弛豫型铁电体PZNT制备与性能研究的进展

无机材料学报, 1999, 14(1): 1-11. doi: 10.3321/j.issn:1000-324X.1999.01.001

弛豫型铁电体PZNT制备与性能研究的进展

许桂生 ^1, , 罗豪 ^2, , 齐振一 ^3, , 徐海清 ^4, , 殷之文 ^5,

1.中国科学院无机功能材料开放实验室,中国科学院上海硅酸盐研究所,上海,200050

2.中国科学院无机功能材料开放实验室,中国科学院上海硅酸盐研究所,上海,200050

3.中国科学院无机功能材料开放实验室,中国科学院上海硅酸盐研究所,上海,200050

4.中国科学院无机功能材料开放实验室,中国科学院上海硅酸盐研究所,上海,200050

5.中国科学院无机功能材料开放实验室,中国科学院上海硅酸盐研究所,上海,200050

关键词： PZNT , 单晶 , 压电性能 , 电致伸缩应变

Progress in Studies on Fabrication and Properties of PZNT Relaxor Ferroelectrics

本文综述了近年来国际上弛豫型铁电体PZNT的制备与介电、压电及电致伸缩性能研究的进展. PZNT单晶体的制备方法以高温PbO熔剂法为主,其尺寸已达40mm. 随PT含量的变化,PZNT的顺电-铁电相变由弥散性、混合型变为一级相变;其铁电-铁电相变可由组份或电场诱导,由介电性能表征. 压电性能在MPB 处及偏向三方相一侧达到最佳,<001>切向的三方相与四方相单晶可分别作为频带宽、分辨率高、且阻抗匹配好的新一代声阵列与单个器件传感器.<001>向的PZNT 单晶具有巨大的电致伸缩应变,可望成为高性能的固体驱动器.

参考文献

[1]	Yamamoto T, Terashima Y. Jpn. Appl. Phys., 1992, 31: 3252-3256
[2]	Nomura S, et al. J. Phys. Soc. Jpn., 1969, 27: 262
[3]	Takenaka T, et al. Ferroelectrics, 1992, 134: 133-138
[4]	Isupov V A, et al. Soviet Phys. Tech, Phys., 1956, 1: 1846-1849
[5]	Smolenskii G A. J. Phys. Soc. Jpn., 1970, 28: 26-31
[6]	Chang Z P, et al. 6th Proc. IEEE int. Symp. Appl. Ferroelectrics, 1986. 482-484
[7]	Shrout T R, Halliyal A. Am. Ceram. Soc. Bull., 1987, 66: 704-711
[8]	Bokov V A, et al. Soviet Physics-Solid State, 1961, 2: 2428-2430
[9]	Sasaki H, Hayakawa S. Growth of single crystal of Pb(Zn1/3Nb2/3)O3 and its properties; The 11th Annual Meeting of Symposium on Synthetic Minerals, Sendai, Japan, October 1966
[10]	Yokomizo Y, et al. J. Phys. Soc. Jpn., 1970, 28: 1278-1284
[11]	Kuwata J, et al. Ferroelectrics, 1981, 37: 579-582
[12]	Mulvihill M L, et al. Jpn. J. Appl. Phys., 1996, 35: 3981-3990
[13]	Kuwata J, Uchino K, Nomura S. Ferroelectrics, 1979, 22: 863-866
[14]	Matsuo Y, et al. J. Am. Ceram. Soc., 1969, 52: 516-517
[15]	Kobayashi T, et al. Jpn. Appl. Phys., 1997. 36
[16]	Jang H M, et al. J. Am. Ceram. Soc. 1992, 75: 82-88
[17]	Krainik N N, et al. Soviet Physics-Solid State, 1971, 12: 1885-1887
[18]	Halliyal A, et al. Stabilization of perovskite phase and dielectric properties of ceramics in the Pb(Zn1/3Nb2/3)O3-BaTiO3 system, unpublished work
[19]	Belsick J, Thesis B S. Pennsylvania State University, 1986
[20]	Nomura S, Arima H. Jpn. J. Appl. Phys., 1977, 11: 358-362
[21]	Hanh L, Nomura S. Jpn. J. Appl. Phys., 1976, 15: 1059-1064
[22]	Jaffe B, et al. Piezoelectric Ceramics, Academic, New York, 1971. 237-242
[23]	Lanagan M, Anderson D, Moffatt D. unpublished work
[24]	Kuwata J, et al. Jpn. J. Appl. Phys., 1982, 21: 1298-1305
[25]	Park S E, Shrout T R. IEEE Trans. on Ultrasonic, Ferroelectric and Frequency Control, 1997, 5: 1140-1147
[26]	Park S E, Shrout T R. Relaxor based ferroelectric single crystals for electro-mechanical actuators, to be published
[27]	Park S E, et al. Relaxor-based single crystal materials for ultrasonic transducer application, to be published in Innovations in Materials Research.
[28]	Arora A K, et al. Ferroelectrics, 1992, 132: 9-25
[29]	Nye J F. Physical Properties of Crystals. Oxford University Press. Oxford: Clarendon Press, 1957
[30]	Berlincourt D A, et al. Piezoelectric and piezomagnetic materials and their function in transducers, New York: Academic Press, 1964, p169 in Physical Acoustics, Volume 1A, edited by Mason W P
[31]	Wi S K, Kim H G. Ferroelectrics, 1992, 132: 225-232
[32]	Park J H, et al. Mater. Res. Bull., 1995, 30: 435-441
[33]	Kumar U, et al. J. Am. Ceram. Soc. 1992, 75: 2155-2164
[34]	Nomura S, Uchino K. Ferroelectrics, 1982, 41: 1117-1132
[35]	Kumar U, et al. Modified lead zinc niobate ceramic electrostrictor for micropositioner applications, p633-636 in Proceedings of Sixth IEEE Symposium on Applications of Ferroelectrics. Lehigh University, Bethlehem, PA, 1986

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弛豫型铁电体PZNT制备与性能研究的进展

Progress in Studies on Fabrication and Properties of PZNT Relaxor Ferroelectrics

参考文献