采用反气相色谱法,于343.15 K到363.15 K温度下测定了双阳离子型离子液体1,10-双(N-甲基咪唑鎓)癸烷六氟磷酸盐[C10(MIM)2][PF6]2的溶解度参数.以正辛烷、正十二烷、正十四烷和正十六烷为探针溶剂,计算了探针溶剂的特性保留体积(V0g)、摩尔吸收焓(ΔHS1)、无限稀释摩尔混合焓(ΔH∞1)、摩尔蒸发焓(ΔHv)、无限稀释活度系数(γ∞12)以及探针溶剂与[C10(MIM)2][PF6]2的Flory-Huggins相互作用参数(χ∞12),测得该离子液体的溶解度参数(δ2)为15.01 (J\5cm-3)1/2.这一结果对研究离子液体的溶液性质和应用有指导作用.
参考文献
[1] | Wang J,Yang X Z,Li G S,et al.Ionic liquids-properties and applications.Beijing:China Textile Press (王军,杨许召,李刚森,等.离子液体的性能及应用.北京:中国纺织出版社),2007 |
[2] | Kou Y,He L.Progress in Chemistry (寇元,何玲.化学进展),2008,20(1):5 |
[3] | Giridhar P,Venkatesan K A,Srinivasan T G,et al.Desalination,2008,232(1/2/3):11 |
[4] | Pena M A,Reíllo A,Escalera B,et al.Int J Pharm,2006,321(1/2):155 |
[5] | Martin J R,Shapella B D.Exp Fluids,2003,34:535 |
[6] | Barton A F M.Chem Rev,1975,75:731 |
[7] | Ma P S.Chemical engineering data.Beijing:China Petrochemical Press (马沛生.化工数据.北京:中国石化出版社),2003:121,217 |
[8] | Sun Z J,Zhang X Y,Huang H,et al.China Rubber Industry (孙志娟,张心亚,黄洪,等.橡胶工业),2007,54(1):54 |
[9] | Mutelet F,Jaubert J N.J Chem Thermodyn,2007(39):1 144 |
[10] | Li K H,Chen Z Y,Zhang S W,et al.Chinese Journal of Analytical Chemistry (李凯慧,陈志瑶,张少文,等.分析化学),2007,35(4):511 |
[11] | Topaloglu Yazici D,Askin A,Butun V.Chromatographia,2008,67:741 |
[12] | Zhao S,Zhang W W,Zhang F,et al.Polym Bull,2008,61:189 |
[13] | Poliny B E,Praushitz J M,Oconnell J P.The properties of gases and liquids.5th ed.New York,NY:McGraw-Hill Professional Publishing,2006:100 |
[14] | Thomson G W.Chem Rev,1946,38(1):1 |
[15] | Lemmon E W,Goodwin A R H.J Phys Chem Ref Data,2000,29(1):1 |
[16] | Barton A F M.CRC handbook of solubility parameters and other cohesion parameters.2nd ed.Boca Raton,Florida:CRC Press,1991 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%