染料敏化太阳能电池用过渡金属化合物对电极的研究进展

无机材料学报, 2013, 28(9): 907-915. doi: 10.3724/SP.J.1077.2013.12780

染料敏化太阳能电池用过渡金属化合物对电极的研究进展

1.山东理工大学化工学院,淄博,255049

2.山东理工大学化工学院,淄博,255049

3.山东理工大学化工学院,淄博,255049

4.山东理工大学化工学院,淄博,255049

基金项目: Natural Science Foundation of Shandong Province(ZR2010BM038) 山东省自然科学基金(ZR2010BM038) 国家自然科学基金(21273137) National Natural Science Foundation of China(21273137)

关键词：对电极 , 过渡金属化合物 , 染料敏化太阳能电池 , 综述

Research Progress on Transition Metal Compound Used as Highly Efficient Counter Electrode of Dye-sensitized Solar Cells

Keywords： counter electrode , transition metal compound , dye-sensitized solar cells , review

由于成本低、制作工艺简单、光电转换效率高,染料敏化太阳能电池被认为是传统太阳能电池最有力的竞争者之一.染料敏化太阳能电池常用的对电极是Pt电极,Pt价格高,储量少,因此寻找一种价格便宜且催化性能较好的材料代替Pt制备对电极是目前的研究热点.过渡金属化合物品种多、制备过程简单、价格低且催化性能好,近年来受到人们的广泛关注,是代替Pt制备染料敏化太阳能电池对电极最好的材料之一.本文综述了染料敏化太阳能电池过渡金属化合物对电极的研究现状,对过渡金属化合物对电极的性能特点及今后研究的重点进行了分析.

