稀土, 2016, 37(6): 75-79. doi: 10.16533/J.CNKI.15-1099/TF.201606013
轧制Fe83Ga17Er0.4合金的磁致伸缩性能及显微组织
梁雨萍
1,
, 郝宏波
2,
, 王婷婷
{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"成功合成了一种磺酸钠基团官能团化的水溶性氮杂环卡宾钯金属配合物。在无膦、以水作溶剂的反应条件下，这种水溶性卡宾钯金属配合物能高效催化碘代芳烃和端基炔烃的Sonogashira偶联反应，反应结束后，可以通过萃取的方式把催化剂从反应混合物中分离出来，该催化剂可以重复循环使用四次。","authors":[{"authorName":"张春艳","id":"07ca8061-2a25-4a9d-86a6-0bf95fa11821","originalAuthorName":"张春艳"},{"authorName":"刘建华","id":"ee5c750a-8c1a-44a4-8514-bc3b5726cc54","originalAuthorName":"刘建华"},{"authorName":"夏春谷","id":"8494467a-6e64-41e2-bbb1-78bf730ef7b1","originalAuthorName":"夏春谷"}],"doi":"10.1016/S1872-2067(15)60843-9","fpage":"1387","id":"4bda3296-afa7-42eb-b957-f9a0a335d732","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"c6991b3a-f96c-431f-a5cf-628b8cb717d2","keyword":"氮杂环卡宾钯金属配合物","originalKeyword":"氮杂环卡宾钯金属配合物"},{"id":"86674c74-4825-4788-90b5-cece7075b262","keyword":"Sonogashira反应","originalKeyword":"Sonogashira反应"},{"id":"0a42a7b7-5096-46c0-ac67-9df2dd165369","keyword":"水","originalKeyword":"水"},{"id":"c5c8eea9-8039-4d26-b0b2-0150f20f95e9","keyword":"碘代芳烃","originalKeyword":"碘代芳烃"},{"id":"6afc28c0-5482-4459-9c55-77d38301f9f0","keyword":"端基炔烃","originalKeyword":"端基炔烃"}],"language":"zh","publisherId":"cuihuaxb201508032","title":"水溶性氮杂环卡宾钯金属配合物催化的Sonogashira反应","volume":"","year":"2015"},{"abstractinfo":"以邻氨基苯甲醇为原料进行催化脱氢反应,经过对催化体系的一系列筛选,最终采用[RuCl2 (p-cymene)] 2/AgOTf共催化体系,使邻氨基苯甲醇发生催化脱氢和芳基端炔发生交叉偶联反应,并以39％ ～47％的收率获得合成一系列2-芳基喹啉衍类生物,发展了邻氨基苯甲醇与芳基末端炔烃合成喹啉衍类生物的新方法,是对喹啉类衍生物合成方法的一个重要补充.","authors":[{"authorName":"刘建本","id":"a4d209b1-a5ae-45c3-a2ca-6d7450fffb78","originalAuthorName":"刘建本"},{"authorName":"陈上","id":"1db880c6-a770-453d-97d8-f96be4930101","originalAuthorName":"陈上"}],"doi":"10.11944/j.issn.1000-0518.2015.03.140250","fpage":"267","id":"45ce79ac-9029-413d-9784-3c86c975d9c9","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"30caaf64-9f9a-44e4-bf35-9514ae4e1508","keyword":"钌催化","originalKeyword":"钌催化"},{"id":"34884a83-d736-405b-8fbc-b56c75eabc21","keyword":"邻氨基苯甲醇","originalKeyword":"邻氨基苯甲醇"},{"id":"844dadd9-f5e4-46a2-874c-6c37cccac463","keyword":"脱氢","originalKeyword":"脱氢"},{"id":"3f02b409-f60c-41c9-bba1-f7501eb1d21c","keyword":"喹啉类衍生物","originalKeyword":"喹啉类衍生物"}],"language":"zh","publisherId":"yyhx201503004","title":"钌/酸共催化邻氨基苯甲醇和芳基端炔合成喹啉衍生物","volume":"32","year":"2015"},{"abstractinfo":"采用改性单体原位反应聚合法(MPMR)制备了苯炔基封端的聚酰亚胺树脂,采用模压方法研究了聚酰亚胺复合材料的成型工艺.