在0.5～1050K温度区间,ZrW2O8具有强烈的各向同性"负热膨胀"(NTE)效应,其负热膨胀可由骨架结构中存在低能刚性单元模型(RUMs)来解释.本文综述了近几年来对ZrW2O8负热膨胀特性及其负热膨胀机理的研究,并对其相变及相变机制做了综述.
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