欢迎登录材料期刊网

材料期刊网

高级检索

目的:提高Ni-P/nano-WC复合刷镀层的性能。方法利用电刷镀技术将Ni-P与nano-WC粉末共同沉积在40Cr基体表面形成纳米颗粒增强的复合镀层,再利用电接触技术对Ni-P/nano-WC复合镀层进行二次强化。利用光学显微镜、场发射扫描电子显微镜(FESEM)、X射线衍射分析(XRD)、能谱分析(EDS)和显微硬度测量等手段,分析电接触强化处理对Ni-P/nano-WC复合镀层的影响。同时利用滚动摩擦试验分析电接触强化前后复合镀层耐磨性的变化情况。结果电接触强化处理后, Ni-P/nano-WC复合刷镀层的孔隙和裂纹减少,复合镀层与基体之间的界面在高温和高压的作用下发生焊合。XRD分析显示复合镀层的晶粒细化,镀层的晶粒尺寸由35.35 nm下降至26.28 nm。随着接触电流的加大,复合镀层的硬度也在逐步加大。经过20 kA电流的强化,复合镀层平均硬度由637HV0.1增加到885HV0.1,镀层硬度分布更加均匀;4 h的滚动摩损表明,随着接触电流的加大,试样的质量损失逐步减小,经20 kA接触电流强化后的Ni-P/nano-WC复合镀层质量损失为503 mg,比未经电接触强化的Ni-P/nano-WC复合镀层低40%。结论电接触强化技术能有效改善Ni-P/nano-WC复合镀层的微观组织与性能,将镀层界面由机械结合变为冶金结合,同时提高镀层的耐磨性能。

ABSTRACT:Objective To improve the properties of Ni-P/nano-WC composite coatings.Methods Electro brush plating was used for co-deposition of Ni-P and nano-WC powder on 40Cr surface to form nano-particle reinforced composite coating. The coating was secondly reinforced by electric contact strengthening (ECS). The microstructures and properties of composite coatings were investigated by optical microscopy, field emission scanning electron microscopy (FESEM), energy dispersive spectrometry (EDS), X-ray diffraction (XRD) and Vickers hardness analysis. The rolling wear test was used to analyze the wear resistance of strengthened/unstrengthened composite coatings.Results The cracks and pores of composite coatings were re-duced after ECS. Furthermore, the composite coating and the substrate were weld under high temperature and pressure envi-ronment. The XRD analysis presented that the size of gain of composite coating was refined which was reduced from 35.35 nm to 26.28 nm. With the increase of contacting electric current, the hardness of composite coating was gradually elevated. The av-erage hardness of coatings was increased from 637HV0.1 to 886HV0.1 through the strengthening of electric current of 20 kA. Hence, the coating hardness distribution was more uniform. After 4-hour rolling wear test, the results showed that with the in-crease of contacting current, the weight losses of samples was gradually reduced. The weight loss of Ni-P/nano-WC composite coatings after 20 kA ECS was 503 mg which was 40% lower than the unstrengthened composite coatings.Conclusion The ECS can effectively improve the microstructure and properties of Ni-P/nano-WC composite coating. The bonding between the com-posite coating and the 40Cr substrate was changed from mechanical bonding to metallurgical bonding, at the same time, the wear resistance was improved.

参考文献

[1] Habib Ashassi-Sorkhabi;Moosa Es'haghi.Corrosion resistance enhancement of electroless Ni-P coating by incorporation of ultrasonically dispersed diamond nanoparticles[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2013Dec.(Dec.):185-193.
[2] 张小彬;昌霞;叶宏;张开林.铸铁电刷镀Ni-P和Ni镀层性能研究[J].表面技术,2015(4):27-31.
[3] 唐爱贵;王晓雷.电泳-电沉积Ni-PTFE复合镀层及其摩擦学行为研究[J].表面技术,2015(5):67-71,135.
[4] Xiaoben Qi;Shigen Zhu;Hao Ding;Zhengkun Zhu;Zhibing Han.Microstructure and wear behaviors of WC-12%Co coating deposited on ductile iron by electric contact surface strengthening[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Oct.1(Oct.1):672-679.
[5] Yalin Wang;Shigen Zhu;Weisheng Gu;Xiaoben Qi.Electric Contact Strengthening to Improve the Bonding Between WC-Co Coating and 45# Steel Substrate[J].Journal of Thermal Spray Technology,20105(5):1142-1146.
[6] 王莉容;陈小明;吴燕明;周夏凉;赵鹏;王胄.HVAP及HVOF工艺制备WC10 Co4 Cr复合涂层及其性能研究[J].表面技术,2015(2):14-18.
[7] 张晓东;揭晓华;罗松;郑琼彬.WC/Co-Cr复合涂层激光熔覆工艺优化与表征[J].表面技术,2015(6):11-16.
[8] Haixia Qu;Shigen Zhu.Two step hot pressing sintering of dense fine grained WC-Al_2O_3 composites[J].CERAMICS INTERNATIONAL,20135(5):5415-5425.
[9] Qu, H.;Zhu, S.;Li, Q.;Ouyang, C..Microstructure and mechanical properties of hot-pressing sintered WC-xvol.%Al _2O _3 composites[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2012:96-103.
[10] Afzal, M.;Ajmal, M.;Nusair Khan, A.;Hussain, A.;Akhter, R..Surface modification of air plasma spraying WC-12%Co cermet coating by laser melting technique[J].Optics & Laser Technology,2014:202-206.
[11] Wu B;Xu BS;Zhang B;Lu YH.Preparation and properties of Ni/nano-Al2O3 composite coatings by automatic brush plating[J].Surface & Coatings Technology,200716/17(16/17):6933-6939.
[12] 王洪森;赵玉辉.ZnO∶Si透明导电薄膜厚度对其光电性能的影响[J].表面技术,2014(1):21-24,34.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%