所制备的树脂和复合材料均具有很高的热稳定性;复合材料在371℃的力学性能保持率高于室温力学性能的50%;其玻璃化转变温度为449℃;纯树脂和复合材料在371℃空气中100 h的热失重小于3%.所研制的聚酰亚胺复合材料基本满足了371℃高温树脂的性能.","authors":[{"authorName":"王震","id":"c7f4b5dd-a417-4c82-a4a7-661ac71192ef","originalAuthorName":"王震"},{"authorName":"杨慧丽","id":"16049d37-2a5f-4d03-abff-127d578462d0","originalAuthorName":"杨慧丽"},{"authorName":"益小苏","id":"4410f48f-0307-4913-9d56-ce3bd0daf43f","originalAuthorName":"益小苏"},{"authorName":"丁孟贤","id":"13d43ee7-428a-486f-964d-f6538fc26493","originalAuthorName":"丁孟贤"}],"doi":"10.3321/j.issn:1000-3851.2006.03.001","fpage":"1","id":"4b3d5b75-c99c-4865-8aad-d0bca3628af6","issue":"3","journal":{"abbrevTitle":"FHCLXB","coverImgSrc":"journal/img/cover/FHCLXB.jpg","id":"26","issnPpub":"1000-3851","publisherId":"FHCLXB","title":"复合材料学报"},"keywords":[{"id":"2d13a623-5aa2-439f-9d26-bb0716af4bed","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"c589af47-b10b-47ea-8335-cb9b91fa9aaa","keyword":"复合材料","originalKeyword":"复合材料"},{"id":"a8baf5dc-1d8a-4535-b753-3e85e4309e3d","keyword":"苯乙炔,热性能,力学性能","originalKeyword":"苯乙炔,热性能,力学性能"}],"language":"zh","publisherId":"fhclxb200603001","title":"苯炔基封端的联苯型聚酰亚胺复合材料","volume":"23","year":"2006"},{"abstractinfo":"设计并合成了具有较大空间位阻侧链的取代炔烃 2-炔丙氧基-1,4-对苯二甲酸二甲酯单体,分别采用WCl6,WCl6-SnPh4和[Rh(nbd)Cl]2催化体系使其聚合,考察了不同催化剂对聚合的影响.采用红外光谱和核磁共振等技术对单体及聚合物结构进行了表征,并用紫外光谱和荧光光谱研究了所得聚合物的光学性能.结果表明,使用[Rh(nbd)Cl]2催化剂时得到的聚合物是高反式结构,荧光光谱中除了侧基的350 nm发射峰外,还在429 nm处存在较弱的共轭主链发射.使用WCl6-SnPh4催化体系得到的聚合物由于较高的顺式含量,主要是侧基的发射,而较大侧基位阻使主链共轭降低.尽管存在较短的间隔基,引入较大空间位阻侧基仍然迫使聚合物主链扭曲,顺式结构中侧基空间位阻的影响更大.","authors":[{"authorName":"查代军","id":"0a1b1825-f1ef-413f-8fdb-b4d06993e206","originalAuthorName":"查代军"},{"authorName":"陈义旺","id":"f1dd76d2-bcf8-4047-8d62-34b04a422f52","originalAuthorName":"陈义旺"},{"authorName":"谌烈","id":"b110319f-a95c-46cc-a572-499f7fdcf23c","originalAuthorName":"谌烈"},{"authorName":"秦志勇","id":"13ac8747-290c-4ec6-b9f6-793ec98b8bae","originalAuthorName":"秦志勇"},{"authorName":"周丹","id":"c16afbfc-f0fd-4d12-a458-a05991bea632","originalAuthorName":"周丹"}],"doi":"","fpage":"737","id":"dbac0c4b-af05-4b09-8b