参考文献

[1]	O'Regan B,Gr?ttzel M.A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films.Nature,1991,353(6346):737-740.
[2]	Nazerruddin M K,Kay A,Rodicio I,et al.Conversion of TiO2 by Cis-x2Bis(2,2'-bipyridine-4,4'-dicarboxylate) ruthenium (Ⅱ)charge-transfer sensitized on nanocrystalline TiO2 electrodes.J.Am.Chem.Soc.,1993,115(14):6382-6390.
[3]	Hagfeldt A,Gr?eetzel M.Light-induced redox reactions innanocrystalline systems.Chem.Rev.,1995,95(1):49-68.
[4]	Gr?tzel M.Photoelectrochemical cells.Nature,2001,414(6861):338-344.
[5]	Gr?tzel M.Conversion of sunlight to electric power by nanocrys-talline dye-sensitized solar cells.J.Photochem.Photobiol.A:Chem.,2004,164(1/2/3):3-14.
[6]	Yanagida S,Yu Y,Manseki K.Iodine/iodide-free dye-sensitized solar cells.Acc.Chem.Res.,2009,42(11):1827-1838.
[7]	Hagfeldt A,Boschloo G,Sun L,et al.Dye-sensitized solar cells.Chem.Rev.,2010,110(11):6595-6663.
[8]	Vougioukalakis G,Philippopoulos A,Stergiopoulos T.Contributions to the development of ruthenium-based sensitizer for dye-sensitized solar cells.Coord.Chem.Rev.,2011,255(21):2602-2621.
[9]	Yella A,Lee H,Tsao H,et al.Porphyrin-sensitized solar cell with cobalt (Ⅱ/Ⅲ) based redox electrolyte exceed 12％ efficiency.Science,2011,334(6056):629-634.
[10]	Papageorgiou N,Maier W F,Gr?ttzel M.An iodine/triiodide reduction electrocatalyst for aqueous and organic media.,J.Electrochem.Soc,1997,114(3):876-884.
[11]	Papageorgiou N.Counter-electrode function in nanocrystalline photoelectrochemical cells configurations.Coord.Chem.Rev.,2004,248(13):1421-1446.
[12]	Wang G,Lin R,Lin Y,et al.A novel high-performance counter electrode for dye-sensitized solar cell.Electrochim.Acta,2005,50(28):5546-5552.
[13]	Calogero G,Calandra P,Irrera A,et al.A new transparent and low-cost counter electrode based on Pt nanoparticles for dye-sensitized solar cells.Energy Environ.Sci.,2011,4(5):1838-1844.
[14]	Sun K,Fan B,Ouyang J.Nanostructured films deposited by polyol reduction of a platinum precursor and their application as counter electrode of dye-sensitized solar cells.J.Phys.Chem.C,2010,114(9):4237-4244.
[15]	Kay A,Gr?ttzel M.Low cost photovoltaic modules base ondye-sensitized nanocrystalline titanium dioxide and carbon powder.Sol.Energy Mater.Sol.Cells,1996,44(1):99-117.
[16]	Murakami T N,Ito S,Wang Q,et al.Highly efficient dye-sensitized solar cells based on carbon black counter electrode.J.Electrochem.Soc.,2006,153(12):A2255-A2261.
[17]	Joshi P,Zhang L,Chen Q,et al.Electrospun carbon nanofibers as low-cost counter electrode for dye-sensitized solar cells.ACS Appl.Mater Interface,2010,2(12):3572-3577.
[18]	Wu M,Lin X,Wang T,et al.Low-cost dye-sensitized solar cells based on nine kinds of carbon counter electrode.Energy Environ.Sci.,2011,4(6):2308-2315.
[19]	Cha S,Koo B,Lee D.Pt-free transparent counter electrode for dye-sensitized solar cells prepared from carbon nanotube micro-balls.J.Mater.Chem.,2010,20(4):656-662.
[20]	Zhao B,Huang H,Jiang P,et al.Flexible counter electrode based on mesoporous carbon aerogel for high-efficiency dye-sensitized solar cells.J.Phys.Chem.C,2011,115(45):22615-22621.
[21]	Wang H,Hu Y.Graphene as a counter electrode material for dye-sensitized solar cells.Energy Environ.Sci.,2012,5(8):8182-8188.
[22]	Trancik J,Barton S,Hone J.Transparent and catalytic carbon nanotube films.Nano Lett.,2008,8(4):982-987.
[23]	Li K,Luo Y,Yu Z,et al.Low temperature fabrication of efficient porous carbon counter electrode for dye-sensitized solar cells.Electrochem.Commun.,2009,11(7):1346-1349.
[24]	Jiang Q,Li G,Gao X.Highly ordered mesoporous carbon array from natural wood materials as counter electrode of dye-sensitized solar cells.Electrochem.Commun.,2010,12(7):924-927.
[25]	Xiao J,Chen L,Yanagida S.Application of polypyrrole as a counter electrode for a dye-sensitized solar cell.J.Mater.Chem.,2011,21(12):4644-4649.
[26]	Bu C,Tai Q,Guo S.A transparent and stable polypyrrole counter electrode for dye-sensitized solar cell.J.Power Source,2013,221(1):78-83.
