以聚乙二醇(PEG,Mn=6000)为模板剂,结晶四氯化锡(SnCl4·5H2O)和尿素为原料,采用微波溶剂热法在180℃、添加0.12 mmol PEG的条件下制备出了单分散性良好的SnO2微球.通过XRD、SEM、TEM和FT-IR等分析手段对产物进行表征,并结合光致发光(PL)谱研究了产物的发光性能.结果表明:SnO2微球是由大量细小晶粒堆积而成的,微球直径约1.3 μm.经400℃煅烧2h后,微球表面致密光滑且直径未发生明显变化.FT-IR谱图中550 cm-1处吸收峰应为表面结构改变引起的表面振动模式.PL谱表明煅烧前SnO2微球在320~450 nm处具有宽而强的发射带,煅烧后发射带强度大幅下降,说明产物的晶格缺陷对近带边发射有重要影响.
参考文献
[1] | Guo Y Q,Li Y,Tan R Q,et al.Synthesis of SnO2 hollow microspheres with core-shell structures through a facile template-free hydrothermal method.Mat.Sci.Eng.B,2010,171(1/2/3):20-24. |
[2] | NI Zi-Feng,YING Peng-Zhan,LUO Yong,et al.Synthesis and characterization of SnO2 nanobelts by carbothermal reduction of SnO2 powder.Journal of Inorganic Materials,2007,22(4):609-612. |
[3] | Kim W S,Kim D,Choi K J,et al.Epitaxial directional growth of tin oxide (101) nanowires on titania (101) substrate.Cryst Growth Des.,2010,10(11):4746-4751. |
[4] | Zhou X M,Fu W Y,Yang H,et al.Synthesis and ethanol-sensing properties of flowerlike SnO2 nanorods bundles by poly(ethylene glycol)-assisted hydrothermal process.Mater.Chem.Phys.,2010,124(1):614-618. |
[5] | Liu Y,Dong J,Liu M,et al.Well-aligned "nano-box-beams" of SnO2.Adv.Mater.,2004,16(4):353-356. |
[6] | Demir-Cakan R,Hu Y S,Antonietti M,et al.Facile one-pot synthesis of mesoporous SnO2 microspheres via nanoparticles assembly and lithium storage properties.Chem.Mater.,2008,20:1227-1229. |
[7] | Tatsuda N,Nakaamura T,Yamamoto D,et al.Synthesis of highly monodispersed mesoporous tin oxide spheres.Chem.Mater.,2009,21:5252-5257. |
[8] | Ho S Y,Wong A S W,Ho G W,et al.Controllable porosity of monodispersed tin oxide nanospheres via an additive-free chemical rout.Cryst.Growth.Des.,2009,9(2):732-736. |
[9] | 赵娜,李大光,赵丰华,等.SnO2纳米粒子的溶剂热制备及光致发光性质.精细化工,2008,25(12):1163-1167. |
[10] | Zhang L,Zhu Y J,Cao S W,et al.SnO2 and ZnO nanostructured spheres self-assembled by nanocrystals: microwave-assisted preparation and enhancement of photocatalytic activity.Chem.Lett.,2008,37(9):1002-1003. |
[11] | ZHANG Jian-Rong,GAO Lian.Synthesis and characterization of tin oxide nanocrystals for gas sensor applications.Journal of Inorganic Materials,2005,20(2):465-469. |
[12] | Shi L,Lin H L.Facile fabrication and optical property of hollow SnO2 spheres and their application in water treatment.Langmuir,2010,26(24):18718-18722. |
[13] | 赵杰,赵经贵,高山,等.二氧化锡气敏纳米粉体的红外光谱研究.光散射学报,2004,16(3):234-236. |
[14] | Li Z Q,Xiong Y J,Xie Y,et al.Selected-control synthesis of ZnO nanowires and nanorods via a PEG-assisted route.Inorg.Chem.,2003,42(24):8105-8109. |
[15] | Kuhnlenz F,Bark-Zollmann S,Stafast H,et al.VUV absorption tail changes of fused silica during ArF laser irradiation.J.Noncryst.Solids,2000,278(1/2/3):115-118. |
[16] | Hu J Q,Ma X L,Shang N G,et al.Large-scale rapid oxidation synthesis of SnO2 nanoribbons.J.Phys.Chem.B,2002,106(15):3823-3826. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%