尖晶石LiMn2O4是最有希望替代LiCoO2的新一代锂离子电池阴极材料.本文对其晶体结构进行了详细的描述;综合评述了近年来各种制备LiMxMn2-xO4的方法,包括高温固相反应、微波烧结法、固相配位反应等“固相合成法”以及Pechini法、溶胶-凝胶法、微乳化等“软化学合成法”.并对各方法的优缺点进行了分析对比.其中“固相配位反应法”是本文作者的创新方法,既保持了高温固相反应法操作简便、易于工业化生产的的优点,同时也具有煅烧温度低、煅烧时间短、产品形貌较好、粒度相对较小、而且化学计量可控等优点.因此,该法具有十分巨大的潜在应用价值.
参考文献
| [1] | 康慨,戴受惠,万玉华.核科技报告,2000,CNIC-01466:1-9. |
| [2] | 周恒辉,慈云祥,刘昌炎.化学进展,1998,10(1):85-94. |
| [3] | 尹大川,王猛,黄卫东.功能材料,1999,30(6):591-594. |
| [4] | Haringer D, Novak P, Haas O, et al. Proc Electrochem Soc., 1998, 16: 296-305. |
| [5] | Kanno R. Mater. Integ., 1999, 12 (3): 13-16 (Japanese). |
| [6] | 康慨,戴受惠,万玉华.功能材料,2000,31(3):283-286. |
| [7] | Hayashi N, Ikuta H, Wakihara M. J. Electrochem Soc., 1999, 146 (4): 1351-1354. |
| [8] | Ammundsen B, Uchiyama T, Itoh T, et al. Langmuir, 1999, 15 (15): 4949-4951. |
| [9] | Frison J C, Hwang S J, Song S W, et al. J. Phys. Chem. B, 1999, 103 (2): 2100-2106. |
| [10] | Hong S J, Chang S H, Yo C H. Bull. Korean. Chem. Soc., 1999, 20 (1): 53-58. |
| [11] | 崔万秋,杨丽芬.功能材料,1998,29(1):378-380,428. |
| [12] | 王要武,阴晓东,徐仲榆.电池,1999,29(2):51-53. |
| [13] | Hasezaki K, Kamada M. Funtai Oyobi Funmatsu Yakin, 1999, 46 (3): 317-320 (Japanese). |
| [14] | Kachibaya E, Japaridze L, Akhvlediani R, et al. Bull. Georgian Acad. Sci., 1998, 157 (3): 428-431. |
| [15] | Saravanan T, Stephan A M, Thirunakaran R, et al. Bull. Electrochem, 1998, 14 (8-9): 286-288. |
| [16] | Hu X H, Ai X P, Yang H X, et al. J. Power Sources, 1998, 74 (2): 240-243. |
| [17] | Siapkas D I, Mitsas C, Samaras I, et al. J. Power Sources, 1998, 72 (1): 22-26. |
| [18] | 卢集政,赖琼钰.化学研究与应用,1998,10(6):620-623. |
| [19] | 严宏伟,陈立泉,黄学杰,等.发明专利公开说明书,1997,CN1143267A,7pp. |
| [20] | Liu W, Kowal K, Farrington G C. J. Electrochem Soc., 1998, 145 (2): 459-465. |
| [21] | Wang G X, Bradhurst D H, Liu H K, et al. Solid State Ionics, 1999, 120 (4): 95-101. |
| [22] | Huang H, Bruce P G. J. Power Sources, 1995, 54: 52-56. |
| [23] | Tsumura T, Inagaki M. Solid State Ionics, 1997, 104 (1,2): 35-43. |
| [24] | Vogler C, Dittrich H, Arnold G, et al. Ionics, 1998, 4 (3-4): 285-298. |
| [25] | Ikuhara Y H, Iwamoto Y, Kikuta K, et al. J. Mater. Res., 1999, 14 (7): 3102-3110. |
| [26] | Hong Y S, Park H B, Yi J E, et al. Bull. Korean Chem. Soc., 1997, 18 (11): 1153-1158. |
| [27] | Yang W S, Liu Q G, Qiu W H, et al. Solid State Ionics, 1999, 121 (1-4): 79-84. |
| [28] | 刘培松,刘兴泉,陈召勇,等.应用化学,2000,17(1):60-62. |
| [29] | Choy J H, Kim D H, Kwon C W, et al. J. Power Sources, 1999, 77 (1): 1-11. |
| [30] | Sun Y K, Kim D W, Jin S H, et al. Korean J. Chem. Eng., 1998, 15 (1): 64-70. |
| [31] | Sun Y K, Kim D W, Choi Y M. J. Power Sources, 1999, 79 (2): 231-237. |
| [32] | Sun Y K, Oh I H, Choi J W. J. New Mater. Electrochem Syst, 1999, 2 (1): 51-57. |
| [33] | Kweon H J, Kim S S, Kim G B, et al. J. Mater. Sci. Lett., 1998, 17 (20): 1697-1701. |
| [34] | Lee Y S, Sun Y K, Nahm K S. Solid State Ionics, 1998, 109 (3,4): 285-294. |
| [35] | Prabaharan S R, Saparil N B, Michael S S, et al. Solid State Ionics, 1998, 112 (1,2): 25-34. |
| [36] | Noguchi Xia Y, H. et al. J. Solid State Chem., 1995, 119: 216. |
| [37] | Takada I, Enoki H, Hayakawa H, et al. Key Eng. Mater., 1999, 157-158: 297-302. |
| [38] | Tsang C, Manthiram A. Solid State Ionics, 1996, 89 (3,4): 305-312. |
| [39] | Peramunage D, Abraham K M. J. Electrochem Soc., 1998, 145 (4): 1131-1136. |
| [40] | Hwang K T, Um W S, Lee H S, et al. J. Power Sources, 1998, 74 (2): 169-174. |
| [41] | Kim M K, Chung H T, Um W S, et al. Mater. Lett., 1999, 39 (3): 133-137. |
| [42] | 杨书廷,张焰峰,吕庆章,等(YANG Shu-Thing, et al).无机材料学报(Journal of Inorganic Materials),2000,15(2):309-314. |
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