[27]	Sakurai S,Jiang H,Takahashi M.Enhanced performance of a dye-sensitized solar cell with a modified poly(3,4-ehtylenedioxy-thiophene)/TiO2/FTO counter electrode.Electrochim Acta,2009,54(23):5463-5469.
[28]	Wu L,Li Q,Fan L,et al.High-performance polypyrrole nanopar-ticles counter electrode for a dye-sensitized solar cells.J.Power Source,2008,181(1):172-176.
[29]	Sun H,Luo Y,Zhang Y,et al.In situ preparation of a flexible polyaniline/carbon composite counter electrode and its application in dye-sensitized solar cells.J.Phys.Chem.C,2010,114(26):11673-11679.
[30]	Tai Q,Chen B,Guo F,et al.In situ prepared transparent ployaniline electrode and its application in bifacial dye-sensitized solar cell.ACSNano,2011,5(5):3795-3799.
[31]	Hong W,Xu Y,Shi G,et al.Transparent graphene/PEDOT-PSS composite films as counter electrodes for dye-sensitized solar cells.Electrochem.Commun.,2008,10(10):1555-1558.
[32]	Zhang J,Hreid T,Li X,et al.Nanostructured polyaniline counter electrode for dye-sensitized solar cells:fabrication and investigation of its electrochemical formation mechanism.Electrochim.Acta,2010,55(11):3664-3668.
[33]	Chen J,Li B,Zheng J,et al.Polyaniline/carbon film as flexible counter electrode in Pt-free dye-sensitized solar cells.Electrochim.Acta,2011,56(12):4624-4630.
[34]	Wu M,Ma T.Pt-free catalysts as counter electrodes in dye-sensitized solar cells.ChemSusChem,2012,5(8):1343-1357.
[35]	Wang M,Anghel A,Marsan B,et al.CoS supersedes Pt as an efficient electrocatalyst for triiodide reduction in dye-sensitized solar cells.J.Am.Chem.Soc.,2009,131(44):15976-15977.
[36]	Lin J,Liao J,Chou S.Cathodic electrodeposition of highly porous cobalt sulfide counter electrodes for dye-sensitized solar ceils.Electrochim.Acta,2011,56(24):8818-8826.
[37]	Lin J,Liao J.Mesoporous electrodeposited CoS film as a counter electrode in dye-sensitized solar cells.J.Electrochem.Soc.,2012,159(2):D65-D71.
[38]	Lin J,Liao J,Wei T.Honeycomb-like CoS counter electrodes for transparent dye-sensitized solar cells.Electrochem.Solid-State Lett.,2011,14(4):D41-D44.
[39]	Kung C,Chen H,Lin C,et al.CoS Acicular nanorod arrays for the counter electrode of an efficient dye-sensitized solar cells.ACS Nano,2012,6(8):7016-7025.
[40]	Chi W,Hart J,Yang S,et al.Empolying electrostatic self-assembly of tailored nickel sulfide nanoparticles for quasi-solid-state dye-sensitized solar cells with Pt-free counter electrode.Chem.Commun.,2012,48(76):9501-9503.
[41]	Sun H,Qin D,Huang S,et al.Dye-sensitized solar cells with NiS counter electrode electrodeposited by a potential reverse technique.Energy Environ.Sci.,2011,4(8):2630-2637.
[42]	Ku Z,Li X,Liu G,et al.Transparent NiS counter electrodes for thiolate/disulfide mediated dye-sensitized solar cells.J.Mater.Chem.4,2013,1(2):237-240.
[43]	Zhao W,Lin T,Sun S,et al.Oriented single-crystalline NiS nanorod arrays "two-in-one" counter electrode for dye-sensitized solar cells.J.Mater.Chem.A,2013,1(2):194-198.
[44]	Wu M,Wang Y,Lin X,et al.Economical and effective sulfide catalysts for dye-sensitized solar cells as counter electrodes.Phys.Chem.Chem.Phys.,2011,13(43):19298-19301.
[45]	Jiang Q,Li J,Gao X.Highly ordered TiN nanotube arrays as counter electrode of dye-sensitized solar cells.Chem.Commun.,2009,45(44):6720-6722.
[46]	Zhang X,Chen X,Dong S,et al.Hierarchical micro/nano structured titanium nitride spheres as high performance counter electrode for a dye-sensitized solar cell.J.Mater.Chem.,2012,22(1):6067-6071.
[47]	Jiang Q,Li G,Liu S,et al.Surface-nitrided nickel with bifunctional structure as low-cost counter electrode for dye-sensitized solar cells.J.Phys.Chem.C,2010,114(31):13397-13401.
[48]	Li G,Song J,Pan G,et al.Highly Pt-like electrocatalytic activity of transition metal nitride foe dye-sensitized solar cells.Energy Environ.Sci.,2011,4(5):1680-1683.
[49]	Wu M,Zhang Q,Xiao J,et al.Two flexible counter electrode based on molybdenum and tungsten nitrides for dye-sensitized solar cells.J.Mater Chem.,2011,21(29):10761-10766.
[50]	Wu M,Lin X,Guo W,et al.Great improvement of catalytic activity of the oxide counter electrode fabricating in N2 atmosphere for dye-sensitized solar cells.Chem.Commun.,2013,49(11):1058-1060.
