研究了玻璃微珠增强硬质聚氨酯泡沫塑料的制备、微观结构、压缩性能和热稳定性.结果表明:当玻璃微珠含量为10%时,增强泡沫塑料的压缩强度和压缩模量达到最大;经过硅烷偶联剂表面处理的玻璃微珠增强的泡沫塑料的压缩强度和压缩模量提高幅度较大,起始分解温度和峰值分解温度也有一定程度的提高.SEM、XPS和EDS分析表明:增强泡沫塑料的泡孔密度增加、泡孔直径变小,玻璃微珠表面与树脂基体间界面粘结状况良好,玻璃微珠在树脂基体中均匀分散.这些因素是造成玻璃微珠增强泡沫塑料压缩性能和热稳定性具有较大改善的原因.
参考文献
[1] | 李国忠.玻璃纤维增强硬质聚氨酯泡沫塑料的微观结构及破坏机理研究[J].复合材料学报,1996,13(2):17-21.Li Guozhong.Research of the micro-structure and destructive mechanism of the rigid polyurethane foam-plastics reinforced by glass fibers[J].Acta Materiae Compositae Sinica,1996,13(2):17-21. |
[2] | 卢子兴,王建华,谢若泽,等.增强聚氨酯泡沫塑料力学行为的研究[J].复合材料学报,1999,16(2):39-45.Lu Zixing,Wang Jianhua,Xie Ruoze,et al.Investigation into mechanical behavior of two reinforced foam plastics[J].Acta Materiae Compositae Sinica,1999,16(2):39-45. |
[3] | 闻荻江,陈再新,李国忠.玻璃纤维增强灌注型聚氨酯泡沫塑料的拉伸、压缩性能和破坏机理[J].复合材料学报,1999,16(4):64-67.Wen Dijiang,Chen Zaixin,Li Guozhong.Stretching and compressing destructive mechanism of the polyurethane foam-plastics reinforced by glass fibers[J].Acta Materiae Compositae Sinica,1999,16(4):64-67. |
[4] | 王建华,芦艾,周秋明,等.短切玻璃纤维增强硬质聚氨酯泡沫塑料的压缩性能[J].高分子材料科学与工程,2001,17(3):150-153.Wang Jianhua,Lu Ai,Zhou Qiuming,et al.Compressing properties of rigid polyurethane foam reinforced by short-cut glass fibers[J].Polymer Materials Science and Engineering,2001,17(3):150-153. |
[5] | 龚宪生,唐一科,景军平.增强泡沫塑料隔振器动态性能的实验研究[J].复合材料学报,2003,20(5):135-141.Gong Xiansheng,Tang Yike,Jing Junping.Experimental investigations on dynamic performance of vibration isolator made of reinforced foam plastics[J].Acta Materiae Compositae Sinica,2003,20(5):135-141. |
[6] | 芦艾,黄锐,王建华,等.纳米碳酸钙对硬质聚氨酯泡沫塑料力学性能的影响[J].中国塑料,2001,15(8):28-31.Lu Ai,Huang Rui,Wang Jianhua,et al.Influences of nanoCaCO3 on mechanical properties of rigid polyurethane foam[J].China Plastics,2001,15(8):28-31. |
[7] | 卢子兴,袁应龙.高应变率加载下增强泡沫塑料的吸能特性及失效机理研究[J].复合材料学报,2002,19(5):114-117.Lu Zixing,Yuan Yinglong.Investigation into the energy absorption and failure characteristics of syntactic foams at high strain rates[J].Acta Materiae Compositae Sinica,2002,19(5):114-117. |
[8] | 周秋明,王建华,田春蓉,等.空心玻璃微珠复合聚氨酯泡沫的模塑成型收缩率[J].塑料工业,2002,30(5):23-31.Zhou Qiuming,Wang Jianhua,Tian Chunrong,et al.Molding shrinkage of polyurethane foam filled with hollow glass bead[J].China Plastics Industry,2002,30(5):23-31. |
[9] | 高四,王军,王亦菲,等.纳米二氧化钛增强硬质聚氨酯泡沫塑料的制备[J].材料工程,2004(2):3-9.Gao si,Wang Jun,Wang Yifei,et al.Preparation of nano titanium dioxide reinforced rigid polyurethane foam[J].Materials Engineering,2004(2):3-9. |
[10] | Yang Zhenguo,Zhao Bin,Qin Sanglu,et al.Study on the mechanical properties of hybrid reinforced rigid polyurethane composite foam[J].J Appl Polym Sci,2004,92(3):1493-1500. |
[11] | 粱基照,李国耀.玻璃微珠表面处理对LDPE增强泡沫塑料拉伸性能的影响[J].复合材料学报,2000,17(1):19-22.Liang Jizhao,Li Guoyao.Effects of glass bead surface treatment on the tensile properties of filled LDPE composites[J].Acta Materiae Compositae Sinica,2000,17(1):19-22. |
[12] | 李春娥,王政,文闻,等.环氧树脂-聚酰胺玻璃微珠体系的固化[J].复合材料学报,2000,17(4):11-14.Li Chune,Wang Zheng,Wen Wen,et al.Cure behavior of epoxy-polyamide-glass microball systems[J].Acta Materiae Compositae Sinica,2000,17(4):11-14. |
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