采用化学共沉淀法制备了La2/3A1/3MnO3:Agx (A=Ca、Sr、Ba,LAMO:Agx,x=0、0.1、0.2、0.3、0.4 mol％)多晶复合材料.XRD结果表明实验制备了纯相LAMO:Agx样品,Ag+离子A位替代致使LCaMO:Agx和LSrMO:Agx晶格常数和晶胞体积发生微小膨胀,LBaMO:Agx晶格常数和晶胞体积发生微小收缩;R-T测试结果表明LCaMO:Agx的电阻温度系数(Temperature Coefficient of Resistance,TCR)数值在x=0.4、Tk=271.3 K(Tk为TCR位于最大值时对应的温度数值)时具有最大值为28％/K.SEM分析结果表明,随着Ag掺杂量增加,LCaMO晶粒尺寸增大,晶粒均匀性和规则性得以改善,晶化质量得到提高.通过Ag微观掺杂机制对LAMO复合材料的TCR数值增强进行了分析讨论.
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