用提拉法成功生长出Nd:Sr3Gd2(BO3)4晶体,并对其光谱性能进行了研究.测量了晶体在200-1000nm波段的吸收谱.用808nm的波长激发,测量了晶体的荧光光谱和荧光寿命,计算得到晶体的发射截面.根据J-O理论计算了晶体的光谱参数,与其它Nd掺杂的品体的光谱参数做了比较和分析.
Spectral properties of Nd3+ ion in Sr3Gd2(BO3)4 crystal were investigated,where the crystal was grown successfully by the Czochralski method.The absorption spectrum in the range of 200-1000 nm was measured.The fluorescence spectrum and lifetime were determined excited with 808nm wavelength,and the emission cross-section was calculated.Based on the Judd-Ofelt theory the spectral parameters were obtained,which were compared with others Nd-doped crystals.
参考文献
[1] | Aka q Kahn-Harari A,Vivien D,et al.A new nonlinear and neodymium laser self-frequency doubling crystal with congruent melting:Ca4GdO(BO3)3(GdCOB).Eur.J.Solid State Inorg.Chem.,1996,33(8):727-736. |
[2] | Iwai M,Kobayashi T,Furuya H,et al.Crystal growth and optical characterization of rare-earth (Re) calcium oxyborate Ca4ReO(BO3)3 (Re= Y or Gd) as new nonlinear optical material.Jpn.J.Appl.Phys.,1997,36(2):1,276-1,279. |
[3] | Wang Guofu.Optical transition probability of the Nd3+ ion in GdA13(BO3)4 crystal.J.Opt.Soc.Am.B,2002,18:173-175. |
[4] | Pan H F,Liu M Q Xue J,et al.Spectra and sensitization of laser self-frequency doubling crystal NYAB.J.Phys.:Condens.Matter,1990,2(19):4525-530. |
[5] | Mill B V,Tkachuk A M,Ershova G I,et al.Growth and spectroscopic properties of Ln2Ca3(BO3)4:Nd(Ln=YLa,Gd) crystals.Op-tics and Spectroscopy,1996,81:201-204. |
[6] | Mill B V,Tkachuk A M,Belokoneva E L,et al.Growth,structure,and intensities of spectra of Ln2Ca3B4012:Nd3+ crystals (Ln=Y,La,Gd).Opt.Spectrosc.,1998,84:65-72. |
[7] | Mill B V,Tkachuk A M,Belokoneva E L,et al.Spectroscopic studies of Ln2Ca3B4O12-Nd3+ (Ln=Y,La,Gd) crystals.J.Alloys Compd,1998,277:291-294. |
[8] | Haumesser P H,Gaume R,Benitez J M,et al.Czochralski growth of six Yb-doped double borate and silicate laser materials.J.Crystal Growth,2001,233(1/2):233-42. |
[9] | Haumesser P H,Gaume R,Viana B,et al.Spectroscopic and crystal-field analysis of new Yb-doped laser materials.J.Phys.:Condes.Matter,2001,13(23):5427-5447. |
[10] | Tu C Y,Wang Y,You Z Y,et al.Growth and spectroscopic characteristics of Ca3Gd2(B03)4:Yb31 laser crystal.J.Crystal Growth,2004,265(1/2):154-158. |
[11] | Tu C Y,Wang Y,You Z Y,et al.The growth and spectroscopic characteristics of Ca3Y2(BO3)4:Er3+laser crystal.J.Crystal Growth,2004,260(3/4):410-13. |
[12] | Wang Y,Tu C Y,You Z Y,et al.Optical properties of Er3+:Ca3Gd2(B03)4 crystal.Opt.Mater.,2006,29:257-261. |
[13] | Wang Y,Tu C Y,You Z Y,et al.The growth and spectroscopic characteristics of Ca3Y2(BO3)4:Tm3+ crystal.J.Crystal Growth,2004,368(1/2):123-125. |
