本文对热致液晶聚合物(TLCP)/玻璃纤维(GF)/聚丙烯(PP)原位混杂复合材料的形态结构、破坏过程、力学性能进行了研究.显微镜的观察结果表明,TLCP的加入使得加工过程中玻纤的破断减弱.TLCP/GF/PP原位混杂复合材料中GF的平均长度是GF/PP复合材料的2.36倍,这使其主承载作用更显著.使用带拉伸实验台的扫描电镜观察到了TLCP微纤或微球对微裂纹扩展的阻滞及延缓作用.TLCP/GF/PP(5/15/85)样品拉伸强度及断裂伸长率分别比GF/PP(15/85)样品提高了22.6%和321%.PP-g-MAH的加入使得原位混杂复合材料的拉伸强度进一步得到提高.
参考文献
[1] | G.Kiss, In-situ composites: blends of isotropic polymers and thermotropic liquid-crystalline polymers,Polym. Eng. Sci., 27, 410(1987) |
[2] | A.I.Isayev, M.Modic, Self-reinforced melt processible polymer composites: extrusion, compression, and injection molding, Polym. Compos., 8, 158(1987) |
[3] | D.G.Baird, M.A.Mcleod, Liquid crystalline polymer blends, in Polymer Blends Vol.2: Performance, Edited by D.R.Paul, C.B.Bucknall, (New York, John Wiley & Sons, Inc., 2000) p.429 |
[4] | He J, Zhang H, Wang Y, In-situ hybrid composites containing reinforcements at two orders of magnitude,Polymer, 38, 4279(1997) |
[5] | He J, Wang Y, Zhang H, In-situ hybrid composites of thermoplastic poly(ether ether ketone), poly(ether sulfone) and polycarbonate, Composites Science and Technology, 60, 1919(2000) |
[6] | He J(何嘉松),Zhang H(张洪志),Wang Y(王育立),In-situ hybrid reinforcedthermoplastic composites(原位混杂增强热塑性复合材料),Chinese Journal of Materials Research(材料研究学报),14(Suppl.),113(2000) |
[7] | He J(何嘉松),Zhang H(张洪志),A composite material containing carbonfiber andliquid crystalline polymer(一种含碳纤维和液晶聚合物的复合材料),China Patent(中国发明专利),ZL 96104860.3(2000) |
[8] | He J(何嘉松),Wang Y(王育立),A composite material of poly(ether ether ketone)modified withthermotropic liquid crystalline polymers(一种用热致液晶聚合物改性的聚醚醚酮复合材料),China Patent(中国发明专利),ZL97111710.1(2001) |
[9] | He J(何嘉松),Wang Y(王育立),A hybrid composite material containing glass fiber and thermotropic liquid crystalline polymerfibrils(一种含玻璃纤维和热致液晶聚合物微纤的混杂复合材料),China Patent(中国发明专利),ZL 97100522.2(2001) |
[10] | S.Y.Fu, B.Lauke, E.Mader, C.Y.Yue, X.Hu, Tensile properties of short-glass-fiber-and short-carbon- fiber-reinforced polypropylene composites, Composites Part A, 31, 1117(2000) |
[11] | S.Y.Fu, B.Lauke, E.Mader, C.Y.Yue, X.Hu, Y.W.Mai, Hybrid effects on tensile properties of hybrid short-glass-fiber- and short-carbon-fiber-reinforced polypropylene composites, Journal of materials science, 36,1243(2001) |
[12] | S.Y.Fu, Y.W.Mai, B.Lauke, C.Y.Yue, Synergistic effect on the fracture of hybrid short glass fiber and short carbon fiber reinforced polypropylene composites, Materials Science and Engineering A, 323, 326(2002) |
[13] | C.S.Own, D.Seader, N.A.D'souza, W.Brostow, Cowoven polypropylene/glass composites with polypropylene + polymer liquid crystal interlayers: dynamic mechanical and thermal analysis, polymer composites, 19,107(1998) |
[14] | Vencent, J.F.Agassant, A study of glass fiber orientation in flows of polymer composites, in Pro. IUPAC Inter.Symp. Interrelations Between Processing Structure and Properties of Polymeric Materials, p.241,Athens, Greece(1982) |
[15] | Oliver Roetting and Georg Hinrichsen, Blends of thermotropic liquid crystalline and thermoplastic polymers:a short review, Advances in Polymer Technology, 13, 57(1994) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%