切削刀具表面TiCN涂层的研究现状与发展

表面技术 , 2016, 45(6): 125-133. doi: 10.16490/j.cnki.issn.1001-3660.2016.06.019

切削刀具表面TiCN涂层的研究现状与发展

覃正海 ^1, , 鲜广 ^2, , 赵海波 ^3, , 郑永强 ^4, , 范洪远 ^5, , 王均 ^6,

1.上汽通用五菱汽车股份有限公司,广西柳州,545007

2.四川大学制造科学与工程学院,成都,610065

3.四川大学分析测试中心,成都,610065

4.上汽通用五菱汽车股份有限公司,广西柳州,545007

5.四川大学制造科学与工程学院,成都,610065

6.四川大学制造科学与工程学院,成都,610065

基金项目: 国家自然科学基金(51275323)Supported by National Science and Technology Major Project(2012ZX04003011) and the National Natural Science Foundation of China (51275323) 国家科技重大专项(2012ZX04003011)

关键词： TiCN涂层 , 切削刀具 , 高温性能

Research Status and Future Development of TiCN Coatings Deposited on Cutting Tools

Keywords： TiCN coatings , cutting tools , elevated temperature property

近年来,我国汽车产业迅猛发展,汽车机械零部件的需求给我国切削加工业带来了发展机遇和挑战.汽车安全性和舒适性的要求,国家节能减排、绿色制造的发展战略,指引切削技术向高速、高效、高精、绿色、智能方向发展,对刀具材料的使用性能也提出了更高要求.TiCN涂层刀具因具有高硬度和高耐磨性被大量应用,尤其是在有色金属及合金的切削加工上具有明显优势.综述了TiCN涂层的微观结构,指出C原子具有细化晶粒和抑制柱状晶形成的作用,涂层的结晶度和择优取向随C含量的改变而变化.总结了TiCN涂层的主要性能特点,包括硬度和致硬机理、耐磨性和减摩机理、热稳定性和热失效机制.介绍了TiCN涂层的沉积原理,指出各种制备方法的优缺点和关键工艺参数.分析了以TiCN为基进行改性获得的涂层的国内外最新研究现状,提出对TiCN涂层进行多层化、多元化以及纳米多层化,是进一步提高该涂层在高温条件下综合性能的方法,也是该涂层为适应高速切削、干式切削等新切削技术要求的发展方向.

