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以烯丙基化合物改性双马来酰亚胺为基体,通过加入聚醚砜树脂(PES),制得了适用于树脂膜熔渗(RFI)工艺的高性能树脂基体膜。该树脂膜性质稳定,能满足RFI工艺要求。其固化树脂耐热性及力学性能优良;所制得的玻璃布复合材料综合性能优异;常温下弯曲强度、层间剪切强度分别达到535 MPa和55.5 MPa。

Based on the modification of bismaleimide by allyl compound, a new type of high performance resin film which is suitable for resin film infusion (RFI) process is synthesized by employing poly(ethersulfone)(PES).The film is stable at room temperature and shows good properties of toughness and inadhesiveness. The main properties of the cured resin are 535 MPa for flexural strength, 16.7 MPa for impact strength, and 236 ℃ for HDT. It can be seen that flexural strength and impaet strength are much better than X4502 which is reported in Refs.[8], and HDT is a little less than that in Refs.[8].Comparitions were also reported for composite samples of same resin and fibre systems which were processed using the wet lay-up with autoclave consolidation and RFI. The result shows that the matrix dominated property(i.e. ILLS) is higher for the RFI samples due to the reduced void content and improved wetting, and the fibre dominated properties are similar due to the similar volume fraction. The glass fibre cloth composite manufactured by RFI has execellent synthetical performance.

参考文献

[1] [1] Nguyen Loc B, Juska Thomas, Mayes Steven. Evaluation of low cost manufacturing technologies for large scale composite ship structures. Collection of Technical Papers-AIAA/ASME/ASCE/AHE/ASC Structures, Structural Dynamics & Materials Conf. New York:AIAA, 1997. 992-1001.
[2] [2] Krusche T, Michaeli W. Resin infusion technology for the autoclave process[J]. Int SAMPE Symp & Exhibition, 1996, 41(2): 1542-1550.
[3] [3] Marsh George. Putting SCRIMP in context[J]. Reinforced Plastics, 1997, 1:22-26.
[4] [4] Pfund  Bruce. Resin infusion in the US marine industry[J]. Reinforced Plastics, 1994, 12:32-34.
[5] [5] Lazarus Paul. Resin infusion of marine composites[J]. Int SAMPE Symp & Exhibition, 1996, 41(2): 1447-1458.
[6] [6]  Williams Christopher, Summerscales John, Grove Stephen. Resin infusion under flexible tooling: a review[J]. Composites-Part A: Applied Science & Manufacturing, 1996, 27(7): 517-524.
[7] [7] Alfred C L, John D M, David Hood, et al. Resin film infusion process simulation of complex shaped composite structures. Collection of Technical Papers-AIAA/ASME/ASCE/AHS Structures, Structural Dynamics & Materials Conf. New York: AIAA,1996. 1828-1837.
[8] [8] 梁国正,顾嫒娟. 双马来酰亚胺树脂[M]. 北京:化工工业出版社,1997.57-96
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