3b-c3a9db1ba115","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"1fb6e716-3b35-432c-ab64-394aa132184a","keyword":"聚乙炔","originalKeyword":"聚乙炔"},{"id":"ca4f1140-b62c-4955-adef-ae4058b9db43","keyword":"催化聚合","originalKeyword":"催化聚合"},{"id":"a1884157-c3e3-4906-88de-a0bd75c7d9d1","keyword":"铑","originalKeyword":"铑"},{"id":"b21b9ac1-c4bc-4990-9c3c-cdb65b822ef8","keyword":"过渡金属催化剂","originalKeyword":"过渡金属催化剂"},{"id":"296efa05-5d02-430c-b8f5-e2b0dd6368a0","keyword":"荧光光谱","originalKeyword":"荧光光谱"}],"language":"zh","publisherId":"cuihuaxb200708014","title":"含空间位阻侧链取代炔烃的合成及其催化聚合","volume":"28","year":"2007"},{"abstractinfo":"端叠氮基聚乙二醇(ATPEG)可分别与N，N，N′，N′-四炔丙基乙二胺(1)及1，1，1-三(炔丙氧甲基)丙烷(2)固化得到交联弹性体。研究了固化时间、扩链剂用量、ATPEG分子量和固化剂对该交联弹性体力学及溶胀性能的影响。观察到ATPEG与2固化胶片的延伸率明显高于与1固化得到的胶片。不同分子量ATPEG与多官能度炔丙基化合物反应时，分子量越高，其在DMF和水中的溶胀比也越大。","authors":[{"authorName":"王晓红","id":"fc0d9bb8-af14-463e-92ec-76242e390326","originalAuthorName":"王晓红"},{"authorName":"冯增国","id":"46ab2399-79ab-448f-a105-c501da52b2ea","originalAuthorName":"冯增国"}],"doi":"","fpage":"91","id":"4a799848-4d63-4108-8eb9-4eee327db164","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"ca7a4a31-a987-4cd0-aeb1-9bcaed24a3e0","keyword":"多官能度炔烃","originalKeyword":"多官能度炔烃"},{"id":"64f6c01f-f186-47ca-b8fa-637d7dc44889","keyword":"叠氮化物","originalKeyword":"叠氮化物"},{"id":"e35a412d-bac5-4693-a792-aab95425f2bb","keyword":"力学性能","originalKeyword":"力学性能"},{"id":"b8bc20ef-8664-4049-88a6-c805e4516434","keyword":"交联弹性体","originalKeyword":"交联弹性体"},{"id":"052407c1-1fe9-457e-a461-de3dad5c71cf","keyword":"固化反应","originalKeyword":"固化反应"}],"language":"zh","publisherId":"gfzclkxygc200103023","title":"由多官能度炔烃与叠氮化物制备交联弹性体","volume":"17","year":"2001"},{"abstractinfo":"为了合成selaginellin家族天然产物,我们开发了炔锂和对亚甲基苯醌的1,6-加成反应. 研究了此反应的反应条件及底物适用范围和限制. 结果表明,对亚甲基苯醌苯环上的取代基对反应速率和产率有显著的影响:吸电子基团增加其亲电性,使反应变快,并且可以得到较高的产率;与此相反,给电子基团则降低了对亚甲基苯醌的亲电性,反应变慢,并且表现出可逆性,产率变低. 端炔对反应影响很小,均能得到高产率的产物. 