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采用海绵钛和单晶硅为原料,通过非自耗电弧熔融技术制备91.5Ti-8.5Si(wt%)和22Ti-78Si(wt%)共晶钎料.在真空中1400℃×10min条件下,研究了共钎料对SiC陶瓷的润湿性能和界面反应.结果表明:两种共晶钎料对SiC陶瓷均具有良好的润湿性能,润湿角分别约为10和25.在润湿实验后,91.5Ti-8.5Si(wt%)钎料和SiC陶瓷分离,22Ti-78Si (wt%)钎料和SiC陶瓷之间结合紧密.在润湿实验的温度制度下,用22Ti-78Si (wt%)钎料(厚度为0.2mm)对SiC陶瓷进行了初步连接,接头的抗弯强度为72MPa.采用SEM、EDS、XRD等检测手段对钎料的形貌和物相组成、钎料和SiC陶瓷的界面结合情况进行了表征,揭示了钎料对SiC陶瓷润湿性和界面反应的机理.

91.5Ti-8.5Si (wt%) and 22Ti-78Si(wt%) eutectic brazes with fine structure were prepared by means of the non-consumable arc-melting technology. Wetting behavior and interfacial reactions of two kinds of brazes on silicon carbide (SiC) were investigated by using the sessile drop method in vacuum at 1400℃ for 10min. The results indicate that two kinds of the brazes exhibit good wettability to SiC ceramic, and their contact angles are about 10°and 25°, respectively. After wetting, separation occurs between 91.5Ti-8.5Si (wt%) and SiC, but adhesion is good between 22Ti-78Si (wt%) and SiC. At wetting temperature system, bending strength of the joint of SiC/22Ti-78Si (wt%) /SiC with the braze thickness of 0.2mm, may reach 72MPa by tentative joining. Microstructure, phase composition and melting temperature of two kinds of the brazes and the interface of the brazes / SiC are examined by SEM, EDS, XRD and DSC, etc. Relationship between wettability of the brazes on SiC ceramic and interfacial reactions are investigated.

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