以十六烷基三甲基溴化铵为插层剂,用球磨法对蛭石进行了快速有机插层,用过熔融共混法制备出纳米有机蛭石/天然橡胶复合材料.用XRD、SEM、TEM对其微观结构进行了表征与分析,证明蛭石以纳米片层分散在天然橡胶基体中.力学性能测试表明:复合材料拉伸强度、扯断伸长率、300%定伸强度、邵氏A硬度、撕裂强度得到明显的改善.DMA、DSC测试表明:复合材料的模量具有明显的提高,而玻璃化转变温度无明显变化.可见有机插层蛭石对天然橡胶的综合性能具有较明显的改善作用.
参考文献
[1] | Pinnavaia T J.Intercalated clay catalysts[J].Science,1983,220(4595):365-371. |
[2] | LeBaron P C,Wang Z,Pinnavaia T J.Polymer layered silicate nanocomposites:An overview[J].Applied Clay Science,1999,15(1-2):11-29. |
[3] | Wang Z,Pinnavaia T J.Nanolayer reinforcement of elastomeric polyurethane[J].Chemistry of Materials,1998,10(12):3769-3771. |
[4] | 王新宇,漆宗能,王佛松.聚合物-层状硅酸盐纳米复合材料制备及应用[J].工程塑料应用,1999,27(2):1-5.Wang Xinyu,Qi Zongneng,Wang Fosong,et al.Preparation and application of polymer layered silicate nanocomposites[J].Engineering Plastics Application,1999,27(2):1 -5. |
[5] | Vaia R A,Jandt K D,Kramer E J,etal.Microstructural evolution of melt intercalated polymer-organically modified layered silicates nanocomposites[J].Chemistry of Materials,1996,8(11):2628-2635. |
[6] | Messersmith P B,Giannelis E P.Synthesis and barrier properties of poly (ε-caprolactone)-layered silicate nanocomposites[J].Journal of Polymer Science Part A:Polymer Chemistry,1995,33(7):1047-1057. |
[7] | Vaia R A,Teukolsky R K,Giannelis E P.Interlayer structure and molecular environment of lkylammonium layered silicates[J].Chemistry of Materials,1994,6(7):1017-1022. |
[8] | Wu J H,Lerner M M.Structural,thermal and electrical characterization of layered nanocomposites derived from Na-mont morillonite and polyethers[J].Chemistry of Materials,1993,5(6):835-838. |
[9] | 王濮,潘兆橹,翁玲宝,等.系统矿物学(中册)[M].北京:地质出版社,1984.464-465.Wang Pu,Pan Zhaolu,Weng Lingbao,et al.Systematic Mineralogy (Second volume)[M].Beijing:Geological Press,1984.464-465. |
[10] | Shelly D B,Hsien C W,Emmanuel P G.Direct polymer intercalation in single crystal vermiculite[J].Chemistry of Materials,1999,11(4):1055-1060. |
[11] | Mekhamera W K,Assaadb F F.Thermodynamics of Sr± Mg vermiculite exchange and the effect of PVA on Mg release[J].ThermochimicaActa,1999,334(1-2):33-38. |
[12] | 王可,朱湛,郭炳南.聚对苯二甲酸乙二醇酯/蛭石纳米复合材料的制备[J].应用化学,2003,20(7):709-711.Wang Ke,Zhu Zhan,Guo Bingnan.Preparation of polyethy lene terephthalate/vermieulite nanocomposite[J].Chinese Journal of Applied Chemistry,2003,20(7):709-711. |
[13] | 叶朝阳,顾宜.苯并噁嗪中间体/蛭石插层纳米复合物热固化行为的研究[J].高分子学报,2004(2):208-212.Ye Zhaoyang,Gu Yi.Study on curing behavior of poly benzoxaine/verminculite nanocomposites[J].Acta Polymerica Sinica,2004(2):208-212. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%