多元金属二硫化物纳米管的制备与结构特征

无机材料学报, 2004, 19(3): 481-486. doi: 10.3321/j.issn:1000-324X.2004.03.006

多元金属二硫化物纳米管的制备与结构特征

李国华 ^1, , 曾跃武 ^2, , 宋旭春 ^3, , 夏军保 ^4, , 陈卫祥 ^5, , 徐铸德 ^6,

1.浙江大学化学系,杭州,310027;浙江工业大学化学工程与材料学院,杭州,310014

2.浙江大学分析测试中心,杭州,310027

3.浙江大学化学系,杭州,310027

4.浙江大学化学系,杭州,310027

5.浙江大学化学系,杭州,310027

6.浙江大学化学系,杭州,310027

基金项目: 国家自然科学基金(20171039;50171063)

关键词：多元金属二硫化物 , 剥离-重新堆垛-结构控制 , 纳米管 , 结构特征

Fabrication of Multimetal Disulfide Nanotube and Its Structural Characteristics

为解决无机类富勒烯纳米化合物的制备过程中存在的技术问题,本文以二硫化钼和二硫化钨为主要原料,采用了剥离-重新堆垛-结构控制这一技术方法,用正丁基锂将上述二硫化物剥离成单层,通过掺杂将金属锰离子引入反应体系中,以将单层二硫化物重新堆垛起来,并进行结构控制.XRD、TEM、HRTEM结果表明,应用上述方法制备出了真空管状多元金属二硫化物纳米化合物;纳米管为多壁管,其微细结构具双层结构特征;并探讨了其形成机理.

参考文献

[1]	Tenne R, Margulis L, Genut M, et al. Nature, 1992, 360: 444-446.
[2]	Margulies L, Salitra G, Tenne R, et al. Nature, 1993, 365: 113-114.
[3]	Feldman Y, Wasserman E. Srolovitz D J, et al. Science, 1995, 267: 222-225.
[4]	Chang Yu-Chi, Chang Ying-yin, Lin Chun-I. Electrochimica Acta., 1998, 43 (3-4): 315-324.
[5]	Srivastava S K, Mandal T K, Samantaray B K. Synthetic Metals, 1997, 90: 135-142.
[6]	Zhan J H, Zhang Z D, Qian X F, et al. J. of Solid State Chemistry, 1998, 141: 270-273.
[7]	Vollath D, Szabo D V. Materials Letters, 1998, 35: 236-244.
[8]	Alperson Boaz, Homyonfer Moshe, Tenne Reshef. J. of electroanalytical Chemistry, 1999, 473: 186-191.
[9]	Chu Gaosheng, Bian Guozhu, Fu Yilu, et al. Materials Letters, 2000, 43: 81-86.
[10]	Afanasievm Pavel, ChristopheGeantetChristophe, Thomazeau Cecile, et al. Chem. Commun., 2000. 1001-1002.
[11]	Thomazeau Cecile, Geantet Christophe, Lacroix Michel Lacroix, et al. J. of Solid State Chemistry, 2001,160: 147-155.
[12]	Nath Manashi, Mukhopadhyat K, Rao C N R. Chemical Physics Letters, 2002, 352: 163-168.
[13]	Peng Yiya, Meng Zhaoyu, Zhong Chang, et al. Materials Chemistry and Physics, 2002, 73: 327-329.
[14]	Li Yadong, Li Xianlin, He Ronggrui, et al. J. AM. CHEM. SOC., 2002, 124: 1411-1416.
[15]	Feldman Y, AzAK, Popovitz-Biro R, et al. Solid State Science, 2000, 2: 663-672.
[16]	Rouxel Jean. Mat. Res. Bull., 1978, 13: 1425-1431.
[17]	Srivastava S K, Avasthi B N. J. of Scientific and Industrial Research, 1982, 41: 656-664.
[18]	Py M A, tIaering R R. National Research Council of Canada, 1983, 10: 76-81.
[19]	Srivastava Suneel Kunar, Avasthi Bhola Nath. J. of Materials Science Letters, .1994, 3: 671-673.
[20]	Srivastava Suneel Kunar, Avasthi Bhola Nath. Synthetic Metals, 1985, 11: 193-205.
[21]	Srivastava Suneel Kunar, Avasthi Bhola Nath. Synthetic Metals, 1985, 10: 213-221.
[22]	Joensen Per, Frindt R F, Morrison S Roy. Mat. Res, Bull., 1986, 21: 457-461.
[23]	Joensen P, Croozier E D, Alberding N, et al. J. Phys. C: Solid State Phys., 1987, 20: 4043-4053.
[24]	Sekine T, Julien C, Samaras I, et al. Materials Science and Engineering, 1989, B3: 153-185.
[25]	Chrissafis K, Zamani M, Kambal K, Materials Science and Engineering, 1989 B3: 145-151.
[26]	Zubavichus Yah V, Slovokhotov Yrii L, Schilling Paul J. et al. Inorganic Chimica Acta., 1998, 280: 211-218.
[27]	Golub A S, Shumilova I B, Zubavichus Y V, et al. Solid State Inoica., 1999, 122: 137-144.
[28]	Zubavichus Y V, Golub A S, Leninko N D, et al. Materials Research Bulletin, 1999, 34 (10/11): 1601-1613.
[29]	Pandey K K. J. of Molecular Structure (Theochem), 1999, 491: 231-235.
[30]	Zhao Yongfang, Jing Xiaogong, Su Wenhui. J. of molecular Structure (Theochem), 2002, 587: 43-48.

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多元金属二硫化物纳米管的制备与结构特征

Fabrication of Multimetal Disulfide Nanotube and Its Structural Characteristics

参考文献