TiB2、ZrB2、HfB2、B4C及BN为代表的硼化物陶瓷具有优异的物理化学性能,在超高温、超硬以及超疏水等极限条件下有广阔的应用前景,但材料的烧结致密化困难、断裂韧性低等问题制约了它们更为广泛的应用.本文针对无压烧结在材料制备过程中的优势,探讨了影响硼化物陶瓷无压烧结的主要因素,总结了以“除氧”机制为代表的硼化物陶瓷无压烧结技术;针对硼化物陶瓷韧性低的不足,介绍了以“板晶增韧”、“纳米相增强”为代表的硼化物陶瓷微结构调控手段和强韧化措施.最后,文章还对硼化物陶瓷的织构化设计、制备方法与性能提升进行了简要介绍.
参考文献
[1] | Fahrenholtz W G,Hilmas G E,Talmy I G,et al.Refractory diborides of zirconium and hafnium.J.Am.Ceram.Soc.,2007,90(5):1347-1364. |
[2] | Thévenot F.Boron carbide--a comprehensive review.J.Eur.Ceram.Soc,1990,6(4):205-225. |
[3] | Eichler J,Lesniak C.Boron nitride (BN) and BN composites for high-temperature applications.J.Eur.Ceram.Soc.,2008,28(5):1105-1109. |
[4] | Becher P F.Microstructural design of toughened ceramics.J.Am.Ceram.Soc.,1991,74(2):255-269. |
[5] | Padture N P.In situ-toughened silicon-carbide.J.Am.Ceram.Soc.,1994,77(2):519-523. |
[6] | Yang F Y,Zhang X H,Han J C,et al.Preparation and properties of ZrB2-SiC ceramic composites reinforced by carbon nanotubes.J.Inorg.Mater,2008,23(5):950-954. |
[7] | Zhu T,Xu L,Zhang X H,et al.Densification,microstructure and mechanical properties of ZrB2-SiCw ceramic composites.J.Eur.Ceram.Soc.,2009,29(13):2893-2901. |
[8] | Zhang G J,Deng Z Y,Kondo N,et al.Reactive hot pressing of ZrB2-SiC composites. J. Am. Ceram. Soc., 2000, 83(9):2330-2332. |
[9] | Zhang X H,Li W J,Hong C Q,et al.Microstructure and mechanical properties of hot pressed ZrB2-SiCp-ZrO2 composites.Mater.Lett.,2008,62(15):2404-2406. |
[10] | Wu H T,Zhang W G.Fabrication and properties of ZrB2-SiC-BN machinable ceramics. J. Eur. Ceram. Soc., 2010, 30(4):1035-1042. |
[11] | Baik S,Becher P F.Effect of oxygen contamination on densification of TiB2.J.Am.Ceram.Soc.,1987,70(8):527-530. |
[12] | Zhang S C,Hilmas G E,Fahrenholtz W G.Pressureless densification of zirconium diboride with boron carbide additions.J.Am.Ceram.Soc.,2006,89(5):1544-1550. |
[13] | Fahrenholtz W G,Hilmas G E,Zhang S C,et al.Pressureless sintering of zirconium diboride:particle size and additive effects.J.Am.Ceram.Soc.,2008,91(5):1398-1404. |
[14] | Brynestad J,Bamberger C E,Land J F,et al.Removal of oxide contamination from TiB2 powders.J.Am.Ceram.Soc.,1983,66(11):C215-C216. |
[15] | Zhang H,Yan Y J,Huang Z R,et al.Pressureless sintering of ZrB2-SiC ceramics:the effect of B4C content.Scr.Mater.,2009,60(7):559-562. |
[16] | Yan Y J,Zhang H,Huang Z R,et al.In situ synthesis of ultrafine ZrB2-SiC composite powders and the pressureless sintering behaviors.J.Am.Ceram.Soc.,2008,91(4):1372-1376. |
[17] | Zou J,Zhang G J,Kan Y M,et al.Pressureless densification of ZrB2-SiC composites with vanadium carbide.Scr.Mater.,2008,59(3):309-312. |
[18] | Wang X G,Guo W M,Zhang G J.Pressureless sintering mechanism and microstructure of ZrB2-SiC ceramics doped with boron.Scr.Mater.,2009,61(2):177-180. |
[19] | Wang X G,Liu J X,Kan Y M,et al.Slip casting and pressureless sintering of ZrB2-SiC ceramics.J.Inorg.Mater.,2009,24(4):831-835. |
[20] | Chamberlain A L,Fahrenholtz W G,Hilmas G E.Pressureless sintering of zirconium diboride.J.Am.Ceram.Soc.,2006,89(2):450-456. |
[21] | Zou J,Zhang G J,Kan Y M,et al.Hot-pressed ZrB2-SiC ceramics with VC addition:chemical reactions,microstructures,and mechanical properties.J.Am.Ceram.Soc.,2009,92(12):2838-2846. |
