.;Zheng, H.;Liu, F.;Zhang, M.;Shang, X.;Wang, X..Synthesis, mechanical, and barrier properties of LDPE/graphene nanocomposites using vinyl triethoxysilane as a coupling agent[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,20112(2):869-878. |
| [24] | Xin Wang;Weiyi Xing;Ping Zhang;Lei Song;Hongyu Yang;Yuan Hu.Covalent functionalization of graphene with organosilane and its use as a reinforcement in epoxy composites[J].Composites science and technology,20126(6):737-743. |
| [25] | Bak, J.M.;Lee, T.;Seo, E.;Lee, Y.;Jeong, H.M.;Kim, B.-S.;Lee, H.-I..Thermoresponsive graphene nanosheets by functionalization with polymer brushes[J].Polymer: The International Journal for the Science and Technology of Polymers,20122(2):316-323. |
| [26] | Ren, L.;Wang, X.;Guo, S.;Liu, T..Functionalization of thermally reduced graphene by in situ atom transfer radical polymerization[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,201112(12):6389-6396. |
| [27] | Qiang Yang;Xuejun Pan;Kimmy Clarke.Covalent Functionalization of Graphene with Polysaccharides[J].Industrial & Engineering Chemistry Research,20121(1):310-317. |
| [28] | 李宁;张琦;张庆庆;宋琴;齐琳;王龙;唐明亮;靳刚;程国胜.双亲性氧化石墨烯的合成及生物相容性[J].高等学校化学学报,2013(1):50-54. |
| [29] | 王平华;王志刚;刘春华;唐龙祥;向康.基于π-π相互作用合成星型聚丙烯腈-石墨烯复合材料[J].功能高分子学报,2010(4):391-395. |
| [30] | 李晓;赵东林;白利忠;李峰;赵海静;高龙飞.盐酸阿霉素在纳米载体氧化石墨烯上的可控负载与释放[J].功能材料,2013(1):96-98,102. |
| [31] | Sasha Stankovich;Richard D. Finer;SonBinh T. Nguyen.Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets[J].Carbon: An International Journal Sponsored by the American Carbon Society,200615(15):3342-3347. |
| [32] | Jay R. Lomeda;Condell D. Doyle;Dmitry V. Kosynkin;Wen-Fang Hwang;James M. Tour.Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets[J].Journal of the American Chemical Society,200848(48):16201-16206. |
| [33] | Muszynski R;Seger B;Kamat PV.Decorating graphene sheets with gold nanoparticles[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200814(14):5263-5266. |
| [34] | Mao, A.;Zhang, D.;Jin, X.;Gu, X.;Wei, X.;Yang, G.;Liu, X..Synthesis of graphene oxide sheets decorated by silver nanoparticles in organic phase and their catalytic activity[J].The journal of physics and chemistry of solids,20128(8):982-986. |
| [35] | Chen, M.;Zhou, H.;Qiu, C.;Yang, H.;Yu, F.;Sun, L..Layer-dependent fluorination and doping of graphene via plasma treatment[J].Nanotechnology,201211(11):115706-1-115706-6. |
| [36] | 张科举;詹福如.氧化石墨烯的离子束辐照表面改性[J].材料导报,2013(16):55-58. |
| [37] | 李景夫;张雷;肖金坤;周科朝.石墨烯和石墨增强铜基复合材料的摩擦磨损性能[J].中国有色金属学报（英文版）,2015(10):3354-3362. |
| [38] | 周年润;许传凯;胡振青;章四琪.铜基石墨复合材料的研究进展[J].材料导报,2009(z1):465-469. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%