参考文献

[1]	陈俊杰;刘利国.刀具涂层技术的现状与发展趋势[J].无锡职业技术学院学报,2007(3):32-34.
[2]	周颐辛;祝新发;张晶晶;钟宁;李戈扬.离子镀TiCN和TiN工具涂层的微结构与切削性能[J].工具技术,2010(11):18-21.
[3]	马胜利;马大衍;王昕;徐可为;介万奇.脉冲直流等离子体辅助化学气相沉积TiN和TiCN薄膜摩擦磨损特性研究[J].摩擦学学报,2003(3):179-182.
[4]	Bin Deng;Ye Tao;Zhijie Hu.The microstructure, mechanical and tribological properties of TiN coatings after Nb and C ion implantation[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2013Nov.1(Nov.1):405-411.
[5]	Microstructure and tribological properties of TiN, TiC and Ti(C, N) thin films prepared by closed-field unbalanced magnetron sputtering ion plating[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,200921(21):8846-8854.
[6]	Chen, R.;Tu, J.P.;Liu, D.G.;Mai, Y.J.;Gu, C.D..Microstructure, mechanical and tribological properties of TiCN nanocomposite films deposited by DC magnetron sputtering[J].Surface & Coatings Technology,201121/22(21/22):5228-5234.
[7]	鲜广;赵海波;范洪远;王辉;王均;杜昊.石墨靶和钛靶共溅射制备的TiCN薄膜的结构和性能[J].真空科学与技术学报,2015(5):614-619.
[8]	Shan, L.;Wang, Y.;Li, J.;Li, H.;Wu, X.;Chen, J..Tribological behaviours of PVD TiN and TiCN coatings in artificial seawater[J].Surface & Coatings Technology,2013:40-50.
[9]	Qianzhi Wang;Fei Zhou;Kangmin Chen;Meiling Wang;Tao Qian.Friction and wear properties of TiCN coatings sliding against SiC and steel balls in air and water[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,201115(15):4830-4841.
[10]	单磊;王永欣;李金龙;陈建敏.TiN、TiCN和CrN涂层在海水环境下的摩擦学性能[J].中国表面工程,2013(6):86-92.
[11]	曹峻;许俊华;喻利花.TiCN/VCN多层膜的力学和摩擦磨损性能[J].粉末冶金材料科学与工程,2013(1):132-138.
[12]	许俊华;曹峻;喻利花.磁控溅射制备 TiCN 复合膜的微结构与性能[J].中国有色金属学报,2012(11):3123-3128.
[13]	Martinez-Martinez D;Sanchez-Lopez JC;Rojas TC;Fernandez A;Eaton P;Belin M.Structural and microtribological studies of Ti-C-N based nanocomposite coatings prepared by reactive sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,20051/2(1/2):64-70.
[14]	D. Martinez-Martinez;C. Lopez-Cartes;A. Justo.Self-lubricating Ti-C-N nanocomposite coatings prepared by double magnetron sputtering[J].Solid state sciences,20093(3):660-670.
[15]	Lu YH;Shen YG.Effect of carbon content on thermal stability of Ti-C-x-N-y thin films[J].Journal of Materials Research,20083(3):671-678.
[16]	Cheng, Y.H.;Browne, T.;Heckerman, B.;Meletis, E.I..Influence of the C content on the mechanical and tribological properties of the TiCN coatings deposited by LAFAD technique[J].Surface & Coatings Technology,201116(16):4024-4029.
[17]	Wang, Q.;Zhou, F.;Zhou, Z.;Yang, Y.;Yan, C.;Wang, C.;Zhang, W.;Li, L.K.Y.;Bello, I.;Lee, S.-T..Influence of carbon content on the microstructure and tribological properties of TiN(C) coatings in water lubrication[J].Surface & Coatings Technology,201218(18):3777-3787.
[18]	Santhanam . T.;Quinto D.T..Comparison of the Steel-Milling Performance of Carbide Inserts with MTCVD and PVD TiCN Coatings[J].International Journal of Refractory Metals & Hard Materials,19961/3(1/3):31-40.
[19]	Zheng, J.;Hao, J.;Liu, X.;Gong, Q.;Liu, W..A thick TiN/TiCN multilayer film by DC magnetron sputtering[J].Surface & Coatings Technology,2012:110-116.
[20]	Bull SJ.;Bhat DG.;Staia MH..Properties and performance of commercial TiCN coatings. Part 1: coating architecture and hardness modelling[J].Surface & Coatings Technology,20030(0):499-506.
[21]	Bull SJ.;Bhat DG.;Staia MH..Properties and performance of commercial TiCN coatings. Part 2: tribological performance[J].Surface & Coatings Technology,20030(0):507-514.
[22]	朱丽慧;张雨萌;彭笑;Peter Leicht;刘一雄.TiC0.81N0.48和TiC0.61N0.44O0.15涂层的热稳定性能[J].材料研究学报,2013(3):312-316.
[23]	Mingdong Bao;Xuebo Xu;Haijun Zhang;Xiaoping Liu;Linhai Tian;Zhaoxin Zeng;Yubin Song.Tribological behavior at elevated temperature of multilayer TiCN/TiC/TiN hard coatings produced by chemical vapor deposition[J].Thin Solid Films,20112(2):833-836.
[24]	宋洪刚;曾祥才;高见;袁晓光;吴春涛.CVD涂层技术对硬质合金材料形成脱碳层（η相层）影响分析[J].工具技术,2010(5):21-23.