[22] | Zou J,Zhang G J,Sun S K,et al.ZrO2 removing reactions of Groups Ⅳ-Ⅵ transition metal carbides in ZrB2 based composites.J.Eur.Ceram.Soc.,2011,31(3):421-427. |
[23] | Zou J,Zhang G J,Kan Y M,et al.Pressureless sintering mechanisms and mechanical properties of hafnium diboride ceramics with pre-sintering heat treatment.Scr.Mater., 2010,62(3):159-162. |
[24] | Zou J,Zhang G J,Kan Y M.Pressureless densification and mechanical properties of hafnium diboride doped with B4C:from solid state sintering to liquid phase sintering.J.Eur.Ceram.Soc.,2010,30(12):2699-2705. |
[25] | Lee H,Speyer R F.Pressureless sintering of boron carbide.J.Am.Ceram.Soc.,2003,86(9):1468-1473. |
[26] | Cho N T,Bao Z H,Speyer R F.Density-and hardness-optimized pressureless sintered and post-hot isostatic pressed B4C.J.Mater.Res.,2005,20(8):2110-2116. |
[27] | Zhang G J,Ando M,Ohji T,et al.High-performance boron nitridecontaining composites by reaction synthesis for the applications in the steel industry.Int.J.Appl.Ceram.Technol.,2005,2(2):162-171. |
[28] | Hagio T,Kobayashi K,Yoshida H,et al.Sintering of the mechanochemically activated powders of hexagonal boron-nitride.J.Am.Ceram.Soc.,1989,72(8):1482-1484. |
[29] | Sciti D,Guicciardi S,Bellosi A,et al.Properties of a pressureless-sintered ZrB2-MoSi2 ceramic composite.J.Am.Ceram.Soc.,2006,89(7):2320-2322. |
[30] | Otani S,Korsukova M M,Mitsuhashi T.Preparation of HfB2 and ZrB2 single crystals by the floating-zone method.J.Cryst.Growth,1998,186(4):582-586. |
[31] | Tao X Y, Dong L X, Wang X N, et al. B4C-nanowires/carbon-microfiber hybrid structures and composites from cotton t-shirts.Adv.Mater.,2010,22(18):2055-2059. |
[32] | Zhang G J,Yue X M,Jin Z Z.Preparation and microstructure of TiB2-TiC-SiC platelet-reinforced ceramics by reactive hot-pressing.J.Eur.Ceram.Soc.,1996,16(10):1145-1148. |
[33] | Zhang G J,Jin Z Z,Yue X M.A multilevel ceramic composite of TiB2-Ti0.9W0.1C-SiC prepared by in situ reactive hot pressing.Mater Lett.,1996,28(1/2/3):1-5. |
[34] | Zhang G J,Yue X M,Jin Z Z,et al.In-situ synthesized TiB2 toughened SiC.J.Eur.Ceram.Soc.,1996,16(4):409-412. |
[35] | Wu W W,Zhang G J,Kan Y M,et al.Reactive hot pressing of ZrB2-SiC-ZrC ultra high-temperature ceramics at 1800℃.J.Am.Ceram.Soc.,2006,89(9):2967-2969. |
[36] | Zou J,Zhang G J,Kan Y M.Formation of tough interlocking microstructure in ZrB2-SiC-based ultrahigh-temperature ceramics by pressureless sintering.J.Mater.Res.,2009,24(7):2428-2434. |
[37] | Zou J,Sun S K,Zhang G J,et al.Chemical reactions,anisotropic grain growth and sintering mechanisms of self-reinforced ZrB2-SiC doped with WC.J.Am.Ceram.Soc.,2011,94(5):1575-1583. |
[38] | Wu W W,Wang Z,Zhang G J,et al.ZrB2-MoSi2 composites toughened by elongated ZrB2 grains via reactive hot pressing.Scr.Mater.,2009,61(3):316-319. |
[39] | Niihara K.Sustainable Materials Development Based on Nanocomposite Structures for the 21th Centry,Proceedings of the 6th International Symposium on Eco-Materials Proceding & Design.2005,Korea,41. |
[40] | Kusunose T,Choa Y H,Sekino T,et al.Mechanical properties of Si3N4/BN composites by chemical processing.Key Eng.Mater,1999,161-163:475-480. |
[41] | Kusunose T,Sekino T,Choa Y H,et al.Fabrication and microstructure of silicon nitride/boron nitride nanocomposites.J.Am.Ceram.Soc.,2002,85(11):2678-2688. |
