以硝酸锌、脲素及酒石酸为反应物,采用水热法制备碱式碳酸锌前驱体微球,通过煅烧前驱体制备了介孔氧化锌微球.通过扫描电子显微镜(SEM)可以观察到,氧化锌微球的直径约为2~4 μm,由大量厚度约为10 nm的介孔纳米片组装而成.X射线衍射(XRD)和透射电镜(TEM)结果表明:ZnO微球为六方纤锌矿结构,结晶较好.比表面积测试(BET)表明ZnO微球为介孔材料,孔径为20~50 nm,ZnO微球比表面积约为29.8 m2/g.以亚甲基蓝为目标降解物,对介孔氧化锌微球进行了光催化降解实验.实验结果表明,所合成的介孔ZnO微球对亚甲基蓝的光催化性能较好.
参考文献
[1] | Mclaren A,Valdes-solis T,Li G Q,et al.Shape and size effects of ZnO nanocrystals on photocatalytic activity.Journal of the American Chemical Society.,2009,131(35):12540-12541. |
[2] | Regan B O',Schwartz D T,Zakeeruddin S M,et al.Electrodeposited nanocomposite n-p heterojunctions for solid-state dye-sensitized photovoltaics.Advanced Materials,2000,12(17):1263-1267. |
[3] | ZHU Xin-Bo,FANG Xiao-Dong,DENG Zan-Hong,et al.Effects of hydrothermal growth conditions of ZnO nanorods arrays on flexible dye-sensitized solar cells.Journal of Inorganic Materials,2012,27(7):775-779. |
[4] | Wan Q,Li Q H,Chen Y J,et al.Fabrication and ethanol sensing characteristics of ZnO nanowire gas sensors.Applied Physics Letters,2004,84(18):3654-3656. |
[5] | Huang M H,Mao S,Feick H,et al.Room-temperature ultraviolet nanowires nanolasers.Science,2001,292(5523):1897-1899. |
[6] | Xi Y,Hu C G,Han X Y,et al.Hydrothermal synthesis of ZnO nanobelts and gas sensitivity property.Solid state communications,2007,141(9):506-509. |
[7] | HU Han-Mei,HUANG Xian-Huai,DENG Chong-Hai,et al.Hydrothermal synthesis of ZnO nanowires and nanobelts on a large scale.Materials Chemistry and Physics,2007,106(1):58-52. |
[8] | Jung S H,Oh E,Lee K H,et al.Sonochemical preparation of shape-selective ZnO nanostructures.Crystal Growth & Design,2008,8(1):265-269. |
[9] | XIN Chun-Yu,ZHANG Ji-De,LIU Cheng-You,et al.Preparation and performance characterization of Zinc Oxide thin films by means of Sol-Gel method.Journal of Jilin University (Science Edition),2012,50(1):122-125. |
[10] | Barreca D,Bekermann D,Comini E,et al.1D ZnO nano-assemblies by Plasma-CVD as chemical sensors for flammable and toxic gases.Sensors andActuators B:Chemical,2010,149(1):1-7. |
[11] | Hu Z S,Oskam G,Searson P C.Influence of solvent on the growth of ZnO nanoparticles.Journal of Colloid and Interface Science,2003,263(2):454-460. |
[12] | WEI Hui-Ying,WU You-Shi,LUN Ning,et al.Hydrothermal synthesis and characterization of ZnO nanorods.Materials Science and Engineering:A,2005,393(1/2):80-82. |
[13] | LI Zheng-Quan,XIONG Yu-Jie,XIE Yi.Selected-control of ZnO nanowires and nanorods via a PEG-asisted route.Inorganic Chemistry,2003,42(24):8105 8109. |
[14] | ZHENG Zhi-Yuan,CHEN Tie-Xin,CAO Liang,et al.Structure and optical properties of ZnO nanowire arrays grown by plasma-assisted molecular beam epitaxy.Journal of Inorganic Materials,2012,27(3):301-304. |
[15] | Zhang X Y,Dai J Y,Ong H C,et al.Hydrothermal synthesis of oriented ZnO nanobelts and their temperature dependent photoluminescence.Chemical Physics Letters,2004,393(1/2/3):17-21. |
[16] | WANG Hong-Qiang,LI Guang-Hai,JIA Li-Chao,et al.Controllable preferential-etching synthesis and photocatalytic activity of porous ZnO nanotubes.Journal of Physical Chemistry C,2008,112(31):11738-11743. |
[17] | HU Yong,MEI Ting,GUO Jun,et al.Temperature-triggered self-assembly of ZnO:from nanocrystals to nanorods to tablets.Inorganic Chemistry,2007,46(26):11031-11035. |
[18] | LI Jin,FAN Hui-Qing,JIA Xiao-Hua.Multilayered ZnO nanosheets with 3D porous architectures:synthesis and gas sensing application.Journal of Physical Chemistry C,2010,114(35):14684-14691. |
[19] | ZHANG Hai-Jiao,WU Ruo-Fei,CHEN Zhi-Wen,et al.Self-assembly fabrication of 3D flower-like ZnO hierarchical nanostructures and their gas sensing properties.Cryst.Eng.Comm.,2012(14):1775-1782. |
[20] | FENG Ying-Jie,ZHANG Mei,GUO Min,et al.Studies on the PEG-assisted hydrothermal synthesis and growth mechanism of ZnO microrod and mesoporous microsphere arrays on the substrate.Cryst.Growth Des.,2010,10:1500-1507. |
[21] | LEI Ai-Hua,QU Bai-Hua,ZHOU Wei-Chang,et al.Facile synthesis and enhanced photocatalytic activity of hierarchical porous ZnO microspheres.Materials Letters,2012,66(1):72-75. |
[22] | XU Ling-Ling,LI Ze-Ming,CAI Qing-Hai,et al.Precursor template synthesis of three-dimensional mesoporous ZnO hierarchical structures and their photocatalytic properties.CrystEngComm,2010,12:2166-2172. |
[23] | ZHANG Jun,WANG Shu-Rong,XU Mi-Juan,et al.Hierarchically porous ZnO architectures for gas sensor application.Cryst.Growth Des.,2009,9(8):3532-3537. |
[24] | SUN Hong-Yu,YU Yan-Long,LUO Jun,et al.Morphologycontrolled synthesis of ZnO 3D hierarchical structures and their photocatalytic performance.CrystEngComm,2012,14:8626-8632. |
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