本方法可用于快速构建selaginellin家族天然产物的骨架结构.","authors":[{"authorName":"唐平生","id":"99b9b491-3ad3-46c5-adac-bf3781b14fe9","originalAuthorName":"唐平生"},{"authorName":"王博","id":"c81b544c-8a7d-475b-b469-cc3f0d6b4bb5","originalAuthorName":"王博"}],"doi":"10.11944/j.issn.1000-0518.2017.06.160379","fpage":"664","id":"f9c3cff6-64c5-4fa6-8ee9-523eccadf1b4","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"18622cb8-11db-42af-b8b8-91f13a3722bb","keyword":"对亚甲基苯醌","originalKeyword":"对亚甲基苯醌"},{"id":"c26862a5-3514-410b-8e28-7f11445aa279","keyword":"端炔","originalKeyword":"端炔"},{"id":"a9149773-8fa4-451d-b77d-96d24faa899b","keyword":"1,6-加成","originalKeyword":"1,6-加成"}],"language":"zh","publisherId":"yyhx201706008","title":"端炔与对亚甲基苯醌的1,6-加成","volume":"34","year":"2017"},{"abstractinfo":"以廉价的亚磷酸三乙酯为配体,首次用于Cu催化的碘代芳烃和末端炔烃的偶联反应,考察了不同Cu盐、金属纯度、碱和催化剂用量等条件对反应性能的影响.结果表明,当以高纯度的CuI (99.999％)为铜源,催化剂用量为5mol％时,在KOH作用下,该催化体系成功催化了一系列碘代芳烃和末端炔烃的反应,表现出良好的催化活性,此外,该催化体系还可用于2-苯基苯并呋喃的合成,为该类化合物的合成提供了一条较为经济的途径.","authors":[{"authorName":"何亭","id":"80135948-1e1f-4eec-a310-eacfe9652327","originalAuthorName":"何亭"},{"authorName":"葛轶岑","id":"606517e3-4353-4263-a13a-b4ed6c73abd9","originalAuthorName":"葛轶岑"},{"authorName":"武垒垒","id":"2a3932b1-7af4-42f1-a55b-502d08337219","originalAuthorName":"武垒垒"},{"authorName":"付海燕","id":"558dec4e-8744-4c83-92e1-cf6146dea363","originalAuthorName":"付海燕"},{"authorName":"陈华","id":"32991480-1bc7-4f84-aa94-22d6b1cb09cc","originalAuthorName":"陈华"},{"authorName":"李贤均","id":"7a11aa1a-5f3b-483b-bc54-1cf13c41e190","originalAuthorName":"李贤均"}],"doi":"10.3724/SP.J.1088.2011.10311","fpage":"1376","id":"adf22c62-fc7f-4b37-b652-82906fcf1ffa","issue":"8","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"9700b016-34ea-4ea5-a9db-deaabd94c572","keyword":"碘化亚铜","originalKeyword":"碘化亚铜"},{"id":"3e473adb-a979-468f-b1a6-ba11348b5f0d","keyword":"亚磷酸三乙酯","originalKeyword":"亚磷酸三乙酯"},{"id":"2bad7b86-3348-46e2-b7e6-e498a53ae5ef","keyword":"碘代芳烃","originalKeyword":"碘代芳烃"},{"id":"eff165e9-9f9b-4246-9b47-9d2342ae1201","keyword":"末端炔烃","originalKeyword":"末端炔烃"},{"id":"c52b5cb4-a506-47dc-b3c9-c5747f3bdba7","keyword":"偶联反应","originalKeyword":"偶联反应"}],"language":"zh","publisherId":"cuihuaxb201108011","title":"碘化亚铜/亚磷酸三乙酯催化碘代芳烃和末端炔烃的偶联反应","volume":"32","year":"2011"},{"abstractinfo":"吡咯啉酮是一类重要的五元杂环,广泛存在于许多天然产物、生物活性分子和高聚物中.在众多吡咯啉酮衍生物中,5-炔基-2-吡咯啉酮引起了化学家们广泛的关注.因为这种分子结构不仅存在于具有潜在治疗作用的药物分子(如眼部降压药、α7乙酰胆碱受体激动剂、抗惊厥和消炎药物)中,也存在于许多天然产物中,例如刺桐类生物碱和多环类生物碱.鉴于此,人们发展了许多合成这类化合物的方法.目前文献报道最多的方法是炔基负离子对5-位具有离去基团的吡咯啉酮化合物的亲核取代反应.离去基团主要有苯硫基、1-苯并咪唑基和烷氧基等.但是这些方法操作步骤繁琐,产生大量的副产物,原子经济性不高.
