以C60及双齿膦dppp为配体,在氮气氛下合成出C60Pt(dppp)配合物，采用质谱、元素分析、红外光谱、紫外可见光谱以及光电子能谱等手段对产物进行表征.同时研究了产物的光电性能及氧化还原性能.光伏效应研究结果表明：产物具有优良的光电转化性能，尤其是在BQ/H2Q介质电对中，光生电压最大达到371mV；当C60Pt(dppp)薄膜厚度为1μm时，光伏效应值最大.
The fullerene complex C60Pt(dppp) was prepared by reacting C60 with dppp in nitrogen atmosphere. The synthesized fullerene complex was characterized by means of Mass Spectrometry (MS), Elemental Analysis, FT-IR, UV-Vis and XPS. Besides these, the photoelectric properties and redox property of this complex were also studied. The results show that the greatest value of photovotaic potential is 371mV in the benzoquinone/hydroquinone redox couple, and the value of photovoltaic effects reach the maximum when the thickness of complex film is 1μm. Based on the merits mensioned above, the complex has excellent photoelectric properties, therefore it has potential application in solar cells.
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