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采用等离子体增强化学气相沉积法(PECVD)制备了多孔SiO2薄膜,系统地研究了不同浓度磷酸处理对多孔SiO2薄膜的质子导电特性、双电层电容和以此多孔SiO2薄膜为栅介质的铟锌氧(IZO)双电层薄膜晶体管性能的影响.结果表明:多孔SiO2薄膜的质子电导率和双电层电容随磷酸浓度升高而增大,60%浓度磷酸处理后多孔SiO2薄膜质子电导率和双电层电容分别达到1.51×10-4 S/cm和6.33 μF/cm2.随磷酸浓度升高,双电层薄膜晶体管的工作电压降低,并且,电流开关比也变大.其中60%浓度磷酸处理后器件工作电压为1.2 V,迁移率为20cm2/(V·s),电流开关比为4×106.这种双电层薄膜晶体管有望应用在化学和生物传感等领域.

参考文献

[1] SHIMOTANI H,ASANUMA H,IWASA Y.Electric double layer transistor of organic semiconductor crystals in a four-probe configuration.Jpn.J.Appl.Phys.,2007,46(6A):3613-3617.
[2] CHO J H,LEE J,XIA Y,et al.Printable ion-gel gate dielectrics for low-voltage polymer thin-film transistors on plastic.Nat.Mater.,2008,7(11):900.
[3] HERLOGSSON L,CRISPIN X,ROBINSON N D,et al.Low-voltage polymer field-effect transistors gated via a proton conductor.Adv.Mater,2007,19(1):97-101.
[4] PANZER M J,NEWMAN C R,FRISBIE C D.Low-voltage operation of a pentacene field-effect transistor with a polymer electrolyte gate dielectric.Appl.Phys.Lett.,2005,86(10):103503-1-3.
[5] PANZER M J,FRISBIE C D.Polymer electrolyte gate dielectric reveals finite windows of high conductivity in organic thin film transistors at high charge carrier densities.J.Am.Chem.Soc.,2005,127(19):6960-6961.
[6] SAID E,CRISPIN X,HERLOGSSON L.Polymer field-effect transistor gated via a poly(styrenesulfonic acid) thin film.Appl.Phys.Lett.,2006,89(143507):143507-1-3.
[7] CHO J H,LEE J,HE Y,et al.High-capacitance ion gel gate dielectrics with faster polarization response times for organic thin film transistors.Adv.Mater.,2008,20(4):686-690.
[8] CHEN Y B,THORN M,CHRISTENSEN S,et al.Enhancement of anhydrous proton transport by supramolecular nanochannels in comb polymers.Nat.Chem.,2010,2(6):503-508.
[9] LORENZ M,VON WENCKSTERN H,GRUNDMANN M.Tungsten oxide as a gate dielectric for highly transparent and temperature-stable zinc-oxide-based thin-film transistors.Adv.Mater.,2011,23(45):5383-5386.
[10] ZHANG H L,GUO L Q,WAN Q.Nanogranular Al2O3 proton conducting films for low-voltage oxide-based homojunction thin-film transistors.J.Mater Chem.C,2013,1(15):2781 2786.
[11] LU A X,SUN J,JIANG J,et al.Microporous SiO2 with huge electricdouble-layer capacitance for low-voltage indium tin oxide thin-film transistors.Appl.Phys.Lett.,2009,95(22):222905-1-3.
[12] ZENG J,HE B B,LAMB K,et al.Phosphoric acid functionalized pre-sintered meso-silica for high temperature proton exchange membrane fuel cells.Chem.Commun.,2013,49(41):4655-4657.
[13] KIM D R,LEE C H,ZHENG X L.Probing flow velocity with silicon nanowire sensors.Nano Lett.,2009,9(5):1984-1988.
[14] JIANG J,SUN J,LU A X,et al.Self-assembled ultralow-voltage flexible transparent thin-film transistors gated by SiO2-based solid electrolyte.IEEE Electron Dev.Lett.,2011,58(2):547-552.
[15] GRUZD A S,TROFIMCHUK E S,NIKONOROVA N I,et al.Novel polyolefin/silicon dioxide/H3PO4 composite membranes with spatially heterogeneous structure for phosphoric acid fuel cell.Int.J.Hydrogen Energy,2013,38(10):4132-4143.
[16] JIN Y,QIAO S Z,DA COSTA J C D,et al.Hydrolytically stable phosphorylated hybrid silicas for proton conduction.Adv.Funct.Mater.,2007,17(16):3304-3311.
[17] AGMON N.The Grothuss mechanism.Chem.Phys.Lett.,1995,244(5/6):456-462.
[18] VILCIAUSKAS L,TUCKERMAN M E,BESTER G,et al.The mechanism of proton conduction in phosphoric acid.Nat.Chem.,2012,4(6):461-466.
[19] LARSSON O,SAID E,BERGGREN M,et al.Insulator polarization mechanisms in polyelectrolyte-gated organic field-effect transistors.Adv.Funct.Mater,2009,19(20):3334 3341.
[20] YUAN H T,SHIMOTANI H,TSUKAZAKI A,et al.Hydrogenationinduced surface polarity recognition and proton memory behavior at protic-ionic-liquid/oxide electric-double-layer interfaces,J.Am.Chem.Soc.,2010,132(19):6672-6678.
[21] GUO L Q,YANG Y Y,ZHU L Q,et al.Effects of humidity on performance of electric-double-layer oxide-based thin-film transistors gated by nanogranular SiO2 solid electrolyte.AIP Advances,2013,3(7):072110-1-9.
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