通过测量样品的M-T曲线、ESR曲线、ρ-T曲线和MR-T曲线, 研究了Fe掺杂(x=0.05, 0.10, 0.20, 0.30, 0.40)对LaMnO3磁电性质的影响. 实验结果表明: 随掺杂浓度的增加, 体系的TC单调下降, 所有掺杂样品均有铁磁-顺磁(FM-PM)相变, 但均无金属-绝缘体(IM)转变. 这些结果归因于Fe掺杂引起Fe3+与Mn3+之间的双交换作用和J-T畸变.
By measuring M-T curves, ESR curves, ρ-T curves and MR-T curves of the samples,
the influences of Fe doping (x=0.05, 0.10, 0.20, 0.30, 0.40) upon magnetic
and electric properties of LaMnO3 were studied. The experimental results indicate that all samples undergo the transition from paramagnetism to ferromagnetism at TC. For the doped samples, there is a paramagnetic-ferromagnetic (PM-FM) transition but there is no insulator-metal(IM) transition. The results are attributed to double exchange interaction between Fe3+ ions and Mn3+ ions and Jahn-Teller effects.
参考文献
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