根据电子束固化复合材料树脂体系的原理,从引入辐敏性的基团入手,合成了含硅丙烯酸酯的活性稀释剂、芳香族酰亚胺活性单体、含丙烯酸的PMR型聚酰胺酸和单官能、双官能的马来酰亚胺单体.在此基础上,对合成所得到的产物和几种环氧树脂进行了辐射交联实验,并考察与分析了不同树脂的辐射固化反应行为.与此同时对合成所得产物进行了表征,对固化物性能进行初步测试.所得研究结果,对电子束固化树脂体系的进一步研究具有重要的参考价值.
The use of electron beams to initiate polymerization reactions is an area on which much interest has focused. The curing of vinyl monomers such as acrylates and maleimides by means of high energy electron beam irradiation normally proceeds via a free-radical mechanism. While e-beam-induced polymerization of epoxy resins proceeds via a cationic mechanism in the presence of an appropriate photoinitiator. This work investigated the synthesis of new maleimide,aromatic imide monomers,active PMR polyamide acid and silaceous acrylates containing vinyl groups. The cure activity of these vinyl monomers was conducted, so as the epoxy resins. The results suggested that the potential curability exists in the active groups and the structure of the chain.
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