目的 通过对超细Al2O3粉体进行接枝改性,改善其在水性浆料中的分散稳定性.方法 Al2O3粉体先用硅烷偶联剂(γ-甲基丙烯酰氧基丙基三甲氧基硅烷)改性,再接枝聚合丙烯酰胺,制备Al2O3-g-PAM复合磨料.研究引发剂和单体加入方式、反应温度、单体浓度等因素对接枝率的影响.采用红外光谱和扫描电镜等对改性粉体进行表征.结果 最佳Al2O3粉体接枝改性条件为:反应温度80℃,单体浓度0.5 mol/L,先加引发剂20m in后,再一次性加入单体.改性后的氧化铝复合磨料在水中和水性浆料中的分散稳定性均得到了明显的改善.氧化铝在水和水性浆料中的分散稳定性与接枝率密切相关:接枝率越高,其在纯水中的分散稳定性越好;但只有接枝率在某一范围内时,其在水性浆料中的分散稳定性才较好.结论 接枝率的控制最为关键,当接枝率在2％～3％之间时,改性氧化铝复合磨料在水性浆料中的分散稳定性较好.
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