本课题组发展了一例新型的端炔C–H键与α,β-不饱和-γ-内酰胺的亲核加成反应,合成了一系列5-炔基-2-吡咯啉酮衍生物.该反应以环状N-酰亚胺正离子为反应活性中间体,反应条件温和,操作简便.据我们所知,这是一例原子经济地合成5-炔基-2-吡咯啉酮衍生物的新方法.环状N-酰亚胺正离子是一类高活性的亲电试剂,广泛应用于构建含氮杂环体系.本课题组利用这一策略实现了一系列C–C和C–N成键反应.基于此,本文原位形成环状N-酰亚胺正离子,以端炔作为亲核试剂,与其发生亲核加成反应,合成了一系列5-炔基-2-吡咯啉酮衍生物,原子经济性为100%.
首先,我们以5 mol%TsOH为Br?nsted酸,考察了Lewis酸效应对反应收率的影响.结果表明, Al(OTf)3给出最好的反应收率,不加Lewis酸没有亲核加成产物生成.然后,我们以5 mol%Al(OTf)3为Lewis酸,考察了Br?nsted酸效应对反应收率的影响.结果表明, HAuCl4·4H2O给出最佳的反应收率54%,不加Br?nsted酸也没有亲核加成产物生成.值得一提的是,当HAuCl4·4H2O为单一催化剂,不加Al(OTf)3时,反应收率也达到55%.然后,我们以HAuCl4·4H2O为催化剂,考察了溶剂效应和反应温度对反应收率的影响.结果表明,四氯乙烷(TTCE)为反应最佳的溶剂,50 oC反应最佳.为了进一步提高反应收率,我们又考察了催化剂用量对反应收率的影响.结果表明,10 mol%的催化剂给出最佳的反应收率60%.进一步优化反应条件,我们没有得到更好的结果.因此最佳的反应条件： N-苄基-α,β-不饱和-γ-内酰胺1(0.4 mmol),苯乙炔2a (1.2 mmol), HAuCl4·4H2O (10 mol%), TTCE (2.0 mL),50 oC下反应15 h.
在确定了最佳的反应条件后,我们对端炔类底物的适用性进行了考察.结果表明,给电子的苯乙炔表现出较高的反应活性；弱吸电子的苯乙炔也表现出较高的反应活性；强吸电子的苯乙炔则抑制反应的发生；位阻效应对该反应没有明显影响；杂环端炔也给出中等以上的收率；然而,简单脂肪端炔不能给出相应的亲核加成产物.
本文发展了一例催化的端炔C–H键与α,β-不饱和-γ-内酰胺的亲核加成反应.该反应以环状N-酰亚胺正离子为关键中间体.反应条件温和,操作简便.构建了一种以中等的收率(45%–76%)合成一系列5-炔基-2-吡咯啉酮衍生物的方法.","authors":[{"authorName":"王茂荣","id":"0a18c988-b799-450c-864b-07eb194697c9","originalAuthorName":"王茂荣"},{"authorName":"高宝","id":"4a18a6b2-2a53-402e-a472-5e7254e3935d","originalAuthorName":"高宝"},{"authorName":"黄汉民","id":"f57928aa-58a0-4bc3-8bd4-19160bd4f93e","originalAuthorName":"黄汉民"}],"doi":"10.1016/S1872-2067(15)61057-9|","fpage":"476","id":"df857c57-6281-4cba-942e-7d429901741b","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"131f6f3b-39f6-41cb-9475-4dc378f592dc","keyword":"碳-氢加成","originalKeyword":"碳-氢加成"},{"id":"0f6e1c3a-81e6-4a68-93c4-00a3060888dc","keyword":"Br?nsted酸","originalKeyword":"Br?nsted酸"},{"id":"f087477a-eb50-4559-b86d-1c73f3914095","keyword":"N-酰亚胺正离子","originalKeyword":"N-酰亚胺正离子"},{"id":"a092bc75-7c2e-412f-8d03-0500e18c6a5e","keyword":"端炔","originalKeyword":"端炔"},{"id":"77bd941b-8f86-43ac-b071-8a74eb0d58d7","keyword":"吡咯啉酮","originalKeyword":"吡咯啉酮"}],"language":"zh","publisherId":"cuihuaxb201604003","title":"催化的端炔C-H键与α,β-不饱和-γ-内酰胺的亲核加成反应","volume":"37","year":"2016"},{"abstractinfo":"三苯基氯化锡和烯(或炔)基膦酸二钠反应，合成了8种新的双(三苯基锡)不饱和烃基膦酸酯.利用元素分析、红外光谱、核磁共振氢谱和锡谱以及质谱表征了这些化合物的结构.