[51]	Yun S,Wang L,Guo W,et al.Non-Pt counter electrode catalysts using tantalum oxide for low-cost dye-sensitized solar cells.Electrochem.Commun.,2012,24(1):69-73.
[52]	Wu M,Lin X,Hagfeldt A,et al.A novel catalyst of WO2 nanorod for the counter electrode of dye-sensitized solar cells.Chem.Commun.,2011,47(15):4535-4537.
[53]	Lin X,Wu M,Wang Y,et al.Novel counter electrode catalyst of niobium oxide supersede Pt for dye-sensitized solar cells.Chem.Commun.,2011,47(41):11489-11491.
[54]	Wu M,Lin X,Hagfeldt A,et al.Low cost molybdenum carbide and tungsten carbide counter electrode for dye-sensitized solar cells.Angew.Chem.lnt.Ed.,2011,50(15):3520-3524.
[55]	Jang J,Ham D,Ramasamy E,et al.Platinum-free tungsten carbide as effective counter electrode for dye-sensitized solar cells.Chem.Commun.,2010,46(45):8600-8602.
[56]	Ko A,Oh J,Lee Y,et al.Characterizations of tungsten carbide as non-Pt counter electrode in dye-sensitized solar cells.Mater Lett.,2011,65(14):2220-2223.
[57]	Krawiec P,De Colar P L,Glaser R,et al.Oxide foams for the synthesis of high-surface-area vanadium nitride catalysts.Adv.Mater,2006,18(4):505-508.
[58]	Bennett L H,Cuthill J R,McAlister A J,et al.Electronic and catalytic properties of tungsten carbide.Science,1975,187(4179):858-859.
[59]	Sun Y,Wu Q,Shi G.Graphene based now energy materials.Energy Environ.Sci.,2011,4(4):1113-1132.
[60]	Pang S,Hernandez Y,Feng X,et al.Graphene as transparent electrode materials of organic electronics.Adv.Mater,2011,23(25):2779-2795.
[61]	Jiang L,Lu X.Graphene application in solar cells.J.Inorganic Mater,2012:27(11):1129-1137.
[62]	Kavan L,Yum J,Gr?ttzel M,et al.Optically transparent cathode for dye-sensitized solar cells based on graphene nanoplatelets.ACS Nano,2011,5(1):165-172.
[63]	Kavan L,Yum J,Gr?ttzel M,et al.Graphene nanoplatelets cathode for Co(Ⅲ)/Ⅱ mediated dye-sensitized solar cells.ACS Nano,2011,5(11):9171-9178.
[64]	Jang S,Kim Y,Kim D,et al.Electrodynamically sprayed thin film of aqueous dispersible graphene nanosheets:highly efficient cathode for dye-sensitized solar cells.ACSAppl.Mater Interface.2012,4(7):3500-3507.
[65]	Choi H,Kim H,Hwang S,et al.Graphene counter electrode for dye-sensitized solar cells by electrophoretic deposition.J.Mater Chem.,2011,21(21):7548-7551.
[66]	Roy-Mayhew J D,Bozym D J,Punckt C,et al.Functionalized graphene as catalytic counter electrode in dye-sensitized solar cells.ACSNano,2010,4(10):6203-6211.
[67]	Zhang H,Neo C,Mei X,et al.Reduced oxide graphene film fabricated by gel coating and its application as Pt-free counter electrode of highly efficient iodide/triodide dye-sensitized solar cells.J.Mater.Chem.,2012,22(29):14465-14474.
[68]	Xu Y,Bai H,Li G,et al.Flexible graphene film via the filtration of water-soluble noncovalent functionalized graphene sheets.J.Am.Chem.Soc.,2008,130(18):5856-5857.
[69]	Zhang D,Li X,Li H,et al.Graphene based counter clectrode for dye-sensitized solar ceils.Carbon,2011,49(15):5382-5388.
[70]	Duo Y,Li G,Song J,et al.Nickel phosphide-embedded graphene as counter electrode of dye-sensitized solar cells.Phys.Chem.Chem.Phys.,2012,14(4):1339-1342.
[71]	Das S,Sudhagar P,Nagarajan S,et al.Synthesis of graphene-CoS electrocatalytic electrodes for dye-sensitized solar ceils.Carbon,2012,50(13):4815-4821.
[72]	Yue G,Lin J,Tai S,et al.A catalytic composite film MoS2/graphene flakes as a counter electrode for Pt-free dye-sensitized solar cells.Electrochim.Acta,2012,85(1):162-168.
[73]	Liu C,Tai S,Chou S,et al.Facile synthesis of MoS2/graphene nanocomposite with high catalytic activity toward triiodide reduction in dye-sensitized solar cells.J.Mater Chem.,2012,22(39):21057-21064.
[74]	Umeyama T,Imahori H.Carbon nanotube-modified electrodes for solar energy conversion.Energy Environ.Sci.,2008,1(1):120-133.
[75]	Ahmad K,Pan W.Dramatic effect of multiwalled carbon nanotube on the electrical properties of alumina ceramic nanocomposites.Compos.Sci.Technol,2009,69(7/8):1016-1021.
