评述了纳米碳管(CNT)的纳米孔隙结构及其决定的特殊物化性质,以及潜在的应用.CNT孔径体系由多层次的孔隙组合而成,开口的一维中空管腔是最基本的孔隙结构,其纳米级的尺度和物理形态决定了它的超常吸附性质和其它物化特性,使CNT成为极具潜力的纳米级能量载体;提供了进行一维物理化学过程的极限反应空间,是真正意义上的纳米反应器;CNT的比表面积和孔径结构及其决定的吸附性质还决定或者影响着许多其它物化性质(如电磁性质).发展纳米碳管中的物理化学研究,制备基于大表面积、可控孔结构CNT的纳米器件,是CNT领域的重要研究方向.
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