在含V和Nb的40Cr钢中添加不同质量分数(0-1.54%)的Mo元素,采用缺口拉伸试样和改进的M-WOL型试样研究了Mo对高强度钢延迟断裂行为的影响.结果表明,随着Mo含量的增加,实验钢的延迟断裂抗力逐渐提高;当Mo含量超过1.15%时,延迟断裂抗力不再提高.EDS分析结果表明,钢中Mo元素在晶界发生偏聚,偏聚范围在几个纳米尺度内.通过电子能量损失谱(EELS)证明,Mo元素在原奥氏体晶界的偏聚能够提高钢的晶界结合强度.在钢中添加Mo能够显著提高钢的回火抗力和晶界结合强度,这是其具有高的延迟断裂抗力的主要原因.碳化物Mo2C对氢的捕集作用亦能够提高钢的延迟断裂抗力.Mo和V元素的二次硬化碳化物在半共格和非共格状态时,实验钢的延迟断裂抗力显著提高.
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