[76]	Lee W,Ramasamy E,Lee D,et al.Efficient dye-sensitized solar cell with catalytic multiwalled carbon nanotube counter electrode.A CS Appl.Mater Interface,2009,1(6):1145-1149.
[77]	Seo S,Kim S,Koo B,et al.Influence of electrolyte composition on the photovoltaic performance and stability of dye-sensitized solar cell with multiwalled carbon nanotube catalyst.Langmuir,2010,26(12):10341-10346.
[78]	Cho H,Kim H,Hwang S,et al.Dye-sensitized solar cells using graphene-based carbon nanocomposite as counter electrode.Sol.Energy Mater Sol.Cell,2011,95(1):323-325.
[79]	Trancik J,Barton S,Hone J.Transparent and catalytic carbon nanotube films.Nano Lett.,2008,8(4):982-987.
[80]	Ramasamy E,Lee W,Lee D,et al.Spray coated multi-walled carbon nanotube counter electrode for triiodide reduction in dye-sensitized solar cells.Electroehem Commun.,2008,10(7):1087-1089.
[81]	Suzuki K,Yamaguchi M,Kumagai M,et al.Application carbon nanotubes to counter electrode of dye-sensitized solar cells.Chem.Lett.,2003,32(1):28-29.
[82]	Tai S,Liu C,Chou S,et al.Few-layer MoS2 nanosheets coated on multiwalled carbon nanotubes as low-cost highly electrocatalytic counter electrode for dye-sensitized solar cells.J.Mater Chem.,2012,22(47):24753-24759.
[83]	Song J,Li G,Xiong F,et al.Synergistic effect of molybdenum nitride and carbon nanotube on electrocatalysis for dye-sensitized solar cells.J.Mater Chem.,2012,22(38):20580-20585.
[84]	Li J,Wang F,Jiang Q,et al.Carbon nanotube with titanium nitride as a low-cost counter electrode materials for dye-sensitized solar cells.Angew.Chem.lnt.Ed.,2010,49(21):3653-3656.
[85]	Yue G,Wu J,Lin J,et al.A counter electrode of multiwalled carbon nanotube decorated with tungsten sulfide used in dye-sensitized solar cells.Carbon,2013,55(1):1-9.
[86]	Lin J,Liao J,Hung T.A composite counter electrode of CoS/MWCNT with highly electrocatalytic activity for dye-sensitized solar cells.Electrochem.Commun.,2011,13(9):977-980.
[87]	Xiao Y,Wu J,Lin J,et al.Pulse electrodeposition of CoS on the MWCNT/Ti as a high performance counter electrode for the Pt-free dye-sensitized solar cells.J.Mater.Chem.A,2013,1(4):1289-1295.
[88]	Ryoo R,Joo S,Kruk M,et al.Ordered mesoporous carbon.Adv.Mater,2001,13(9):677-681.
[89]	Lee J,Kim J,Hyeon T.Recent progress in the synthesis of porous carbon materials.Adv.Mater,2006,18(16):2073-2094.
[90]	Candelaria S,Shao Y,Zhou W,et al.Nanostrucutred carbon for energy storage and conversion.Nano Energy,2012,1(2):195-220.
[91]	Ramasamy E,Chun J,Lee J.Soft-template synthesized ordered mesoporous carbon counter electrode for dye-sensitized solar cells.Carbon,2010,48(15):4563-4565.
[92]	Fang B,Fan S,Kim J,et al.Incorporation hierarchical nanostructured carbon counter electrode into metal-free organic dye-sensitized solar cell.Langmuir,2010,26(13):11238-11243.
[93]	Wang G,Xing W,Zhuo S.Application of mesoporous carbon to counter electrode for dye-sensitized solar cells.J.Power Source,2009,194(1):568-573.
[94]	Ramasamy E,Lee J.Large-pore sized mesoporous carbon electro-catalyst for efficient dye-sensitized solar ceils.Chem.Commun.,2010,46(12):2136-2138.
[95]	Srinivasu P,Islam A,Singh S O,et al.Highly efficient nanoporous graphitic carbon with tunable texture properties for dye-sensitized solar cells.J.Mater.Chem.,2012,22(39):20866-20869.
[96]	Wu M,Bai J,Wang Y,et al.Highly efficient phosphide/carbon counter electrode for both iodide and organic redox couples in dye-sensitized solar cells.J.Mater.Chem,2012,22(22):11121-11127.
[97]	Wu M,Lin X,Hagfeldt A,et al.Low-cost Molybdenum carbide and tungsten carbide counter electrode for dye-sensitized solar cells.Angew.Chem.Int.Ed.,2011,50(13):3520-3524.
[98]	Wu M,Lin X,Wang L,et al.In-situ synthesized economical tungsten oxide imbedded in mesoporous carbon for dye-sensitized solar cells as counter electrode catalyst.J.Phys.Chem.C,2011,115(45):22598-22602.
[99]	Wu M,Lin X,Wang Y,et al.Economical Pt-free catalysts for counter electrode of dye-sensitized solar cells.J.Am.Chem.Soc.,2012,134(7):3419-3428.

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