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以十二烷基苯磺酸钠(SDBS)和Span-40表面活性剂为添加剂,AR沥青为原料,制备炭素泡沫材料,测定了材料的体积密度、显气孔率、压缩强度、常温热导率以及微晶结构参数,研究了添加表面活性剂后AR沥青的流变性能和炭素泡沫材料孔胞结构的变化.结果表明,表面活性剂使炭素泡沫的平均孔径变小,孔径分布趋于均匀,韧带的层片织构排列更为规整、致密.添加SDBS的炭素泡沫,孔壁较薄,开孔率较高,具有较低的体积密度(0.36 g/cm3)、较高的显气孔率(83.35%)、较小的层片间距d002(0.3366 nm)、较高的常温热导率(55.96 W/m·K)和比热导率(155.44(W/m·K)/(g/cm3)).添加span-40对炭素泡沫的体积密度、显气孔率和热导率的影响较小,但是使石墨化度提高,使其具有较高的压缩强度(2.39 MPa).

参考文献

[1] J.Klett,R.Hardy,E.Romine,C.Walls,T.Burchell,Highthermal-conductivity,mesophase pitch-derived carbon foams:effect of precursor on structure and properties,Carbon,38(7),953(2000)
[2] N.C.Gallego,J.W.Klett,Carbon foams for thermal management,Carbon,41(7),1461(2003)
[3] J.Klett,A.McMillan,N.Gallego,T.Burchell,C.Walls,Effects of heat treatment conditions on the thermal properties of mesophase pitch-derived graphitic foams,Carbon,42(8-9),1849(2004)
[4] J.W.Klett,A.D.McMillan,N.C.Gallego,C.A.Walls,The role of structure on the thermal properties of graphitic foams,Journal of Materials Science,39,3659(2004)
[5] CAO Min,ZHANG Shu,ZHOU Jianming,WANG Yonggang,Preparation and applications of carbon foam,Journal of Materials Science & Engineering,22(8),613(2004)(曹敏,张书,周建明,王永刚,炭素泡沫材料的制备和应用,材料科学与工程学报,22(8),613(2004))
[6] CAO Min,ZHANG Shu,WANG Yongang,Influence of preparation conditions on the pore structure of carbon foam,New Carbon Materials,20(2),134(2005)(曹敏,张书,王永刚,制备条件对炭泡沫结构的影响,新型炭材料,20(2),134(2005))
[7] CAO Min,ZHANG Shu,MIN Zhenhua,WANG Yonggang,XU Dongyao,The influence of gas release modes on pore structure and performance of carbon foam (Gyeongju,Proceeding of International Conference on Carbon,2005) p.295
[8] WANG Yonggang,CAO Min,ZHANG Shu,WANG Xiudan,XU Deping,Effect of precursors on pore structure of carbon foam,(Gyeongju,Proceeding of International Conference on Carbon,2005) p.177
[9] ZHAO Guoxi,ZHU Buyao,Principles of Surfactant Action (Beijing,China Light Industry Press,2003) p.513(赵国玺,朱步瑶,表面活性剂作用原理(北京,中国轻工业出版社,2003)p.513)
[10] QIU Jieshan,LI Ping,LIU Guishan,ZHOU Ying,Effect of iron nitrite on the preparation of carbon foams form mesophase pitch,New Carbon Materials,20(3),193(2005) (邱介山,李平,刘贵山,周颖,由中间相沥青制备泡沫炭:Fe(NO3)3的影响,新型炭材料,20(3),193(2005))
[11] YU Kun,Analysis Basis of Material Structure (Beijing,Science Press,2002) p.175(余焜,材料结构分析基础(北京,科学出版社,2002)p.175)
[12] MO Zhisheng,ZHANG Hongfang,Structure of Crystal Polymer and X-ray Diffraction (Beijing,Science Press,2003) p.136(莫志深,张宏放,晶态聚合物结构和X射线衍射(北京,科学出版社,2003)p.136)
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