[25]	I. Zukerman;A. Raveh;H. Kalman;J. E. Klemberg-Sapieha;L. Martinu.Thermal stability and wear resistance of hard TiN/TiCN coatings on plasma nitrided PH 15-5 steel[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,20077/12(7/12):1249-1252.
[26]	Zukerman I;Raveh A;Landau Y;Weiss R;Shneck R;Shneor Y;Kalman H;Klemberg-Saphieha JE;Martinu L.Tribological properties of duplex treated TiN/TiCN coatings on plasma nitrided PH15-5 steel[J].Surface & Coatings Technology,200713(13):6171-6175.
[27]	L. Karlsson;A. Horling;M. P. Johansson;L. Hultman;G. Ramanath.The influence of thermal annealing on residual stresses and mechanical properties of arc-evaporated TiC_xN_(1-x) (x = 0, 0.15 and 0.45) thin films[J].Acta materialia,200220(20):5103-5114.
[28]	Cheng, Y.H.;Browne, T.;Heckerman, B..Influence of CH_4 fraction on the composition, structure, and internal stress of the TiCN coatings deposited by LAFAD technique[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,20101(1):89-94.
[29]	石玉龙;彭红瑞;李世直.MOPCVD制备Ti（CN）硬膜研究[J].真空科学与技术学报,2000(1):60-62.
[30]	潘应君;陈淑花;吴新杰;李平生;张细菊.PCVD法沉积Ti（CN）涂层及其抗氧化性研究[J].武汉理工大学学报,2004(4):12-14.
[31]	朱琳;何继宁;阎殿然;董艳春;肖立松.利用反应等离子喷涂制备TiCN涂层的研究[J].材料导报,2006(z2):468-470.
[32]	朱琳;何继宁;阎殿然;肖立松;董艳春;薛丁川;孟德亮.等离子喷涂合成TiCN厚涂层及其摩擦磨损特性[J].科学通报,2007(8):972-977.
[33]	米鹏博;何继宁;阎殿然;张建新;董艳春;杨勇.石墨粒径对反应等离子喷涂TiCN涂层性能的影响[J].材料热处理学报,2015(z1):161-165.
[34]	耿振;郝建军;张素;李建昌;马跃进.熔覆电流对反应氮弧熔覆TiCN/Fe涂层组织和性能的影响[J].河北农业大学学报,2014(6):110-113.
[35]	韩修训;阎逢元;阎鹏勋;刘维民.多层涂层的摩擦学研究进展[J].机械工程材料,2002(5):1-5,41.
[36]	Su, J.F.;Yu, D.;Nie, X.;Hu, H..Inclined impact-sliding wear tests of TiN/Al_2O_3/TiCN coatings on cemented carbide substrates[J].Surface & Coatings Technology,20117(7):1998-2004.
[37]	戴建伟;许振华;王凯;何利民;牟仁德.不同温度下沉积TiN/TiCN/Al2O3/TiN复合涂层的物相结构和性能[J].机械工程材料,2014(7):84-89.
[38]	谢灿强;陈康华;王社权;祝昌军;徐银超;陈响明.TiN/TiCN/Al2O3/TiN CVD多层涂层硬质合金的氧化行为[J].粉末冶金材料科学与工程,2011(1):26-31.
[39]	陈响明;易丹青;黄道远;李秀萍;刘会群;吴春萍.化学气相沉积硬质合金TiN/TiCN/Al2O3/TiN层涂层的抗氧化性能[J].中国有色金属学报,2011(8):1967-1973.
[40]	Zhang, Xuhai;Qiu, Yuedong;Tan, Zheng;Lin, Jianliang;Xu, Aiqun;Zeng, Yuqiao;Moore, J. J.;Jiang, Jianqing.Effect of Al content on structure and properties of TiAlCN coatings prepared by magnetron sputtering[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2014:81-85.
[41]	Zeng, Yuqiao;Qiu, Yuedong;Mao, Xiangyang;Tan, Shuyong;Tan, Zhen;Zhang, Xuhai;Chen, Jian;Jiang, Jianqing.Superhard TiAlCN coatings prepared by radio frequency magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2015Jun.1(Jun.1):283-288.
[42]	Shtansky, D. V.;Kiryukhantsev-Korneev, Ph V.;Sheveyko, A. N.;Mavrin, B. N.;Rojas, C.;Fernandez, A.;Levashov, E. A..Comparative investigation of TiAlC(N), TiCrAlC(N), and CrAlC(N) coatings deposited by sputtering of MAX-phase Ti2-xCrxAlC targets[J].Surface & Coatings Technology,200923(23):3595-3609.
[43]	Yang, Y.;Guo, N.;Li, J..Synthesizing, microstructure and microhardness distribution of Ti-Si-C-N/TiCN composite coating on Ti-6Al-4V by laser cladding[J].Surface & Coatings Technology,2013:1-7.
[44]	Kuptsov, K.A.;Kiryukhantsev-Korneev, P.;Sheveyko, A.N.;Shtansky, D.V..Comparative study of electrochemical and impact wear behavior of TiCN, TiSiCN, TiCrSiCN, and TiAlSiCN coatings[J].Surface & Coatings Technology,2013:273-281.
[45]	张雨萌;朱丽慧;班志刚;刘一雄.氧的掺入对化学气相沉积TiCN涂层的影响[J].硬质合金,2012(2):66-71.
[46]	J. H. Hsieh;C. Li;W. Wu;A. L. K. Tan.Synthesis of Ti(C, N, O) coatings by unbalanced magnetron sputtering[J].Journal of Materials Processing Technology,20031/3(1/3):662-667.
[47]	Chappe, JM;Vaz, F;Cunha, L;Moura, C;De Lucas, MCM;Imhoff, L;Bourgeois, S;Pierson, JF.Development of dark Ti(C,O,N) coatings prepared by reactive sputtering[J].Surface & Coatings Technology,20085/7(5/7):804-807.
[48]	杜会静;田永君.超硬纳米多层膜致硬机理研究[J].无机材料学报,2006(4):769-775.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网