欢迎登录材料期刊网

材料期刊网

高级检索

采用EDTA为模板,以CaCO3、NH4H2PO4、Eu2O3、Tb7O4、HNO3为原料,用NH3·H2O调节pH值,成功制备了掺铕羟基磷灰石(HA:Eu3+)及掺铽羟基磷灰石(HA∶Tb3+)纳米棒,并采用XRD、场发射环境扫描电子显微镜、荧光光谱、酶联监测仪等对其荧光及细胞毒性进行了研究.结果表明:制备的HA∶Eu3+纳米棒最强发射峰位于617nm处,发射出明亮的红光;制备的HA∶Tb3+纳米棒最强发射峰位于544 nm处,发射出明亮的绿光;细胞毒性研究表明HA∶RE (RE=Eu3+、Tb3+)纳米棒是一种良好的生物示踪材料.

参考文献

[1] Sun J J,Bae C J,Koh Y H,et al.Fabrication of hydroxyapatitepoly(epsilon-caprolactone) scaffolds by a combination of the extrusion and bi-axial lamination processes.J.Mater Sci.:Mater Med.,2007,18(6):1017-1023.
[2] Huang J,Jayasinghe S N,Best S M,et al.Electrospraying of a nano-hydroxyapatite suspension.J.Mater.Sci.,2004,39(3):1029-1032.
[3] Kumar R,Prakash K,Cheang P,et al.Temperature driven morphological changes of chemically precipitated hydroxyapatite nanoparticles.Langmuir,2004,20(13):5196-5200.
[4] LIAO Jian-Guo,ZHANG Li,ZUO Yi,et al.Surface modification of nano-hydroxyapatite with stearic acid.Chin.J.Inorg.Chem.,2009,25(7):1267-1273.
[5] LIANG Qiong,HAN Dong-Mei,GU Fu-Bo,et al.Synthesis of hydroxyapatite nanorods by hydrothermal recrystallization method.Chin.J.Inorg.Chem.,2007,23(1):86-90.
[6] SUN Yan-Rong,FAN Tao,HUANG Yong,et al.Research trend and prospect of hydroxyapatite bioceramics materials.J.Chin.Ceram.Soc.,2010,38(6):1145-1150.
[7] LI Ling,LIU Yu-Kan,TAO Jin-Hui,et al.Synthesis and characterization of terbium-doped nano-hydroxyapatite biological flurescent probe.Chin.J.Inorg.Chem.,2008,24(9):1369-1373.
[8] Nudelman F,Pieterse K,George A,et al.The role of collagen in bone apatite formation in the presence of hydroxyapatite nucleation inhibitors.Nat.Mater,2010,9(12):1004-1009.
[9] Peroosa S,Dub Z,Henriette N,et al.A computer modelling study of the uptake,structure and distribution of carbonate defects in hydroxyapatite.Biomaterials,2006,27(9):2150-2161.
[10] Mendonca G,Mendonca D B S,Aragao F J L,et al.Advancing dental implant surface technology-from micron-to nanotopography.Biomaterials,2008,29(28):3822-3835.
[11] Yanagida H,Okada M,Masuda M,et al.Cell adhesion and tissue response to hydroxyapatite nanocrystal-coated poly(L-lactic acid) fabric.J.Biosci.Bioeng.,2009,108(3):235-243.
[12] Ren F Z,Xin R L,Ge X,et al.Characterization and structural analysis of zinc-substituted hydroxyapatites.Acta Biomater.,2009,5(8):3141-3149.
[13] Zhang Y Z,Venugopal J R,E1-Turki A,et al.Electrospun biomimetic nanocomposite nanofibers of hydroxyapatite/chitosan for bone tissue engineering.Biomater.,2008,29(32):4314-4322.
[14] Zhang H P,Lu X,Leng Y,et al.Molecular dynamics simulations on the interaction between polymers and hydroxyapatite with and without coupling agents.Acta Biomater.,2009,5(4):1169-1181.
[15] Panda R N,Hsieh M F,Chung R J,et al.FTIR,XRD,SEM and solid state NMR investigations of carbonate-containing hydroxyapatite nano-particles synthesized by hydroxide-gel technique.J.Phys.Chem.Solids,2003,64(2):193-199.
[16] Mao X,Chu C L,Mao Z,et al.The development and identification of constructing tissue engineered bone by seeding osteoblasts from differentiated rat marrow stromal stem cells onto three-dimensional porous nano-hydroxylapatite bone matrix in vitro.Tissue and Cell,2005,37(5):349-357.
[17] Kino R,Ikoma T,Yunoki S,et al.Preparation and characterization of multilayered hydroxyapatite/silk fibroin film.J.Biosci.Bioeng.,2007,103(6):514-520.
[18] Pelled G,Tai K,Sheyn D,et al.Structural and nanoindentation studies of stem cell-based tissue-engineered bone.J.Biomech.,2007,40(2):399-411.
[19] Cao Chuan-Bao,Liu Si-Yuan,Lǔ Rui-Tao,et al.One step hydrothermal preparation of ZnSe nanorods and their characterization.Transactions of Beijing Institute of Technology,2004,24(10):932-934.
[20] Wang F K,Cao B R,Mao C B.Bacteriophage bundles with prealigned Ca2+ initiate the oriented nucleation and growth of hydroxyapatite.J.Chem.Mater.,2010,22(12):3630-3636.
[21] Kazuhiko K,Satoko T,Masato W,et al.Effects of modification of calcium hydroxyapatites by trivalent metal ions on the protein adsorption behavior.J.Phys.Chem.B,2010,114(7):2399-2404.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%