采用复阻抗方法，系统地研究了BaTiO3基PTCR陶瓷的电性能．通过Cole-Cole图，计算了样品的晶粒、晶界电阻值和弛豫时间常数，同时利用Heywang模型估算了势垒高度．Cole-Cole图分析表明，随着测试温度的提高，Cole-Cole圆将从单半圆向双扭线过渡，表明在居里温度附近，由于热激活出现了不同的缺陷类型．实验结果表明了PTC效应是一种晶界效应，晶粒电阻随温度的变化呈NTC特性，而晶界电阻却呈明显的PTC特性．Heywang模型作为经典的理论模型，经过不断的完善，至今仍能对陶瓷材料PTC现象的宏观机制做出明确的解析．
Complex impedance spectra of BaTiO3 with boron addition on the electrical characteristics of PTCR were studied. Cole-Cole plot shows a single semicircle in room temperature (T < Tc) but shows a overlapping semicircle and skew circle above the Curie temperature (Tc < T < Tm), which may indicate relaxational processes with multiple defects, such as VBa,Vo etc, from single defect such as VBa by thermal activation in the regions of the grain boundary layer. The grain resistance, grain boundary resistance and relaxational time constant were calculated from the Cole-Cole plot and the barrier height was calculated by the Heywang model. The results show that PTC effect originates from the grain boundary. The grain resistance exhibits NTC, but the grain boundary resistance shows obviously PTC. Up to date, the Heywang model or Heywang-Jonker model is the most accepted model to explain the PTC mechanism by phenomenal explanation.
参考文献
| [1] | Heywang W. Solid State Electron, 1961, 3 (1): 51 |
| [2] | Jonker G H. Solid State Electron, 1964, 7 (2): 895-903. |
| [3] | Daniels J, Wernicke R. Philips Res. Rep., 1976, 31 (6): 544-559. |
| [4] | Amin A. J. of Amer. Ceram. Soc., 1989, 72:369 |
| [5] | Wang D Y, Umeya K. ibid, 1990, 73:669 |
| [6] | Nemoto H, et al. ibid, 1980, 63:398 |
| [7] | Kutty T R N, et al. Mat. Res. Bull., 1985, 20:565 |
| [8] | Roseman R D, et al. Ferroelectrics, 1996, 177 (3/4): 273-282. |
| [9] | Bauerle J E. J. Phys. Chem. Solids, 1969, 30:2657 |
| [10] | Cole K S, Cole R H. J. Chem. Phys., 1941, 9:341 |
| [11] | Hari N S, Padmini P, kutty T R N. J. of Mater. Sci.: Mater. in Electronics, 1997, 8: 15-22. |
| [12] | Bottcher C J F, Bordwigk P. Theory of Electric Polarization. Elservier Scientific Publishing Company,1978. |
| [13] | Wang G M, Lei J H, Du H L. Functional Mat., (in Chinese) 1996, 27 (5): 415-420. |
| [14] | Zhang Z T, Qi J Q, Tang Z L, et al. J of Chinese Ceram. Soc., (in Chinese) 1996, 24 (1): 100-104. |
| [15] | Lu Y Y, Tseng T Y. Mater. Chem. and Phys., 1998, 53: 132-137. |
| [16] | Maiti H S, Basu R N. Mat. Res. Bull., 1986, 21: 1107-1114. |
| [17] | Davidson D W, Cole R H, J. Chem. Phys., 1950, 18: 1417; 1951, 19:1484 |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%