对LY12铝合金/环氧电极在NaCl溶液中于不同浸泡阶段的阻抗参数进行了解析根据涂层电容值(Cc)随时间的变化看出涂层中水的扩散是通过"两段吸收"来进行的,通过浸泡初期lnCc-t0.5曲线上的线性段求得了水在涂层中的表观扩散系数值.根据电化学阻抗谱中Cl-参与成膜阻抗出现时间求得Cl-在环氧涂层中的扩散系数值为4.67×10-12@cm2s-1.受涂层吸水的影响,涂层电容上升与涂层电阻下降主要发生在浸泡初期,而涂层电极开路电位(Eoc)值的变化贯穿整个浸泡过程.开路电位值经历4个变化阶段:在前期Eoc急剧上升,随后上升速度变缓,在中后期Eoc上升速率再次增大,在浸泡后期Eoc值开始下降,金属基体发生活化,涂层失效.实验表明,含Cl-盐膜的形成、生长及溶解等过程与Eoc间存在密切关系,在LY12铝合金/环氧体系的失效过程中起到关键作用.
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