欢迎登录材料期刊网

材料期刊网

高级检索

采用固相法制备了致密PZT95/5铁电陶瓷,研究了低温下致密PZT95/5铁电陶瓷相结构和电性能的变化规律.变温X射线衍射(XRD)研究表明,低温(-60℃)下极化和未极化致密PZT95/5铁电陶瓷相结构保持不变.电性能研究表明随着温度从30℃下降至-60℃,致密PZT95/5铁电陶瓷的相对介电常数从278显著下降至173,而电阻率和剩余极化强度基本保持不变.结合冲击波载荷下动态放电模拟分析,发现相对介电常数的降低将引起动态电场增大至常温下的1.5倍,这可能是导致致密PZT95/5铁电陶瓷低温下击穿概率显著增大的关键因素.

参考文献

[1] Jaffe B,Cook W R,Jaffe H.Piezoelectric Ceramics.Academic Press,London,1971.
[2] Haertling G H.Ferroelectric ceramics:history and technology.J.Am.Ceram.Soc.,1999,82(4):797-818.
[3] Hall D A,Evans J D S,Covey-Crump S J,et al.Effects of superimposed electric field and porosity on the hydrostatic pressure-induced rhombohedral to orthorhombic martensitic phase transformation in PZT95/5 ceramics.Acta Mater.,2010,58(20):6584-6591.
[4] Lysne P C.Dielectric properties of shock-wave-compressed PZT95/5.J.Appl.Phys.,1977,48(3):1020-1023.
[5] Lysne P C,Percival C M.Electric energy generation by shock compression of ferroelectric ceramics:normal-mode response of PZT95/5.J.Appl.Phys.,1975,46(4):1519-1525.
[6] Neilson F W.Effects of strong shocks in ferroelectric materials.Bull.Am.Phys.Soc.,1957,2:302-305.
[7] Setchell R E.Shock wave compression of the ferroelectric ceramic Pb0.99(Zr0.95Ti0.05)0.98Nb0.02O3:depoling currents.J.Appl.Phys.,2005,97(1):013507-1-16.
[8] 杨洪.高抗电强度PZT95/5型铁电陶瓷的研制及电击穿机理研究.上海:上海硅酸盐研究所博士论文,2006.
[9] Lysne P C.Dielectric breakdown of shock-loaded PZT 65/35.J.Appl.Phys.,1973,44(2):577-582.
[10] Shkuratov S I,Talantsev E F,Baird J.Electric breakdown of longitudinally shocked Pb(Zr0.52Ti0.48)O3 ceramics.J.Appl.Phys.,2011,110(2):024113-1-5.
[11] YANG Hong,DONG Xian-Lin,ZHONG Ni,et al.Dielectric breakdown properties of Zr-rich lead zirconate titanate ceramics.Jpn.J.Appl.Phys.,2004,43:7579-7582.
[12] Dungan R H,Storz L J.Relation between chemical,mechanical and electrical properites of Nb2O5-Modified 95mo1% PbZrO3-5mol%PbTiO3.J.Am.Ceram.Soc.,1985,68 (10):530-533.
[13] 方进鑫,殷之文.电介质物理.北京:科学出版社,2000.
[14] 韩如绮,黄昆.固体物理学.北京:高等教育出版社,1985.
[15] Zhang Q M,Wang H,Kim N,et al.Direct evaluation of domain wall and intrinsic contributions to the dielectric and piezoelectric response and their temperature dependence on lead zirconatetitanate ceramics.J.Appl.Phys.,1994,75(1):454-459.
[16] NIE Heng-Chang,CHEN Xue-Feng,FENG Ning-Bo,et al.Effect of external fields on the switching current in PZT ferroelectric ceramics.Sol.Stat.Commu.,2010,150:101-103.
[17] ZENG Tao,WANG Gen-Shui,DONG Xian-Lin,et al.Investigation on FR(LT)-FR(HT) phase transition and pyroelectric properties of porous Zr-rich lead zirconate titante ceramics.Mater.Sci.& Eng.B,2007,140:5-9.
[18] Weibull W.A statistical distribution function of wide applicability.J.Appt.Mech.,1951,18:292-297.
[19] ZENG Tao,DONG Xian-Lin,YANG Hong,et al.Enhancement of mechanical and dielectric breakdown properties by diffusion of SiC into lead zirconate titanate ceramics.Scripta Mater.,2006,55(10):923-926.
[20] Cereceda N,Noheda B,Gonzalo J A.Investigation of the character of the phase transitions in Nb doped Zr-rich PZT by pyroelectric and dielectric measurements.J.Euro.Ceram.Soc.,1999,19:1201-1206.
[21] 王永龄.功能陶瓷性能与应用.北京:科学出版社,2003.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%