[14] | Wei B,Lin Z B,Zhang L Z,et al.Growth and spectroscopic characterization of Er3':Ca3La2(B03)4 crystal.Journal of Physics D:Applied Physics,2007,40(9):2792-2796. |
[15] | Judd B R.Optical absorption intensities of rare-earth ions.Physical Review,1962,127(3):750-761. |
[16] | Ofelt G S.Intensities of crystal spectra of rare-earth ions.J.Chem.Phys,1962,37(3):511-520. |
[17] | Fowler W B,Dexter D L.Relation between absorption and emission probabilities in luminescent centers in ionic solids.J.Phys.Rev,1962,128(5):2154-2165. |
[18] | Camall WT,Fields PR,Rajnak K.Electronic energy levels in the trivalent lanthanide aquo ions.l.Pr3+,Nd3+,Pm3',Sm'+,Dy3+,Ho3+ Era+,and Tm3+.J.Chem.Phys.,1968,49(10):4424-4434. |
[19] | Krupke W F.Radiative transition probabilities within the 4f ground configuration of Nd:YAG IEEE.J.Quantum Electron.,1971,QE-7:153-159. |
[20] | Chen W Z,Wang G F,Lin Z B,et al.Spectral parameters of Nd3+ ion in (3-Nd3':LaSc3(BO3)4 crystal.Optics Communications,1999,162(1/2/3):49-52. |
[21] | Pan S K,Hu Z S,Lin Z B,et al.Optical transition probability of Nd3+ ion in a-Ba3Y(B03)3 crystal.Mat.Res.Innovat.,2002,6(5/6):281-284. |
[22] | Han X M.Wang G F.Spectral parameters of Nd3+ ion in Nd:KLa(WO4)2crystal.Material Research Innovation,2002(6):235-238. |
[23] | Wang G F,Chen W Z,Lin Z B,et al.Optical transition probability of Nd3+ ion in a-Nd31:LaSc3(BO3)4 crystal.Physical Review B,1999,60(23):15469-15471. |
[24] | Lin Z B,Hu Z S,Wang G F.Spectral parameters of Nd3+ ion in Sr6NdSc(B03)6 crystal.Mat.Res.Innovat.,2003,7(4):253-256. |
[25] | ZHANG Hong,LUO Zundu,ZHENG An,et al.Spectral parameters of Nd3+ in crystal.Journal Infrared Millimeter and Waves,1988(4):297-300. |
[26] | Krupke W F,Shinn M D,Marion J E,et al.Spectroscopic,optical,and thermomechanical properties of peodymium-and chromiumdoped gadolinium scandium gallium garnet.J.Opt.Soc.Am.B,1986,3(1):102-114. |
[27] | Lu J,Prabha M,Song J,et al.High-power Nd3+:Y3Al5O12 ceramic laser.Appl.Phys.B:Lasers Opt.,2000,71(4):469-473. |
[28] | Sato Y,Taira T.Comparative study on the spectroscopic properties of Nd:GdVO4 and Nd:YV04 with hybrid process.IEEE J.Set Top.Quantum Electron.,2005,11:613-620. |
[29] | Jaque D,Capmany J,Luo Z D,et al.Optical bands and energy levels of Nd3+ ion in the YAl3(BO3)4 nonlinear laser crystal.J.Phys.:Condens.Matter,1997,9:9715-9729. |
[30] | Chen X Y,Luo Z D,Jaque D,et al.Comparison of optical spectroscopy of Nd3+ in NdAl3(BO3)4 (NAB),Nd:GdA13(13O3)4 (NGAB) and Nd:Gda.ZY0XAl3(BO3)4 (NGYAB) crystals.J.Phys.:Condens.Matter,2001,13(15):1171-1178. |
[31] | Jacinto C,Catunda T,Jaque D,et al.Fluorescence quantum efficiency and Auger upconversion losses of the stoichiometric laser crystal NdA13(BO3)4.Phys.Rev.B,2005,72(23):235111-1-8. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%