以醋酸镉、硫粉为原料制备CdS量子点,研究了硫的加入量对其光学性质的影响,结果表明:合成的CdS量子点粒径均匀,分散性较好,随着硫加入量的增加CdS量子点的粒径增大;反应中过量的硫能有效地填补硫空位,从而抑制表面态发光,同时,ODA的修饰也能有效地钝化表面态,减小表面态的发光强度.
参考文献
[1] | ZHAO Jialong,J.A.Bardecker,A.M.Munro,M.S.Liu,NIU Yuhua,I.K.Ding,LUO Jingdong,CHEN Baoquan,A.K.Y.Jen,D.S.Ginger,Efficient CdSe/CdS quantum dot light-emitting diodes using a thermally Polymerized hole transport layer,Nano Lett.,6(3),463(2006) |
[2] | R.F.Heuffa,D.T.Cramba,M.Marrocco,Fluorescence correlation spectroscopy for diffusion of mobile quantum dots in dilute solutions,Chem.Phys.Lett.,454(4-6),257(2008) |
[3] | WU Guangming,ZHU Jiang,LI Yuefa,JIA Rui,Photoluminescence study of self-organized InAs quantum dots (wires) on InP (001) substrate,Chinese J.Mater.Res.,17(6),566(2003) (武光明,朱江,李月法,贾锐,InP(001)基衬底上自组织生长量子点线的光学性质研究,材料研究学报,17(6),566(2003)) |
[4] | WU Guangming,LI Yuefa,JIA Rui,Fabrication and characterization of InAs self-organized quantum dots (wires),Chinese J.Mater.Res.,16(5),490(2002) (武光明,李月法,贾锐,InAs自组织量子点线的制备和表征,材料研究学报,16(5),490(2002)) |
[5] | H.Kumano,H.Kobayashi,Y.Hayashi,M.Jo,I.Suemune,H.Sasakura,S.Adachi,S.Muto,Single photon emission with high degree of circular polarization from a single quantum dot under zero magnetic field,Physica E,40(6),1824(2008) |
[6] | B.Lounis,H.A.Bechtel,D.Cerion,P.Alivisatos,W.E.Moerner,Photon antibunching in single CdSe/ZnS quantum dot fluorescence,Chem.Phys.Lett.,329(5-6),399(2000) |
[7] | P.N.Vijayan,K.Dhanalakshmi,G.Sundararajan,P.K.Nair,Y.V.G.S.Murti,Synthesis and characterization of CdS nanocrystals in a perfluorinated ionomer(Nafion),Mater.Sci.Eng.B,83(1-3),61(2001) |
[8] | K.R.Choudhury,M.Samoc,A.Patra,P.N.Prasad,Charge.carrier transport in poly(N-vinylcarbazole):CdS quantum dot hybrid nanocomposite,J.Phys.Chem.B,108(5),1556(2004) |
[9] | B.A.Harruff,C.E.Bunker,Spectral properties of AOTprotected CdS nanoparticles:quantum yield enhancement by photolysis,Langmuir,19(3),893(2003) |
[10] | MAO Jie,YAO Junna,WANG Lina,LIU Weisheng,Easily prepared high-quantum-yield CdS quantum dots in water using hyperbranched polyethylenimine as modifier,J.Colloid Interf.Sci.,319(1),353(2008) |
[11] | K.V.Anikin,N.N.Melnik,A.V.Simakin,G.A.Shafeev,V.V.Voronov,A.G.Vitukhnovsky,Formation of ZnSe and CdS quantum dots via laser ablation in liquids,Chem.Phys.Lett.,366(3-4),357(2002) |
[12] | D.Behar,I.Rubinstein,G.Hodes,S.Cohen,H.Cohen,Electrodeposition of CdS quantum dots and their optoelectronic characterization by photoelectrochemical and scanning probe spectroscopies,Superlatt.Microstruct.,25(4),659(1999) |
[13] | H.Kumano,A.Ueta,I.Suemune,Modified spontaneous emission properties of CdS quantum dots embedded in novel three dimensional microcavities,Physica E,13(24),441(2002) |
[14] | GUO Wenzhuo,J.J.Li,Y.A.Wang,PENG Xiaogang,Luminescent CdSe/CdS Core/Shell nanocrystals in dendron boxes:superior chemical,photochemical and thermal Stability,J.Am.Chem.Soc.,125(13),3901(2003) |
[15] | C.Unni,D.Philip,K.G.Gopchandran,Studies on optical absorption and photoluminescence of thioglycerol stabilized CdS quantum dots,Spectrochim.Acta A,4,23(2008) |
[16] | A.B.Hernandez,G.L.Conzalez,L.M.Montes,U.Pal,Exciton energies of wurtzite CdS nanoparticles,Sol.Energy.Sol.Cells,79(4),539(2003) |
[17] | M.Pattabi,B.S.Amma,Synthesis and stability studies of thiophenol capped CdS nanoparticles,Sol.Energy.Sol.Cells,90(15),2377(2006) |
[18] | F.C.Weinstein,J.D.Dow,B.Y.Lao,Optical response of semiconductors in electric fields:excitonic effects,Phys.Rev.B,4(10),3502(1971) |
[19] | XU Guoqin,LIU Bing,XU Shijie,C.H.Chew,S.J.Chua,L.M.Gana,Luminescence studies of CdS spherical particles via hydrothermal synthesis,J.Phys.Chem.of Solid.,61(6),829(2000) |
[20] | J.R.Lakowicz,I.Gryczynski,G.Piszczek,C.J.Murphy,Emission spectral properties of cadmium sulfide nanoparticles with multiphoton excitation,J.Phys.Chem.B,106(21),5365(2002) |
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