[42] | Kusunose T,Sekino T,Choa Y H,et al.Machinability of silicon nitride/boron nitride nanocomposites.J.Am.Ceram.Soc.,2002,85(11):2689-2695. |
[43] | Zhang G J,Yang J F,Ando M,et al.Mullite-boron nitride composite with high strength and low elasticity.J.Am.Ceram.Soc.,2004,87(2):296-298. |
[44] | Wang X D,Qiao G J,Jin Z H.Fabrication of machinable silicon carbide-boron nitride ceramic nanocomposites.J.Am.Ceram.Soc.,2004,87(4):565-570. |
[45] | Kusunose T,Sekino T,Ando Y.Synthesis of SiC/BN nanocomposite powders by carbothermal reduction and nitridation of borosilicate glass,and the properties of their sintered composites.Nanotechnology,2008,19(27):275603. |
[46] | Li J G,Gao L.Preparation of h-BN nano-film coated alpha-Si3N4 composite particles by a chemical route.J.Mater Chem.,2003,13(3):628-630. |
[47] | Gao L,Jin X H,Li J G,et al.BN/Si3N4 nanocomposite with high strength and good machinability.Mater.Sci.Eng.A,2006,415(1/2):145-148. |
[48] | Zhang G J,Yang J F,Ando M,et al.Reactive synthesis of aluminaboron nitride composites.Acta Mater,2004,52(7):1823-1835. |
[49] | Zhang G J,Ohji T.In situ reaction synthesis of silicon carbideboron nitride composites.J.Am.Ceram.Soc.,2001,84(7):1475-1479. |
[50] | Coblenz W S,Lewis D.In situ reaction of B2O3 with AlN and/or Si3N4 to form BN-toughened composites.J.Am.Ceram.Soc.,1988,71(12):1080-1085. |
[51] | Zhang G J,Ohji T.Effect of BN content on elastic modulus and bending strength of SiC-BN in situ composites.J.Mater Res.,2000,15(9):1876-1880. |
[52] | Zhang G J,Yang H F,Ando M,et al.Reaction synthesis of aluminum nitride-boron nitride composites based on the nitridation of aluminum boride.J.Am.Ceram.Soc.,2002,85(12):2938-2944. |
[53] | Zhang G J,Yang J F,Ohji T.In situ Si3N4-SiC-BN composites:preparation,microstructures and properties.Mater Sci.Eng.A,2002,328(1/2):201-205. |
[54] | Zhang G J,Beppu Y,Ando M,et al.In situ reaction synthesis of silicon carbide-boron nitride composite from silicon nitride-boron oxide-carbon.J.Am.Ceram.Soc.,2002,85(11):2858-2860. |
[55] | Zhang G J,Beppu Y,Ohji T,et al.Reaction mechanism and microstructure development of strain tolerant in situ SiC-BN composites.Acta Mater.,2001,49(1):77-82. |
[56] | Zhu X W,Sakka Y.Textured silicon nitride:processing and anisotropic properties. Sci. Technol. Adv. Mater., 2008, 9(3):033001-1-47. |
[57] | Ni D W,Zhang G J,Kan Y M,et al.Highly textured ZrB2-based ultrahigh temperature ceramics via strong magnetic field alignment.Scr.Mater,2009,60(8):615-618. |
[58] | Ni D W,Zhang G J,Kan Y M,et al.Textured HfB2-based ultrahigh-temperature ceramics with anisotropic oxidation behavior.Scr.Mater,2009,60(10):913-916. |
[59] | Grasso S,Hu C F,Vasylkiv O,et al.High-hardness B4C textured by a strong magnetic field technique.Scr.Mater,2011,64(3):256-259. |
[60] | Liu H T,Zou J,Ni D W,et al.Textured and platelet-reinforced ZrB2-based ultra-high-temperature ceramics.Scr.Mater.,2011,65(1):37-40. |
[61] | Ni D W,Zhang G J,Kan Y M,et al.Textured h-BN ceramics prepared by slip casting.J.Am.Ceram.Soc.,2011,94(5):1397-1404. |
[62] | Xue J X,Liu J X,Zhang G J,et al.Pressure-induced preferential grain growth,texture development and anisotropic properties of hot pressed hexagonal boron nitride ceramics.Scr.Mater.,2011,65(1):966-969. |
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