生物活性测试表明，该类化合物具有很高的杀菌活性.","authors":[{"authorName":"尹汉东","id":"051d8029-7e6c-4e9c-ac3e-2959aaf4b8d8","originalAuthorName":"尹汉东"},{"authorName":"张如芬","id":"c5eb45c6-90c8-4f80-8a94-603e9a78eea2","originalAuthorName":"张如芬"},{"authorName":"马春林","id":"32ce6414-8caf-40ec-8edc-e4a90cf516e6","originalAuthorName":"马春林"}],"doi":"10.3969/j.issn.1000-0518.2001.02.013","fpage":"134","id":"630e4b5a-a6a7-4960-baa1-9708c4b04d32","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"acade526-ab67-4549-a882-ea07d27f1adc","keyword":"三苯基锡","originalKeyword":"三苯基锡"},{"id":"77f5e66e-85d4-4ef5-a588-106b9cbda452","keyword":"不饱和烃基膦酸酯.合成","originalKeyword":"不饱和烃基膦酸酯.合成"},{"id":"7171c1cd-37e2-4154-b0ab-95c41c83a174","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx200102013","title":"双(三苯基锡)不饱和烃基膦酸酯的合成和性质","volume":"18","year":"2001"},{"abstractinfo":"报道了一种用于端炔水合反应的水溶性salen-Co(III)配合物催化剂，在使用硫酸作为共催化剂的条件下能高效得到产物甲基酮。该催化剂用量少，反应结束后可利用简单的萃取实现产物与催化剂分离，简化了后处理过程。此外，催化剂还可回收重复使用，但催化剂活性会略有下降。","authors":[{"authorName":"王寿峰","id":"d3f3d5e6-6df5-43ee-93c6-e628af261cf2","originalAuthorName":"王寿峰"},{"authorName":"苗成霞","id":"7b96319c-0b13-45a5-ab9c-af97f16d09fe","originalAuthorName":"苗成霞"},{"authorName":"王文芳","id":"475a0cdf-3c9d-40b6-8b5d-f70e3fb06819","originalAuthorName":"王文芳"},{"authorName":"雷自强","id":"8103bf0c-bfb5-40a8-bba6-a553230cc821","originalAuthorName":"雷自强"},{"authorName":"孙伟","id":"03bd82f0-3fc1-47c7-9f1c-99b45d8c72c3","originalAuthorName":"孙伟"}],"doi":"10.1016/S1872-2067(14)60105-4","fpage":"1695","id":"579307e8-4306-4f5d-91c7-10df10803e34","issue":"10","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"df640430-dd73-4c5c-8d7e-72aaf8ffa740","keyword":"水合反应","originalKeyword":"水合反应"},{"id":"dc27508e-1231-4b52-92a6-f12f597b9713","keyword":"炔烃","originalKeyword":"炔烃"},{"id":"e4786d66-fccb-4456-aa69-10aeb6fc31a0","keyword":"水溶性","originalKeyword":"水溶性"},{"id":"33eaf8a5-4aa4-48b8-b7ac-b5b201aa79d9","keyword":"钴","originalKeyword":"钴"},{"id":"fae667d6-21fb-4438-a512-c28aa3847d7e","keyword":"希夫碱配合物","originalKeyword":"希夫碱配合物"}],"language":"zh","publisherId":"cuihuaxb201410013","title":"水溶性salen-Co（III）配合物催化的端炔水合反应","volume":"","year":"2014"}],"totalpage":2078,"totalrecord":20779}