本工作研究了水热法制备钨系氧化物过程中反应温度对产物物相、微结构和光学性能的影响.XRD结果表明100℃条件下制备的样品为纳米六方相铵钨青铜(NH4)xWO3-y.随着水热温度升高(140和180℃),部分六方相(NH4)xWO3-y逐步转变为正交相三氧化钨WO3·1/3H2O,形成两相共存产物.SEM和TEM分析证实(NH4)xWO3-y和WO3·1/3H2O粒子均为沿[001]方向(c轴)生长的短棒状单晶,随水热反应进行它们会通过取向融并(oriented attachment)方式进一步长大.结构分析同时证实,棒状晶的物相与其尺寸存在明显联系,纳米尺寸的棒状晶为六方(NH4)xWO3-y相,而微米尺寸的棒状晶为正交WO3·1/3H2O相.依据实验结果,提出了一种表面能控制的六方相(NH4)xWO3-y向正交相WO3·1/3H2O相转变机理.光学性能测量表明,100℃制备的六方相(NH4)xWO3-y样品可以很好的遮蔽近红外光(遮蔽率:74.5％),同时保持高可见光透过率(67.6％).
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