欢迎登录材料期刊网

材料期刊网

高级检索

研究了不同直径和含量多壁碳纳米管填充环氧有机硅树脂吸波涂层在2~18GHz频率范围内的介电和吸波性能.可以得到吸波涂层的介电常数随着碳纳米管含量的增加而增大.当碳纳米管含量相同时,吸波涂层介电常数随着碳纳米管直径的增加而增大.当碳纳米管含量大于5wt%时,吸波涂层的介电常数在低频急剧增加,且随频率增大而减少,出现频散效应.反射率测试结果表明:当涂层中多壁碳纳米管含量为10wt%、厚度为2mm时,吸波涂层的最大吸收峰随碳纳米管直径的增大向低频移动.多壁碳纳米管填充环氧有机硅树脂吸波涂层的吸波性能在7~14GHz范围内可达到-10dB,具有较好的吸波效果.

Multi-walled carbon nanotubes as dielectric absorber and epoxy-silicone resin as matrix were used to fabricate multi-walled carbon nanotubes/epoxy-silicone resin coatings. The effects of multi-walled carbon nano-tubes content and diameter on dielectric and microwave absorbing properties of the coatings were investigated in the frequency range from 2GHz to 18GHz. The results indicate that both of the real and imaginary part of the per-mittivity are enhanced with increasing multi-walled carbon nanotubes content and diameter. When the multi-walled carbon nanotubes content is 2wt% , the complex permittivity of the coatings keep almost constant in the frequency range from 2CHz to 18GHz, and are independent on the multi-walled carbon nanotubes diameter. As the multi-walled carbon nanotubes content increases to 5wt% , the complex permittivity of the coatings decreases with the increase of frequency, and also exhibits visible frequency-dependence dielectric response. The minimum reflection loss of the coatings shifts to the low frequency region (from 12.8GHz to 10. 8GHz) as the multi-walled carbon nanotubes diameter increasing. The results of the microwave absorbing properties show that the good nucrowave absorption ability (below - 10dB) can be obtained in a frequency range from 7GHz to 14GHz when the multi-walled carbon nanotubes content is 10wt% and the coating thickness is 2mm.

参考文献

[1] Yusoff A N.Abdullah M H,Ahmad S H,et al.Electromagnetic and absorption properties of some microwave absorbers.J.App.Phys.,2002,92 (2):876-882.
[2] Dresselhaus M S.Applied physics nanotube antennas.Nature,2004,432(7020):959-960.
[3] Martel R,Schmidt T,Shea H R,et al.Single-and multi-wall carbon nanotube field-effect tranaistors.Appl.Phys.Lett.,1998,73(17):2447-2449.
[4] Andrews R,Jacques D,Qian D,et al.Purification and structural annealing of multiwalled carbon nanotubes at graphitization temperatures.Carbon,2001,39 (11):1681-1687.
[5] Makeiff Darren A,Huber Trisha.Microwave absorption by polyanilinecarbon nanotube composites.Synthetic Met.,2006,156(7/8):497-505.
[6] 李建婷,曹全喜,姚娇艳,等.热酸氧化及镀镍对碳纳米管吸波性能的影响.功能材料与器件学报,2007,13(5):443-448.
[7] 林海燕,朱红,郭洪范,等.Fe填充碳纳米管微波吸收材料的研究.北京交通大学学报,2007,31(3):97-104.
[8] Watts P C P,Ponnampalam D R,Hsu W K.et al.The complex permittivity of multi-walled carbon nanotube-polystyrene composite films in X-band.Chem.Phys.Lett.,2003,378(5/6):609-614.
[9] Yang Y,Gupta M C,Dudley K L,et al.A comparative study of EMI shielding properties of carbon nanofiber and multi-walled carbon nanotube filled polymer composites.J.Nanosci.Nanotech.,2005,5(6):927-931.
[10] Mdarhri A,Carmona F,Brosseau C.et al.Direct current electrical and microwave properties of polymer-multiwalled carbon nanotubes composites.J.Appl.Phys.,2008,103(5):054303-1-9
[11] Li N.Huang Y.Du F,et al.Electromagnetic interference (EMI)shielding of single-walled carbon nanotube epoxy composites.Nano Lett.,2006.6(6):1141-1145.
[12] 赵东林,沈曾民(ZHAO Dung-Lin,et al).螺旋形手征碳纤维的微波介电特性.无机材料学报(Journal of Inorganic Materials),2003,18(5):1057-1062.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%